IP Library Granted Patent US 10,632,722
Granted Patent B2
US 10,632,722 · App. 15/723,339 · Granted Apr 28, 2020

Composite material, method of forming the same, and apparatus including composite material

Inventors: Haengdeog Koh (Hwaseong-si, KR); Doyoon Kim (Hwaseong-si, KR); Seyun Kim (Seoul, KR); Jinhong Kim (Seoul, KR); Hajin Kim (Hwaseong-si, KR); Soichiro Mizusaki (Suwon-si, KR); Minjong Bae (Yongin-si, KR); Hiesang Sohn (Seoul, KR); Changsoo Lee (Seoul, KR)
Assignee: SAMSUNG ELECTRONICS CO., LTD.
B32B17/10174C01G55/004C03C3/093C03C8/02C03C14/002C03C14/006C03C17/008B32B17/10944B82Y30/00C01P2002/02C01P2004/03C01P2004/50C01P2004/51C01P2004/62C01P2004/64C03C2214/02C03C2214/16C03C2217/452C03C2217/48
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Quick Facts
Patent No.
US 10,632,722
App. No.
15/723,339
Granted
Apr 28, 2020
Kind
B2
Abstract

A composite material structure including a matrix material layer; and a plurality of one-dimensional nanostructure distributed in the matrix material layer and having an electrical conductivity which is greater than an electrical conductivity of the matrix material layer, wherein the plurality of one-dimensional nanostructures includes a first one-dimensional nanostructure and a second one-dimensional nanostructure in contact with each other.

Claims (52)

1. A composite material structure comprising:

a matrix material layer comprising a glass material; and

a plurality of one-dimensional nanostructures distributed in the matrix material layer and having an electrical conductivity greater than an electrical conductivity of the matrix material layer,

wherein the plurality of one-dimensional nanostructures comprises a first one-dimensional nanostructure and a second one-dimensional nanostructure in contact with each other,

wherein the plurality of one-dimensional nanostructures comprises a metal oxide in a form of a nanowire, a nanorod, or a combination thereof,

wherein at least a portion of the plurality of one-dimensional nanostructures protrudes from a surface of the glass material, and

wherein an amount of the plurality of one-dimensional nanostructures in the composite material is less than or equal to 5 volume percent, based on a total volume of the composite material.

2. The composite material structure of claim 1 , wherein the plurality of one-dimensional nanostructures has an aspect ratio of about 2 or higher.

3. The composite material structure of claim 1 , wherein the plurality of one-dimensional nanostructures has a diameter of about 5 nanometers to about 300 nanometers and a length of about 500 nanometers to about 20 micrometers.

4. The composite material structure of claim 1 , wherein at least a portion of the plurality of one-dimensional nanostructures protrudes from a surface of the matrix material layer.

5. The composite material structure of claim 1 , wherein the plurality of one-dimensional nanostructures comprises RuO 2 .

6. The composite material structure of claim 1 , wherein the plurality of one-dimensional nanostructures comprises a rutile crystalline structure.

7. The composite material structure of claim 1 , wherein the glass material comprises a silicon oxide, a lithium oxide, a nickel oxide, a cobalt oxide, a boron oxide, a potassium oxide, an aluminum oxide, a titanium oxide, a manganese oxide, a copper oxide, a zirconium oxide, a phosphorus oxide, a zinc oxide, a bismuth oxide, a lead oxide, a sodium oxide, or a combination thereof.

8. The composite material structure of claim 1 , wherein an amount of the plurality of one-dimensional nanostructures in the composite material is less than or equal to about 2.5 volume percent, based on a total volume of the composite material.

9. The composite material structure of claim 1 , wherein the composite material has an electrical conductivity of about 5 Siemens per meter or greater at room temperature.

10. The composite material structure of claim 1 , wherein the composite material structure is a heating element.

11. The composite material structure of claim 1 , wherein the composite material structure is a resistor.

12. An apparatus comprising a heating element, wherein the heating element comprises a composite material structure, the composite material structure comprising:

a matrix material layer comprising a glass material; and

a plurality of one-dimensional nanostructures distributed in the matrix material layer and having an electrical conductivity greater than an electrical conductivity of the matrix material layer,

wherein the plurality of one-dimensional nanostructures comprises a first one-dimensional nanostructure and a second one-dimensional nanostructure in contact with each other,

wherein the plurality of one-dimensional nanostructures comprises a metal oxide in a form of a nanowire, a nanorod, or a combination thereof,

wherein at least a portion of the plurality of one-dimensional nanostructures protrudes from a surface of the glass material, and

wherein an amount of the plurality of one-dimensional nanostructures in the composite material is less than or equal to 5 volume percent, based on a total volume of the composite material.

