Fuel cell stack and method for manufacturing fuel cell stack
A fuel cell stack including a plurality of electricity generation units fastened by means of a plurality of fastening members. Each electricity generation unit includes a single cell, and a sealing member sandwiched between two other members thereby sealing one of the anode chamber and the cathode chamber. The surface of the sealing member included in at least one electricity generation units, the surface facing either of the two other members, has a surface roughness Ra of 3.0 μm or less.
1. A fuel cell stack comprising:
a plurality of electricity generation units disposed in a first direction; and
a plurality of fastening members extending in the first direction, the fuel cell stack being fastened by means of the fastening members and being characterized in that
each of the electricity generation units comprises:
a single cell including an electrolyte layer, and a cathode and an anode which face each