13. A method of forming a composite material structure, the method comprising:

providing a solution comprising a plurality of colloidal particles comprising a metal element;

adding a glass powder to the solution to form a solution comprising the plurality of colloidal particles and the glass powder;

adding a binder to the solution comprising the plurality of colloidal particles and the glass powder to form a mixed solution comprising the plurality of colloidal particles, the glass powder, and the binder;

forming a film by applying the mixed solution containing the plurality of colloidal particles, the glass powder, and the binder onto a substrate; and

forming a plurality of one-dimensional nanostructures from the plurality of colloidal particles and forming a matrix material layer from the glass powder by performing a thermal treatment process on the film to prepare the composite material structure, wherein the plurality of one-dimensional nanostructures is formed in the matrix material layer,

wherein the plurality of one-dimensional nanostructures comprises a metal oxide in a form of a nanowire, a nanorod, or a combination thereof,

wherein at least a portion of the plurality of one-dimensional nanostructures protrudes from a surface of the glass material, and

wherein an amount of the plurality of one-dimensional nanostructures in the composite material is less than or equal to 5 volume percent, based on a total volume of the composite material.

14. The method of claim 13 , wherein the thermal treatment process comprises:

annealing the film; and

sintering the film,

wherein in the annealing of the film, the plurality of one-dimensional nanostructure is formed from at least a portion of the plurality of the colloidal particles on a surface of the glass powder, and

wherein in the sintering of the film, the matrix material layer is formed from the glass powder.

15. The method of claim 14 , wherein the annealing of the film is performed at a temperature of about 300° C. to about 500° C.

16. The method of claim 14 , wherein the sintering of the film is performed at a temperature of about 500° C. to about 1200° C.

17. The method of claim 13 , wherein the providing of the solution comprising the plurality of colloidal particles comprising the metal element comprises:

dissolving a metal precursor in an acid solution; and

forming the plurality of the colloidal particles from the metal precursor by adding a basic solution to the acid solution.

18. The method of claim 13 , wherein the plurality of the colloidal particles is amorphous, and the plurality of one-dimensional nanostructures are crystalline.

19. The method of claim 13 , wherein the plurality of one-dimensional nanostructures comprises a nanowire, a nanorod, or a combination thereof.

20. The method of claim 13 , wherein the plurality of one-dimensional nanostructures comprises a metal oxide.

21. The method of claim 13 , wherein the plurality of one-dimensional nanostructures comprises rutile RuO 2 .

22. A method of manufacturing an apparatus, the method comprising:

forming a heating element; and

forming an electrode structure electrically connected to the heating element,

wherein the forming of the heating element comprises forming a composite material structure using the method of claim 13 .

23. The composite material structure of claim 1 , wherein the glass material comprises glass particles or an enamel powder, and wherein the plurality of one-dimensional nanostructures protrude from a surface of the glass particles or the enamel powder.

Assignments (4)
RELEASE OF SECURITY INTEREST Recorded Jun 28, 2023
From: THE HUNTINGTON NATIONAL BANK (SUCCESSOR BY MERGER TO TCF NATIONAL BANK)
To: GED PURCHASER, INC.; GED INTEGRATED HOLDINGS, INC.; GED INTEGRATED SOLUTIONS, INC.; NORFIELD ACQUISITION, LLC
Reel/Frame 064149/0591 →
SECURITY INTEREST Recorded May 25, 2021
From: GED PURCHASER, INC.; GED INTEGRATED HOLDINGS, INC.; GED INTEGRATED SOLUTIONS, INC.; NORFIELD ACQUISITION, LLC
To: TCF NATIONAL BANK, AS ADMINISTRATIVE AGENT
Reel/Frame 056392/0656 →
SECURITY INTEREST Recorded Feb 22, 2021
From: GED INTEGRATED SOLUTIONS, INC.
To: TCF NATIONAL BANK
Reel/Frame 055357/0011 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 3, 2017
From: KOH, HAENGDEOG; KIM, DOYOON; KIM, SEYUN; KIM, JINHONG; KIM, HAJIN; MIZUSAKI, SOICHIRO; BAE, MINJONG; SOHN, HIESANG; LEE, CHANGSOO
To: SAMSUNG ELECTRONICS CO., LTD.
Reel/Frame 043768/0852 →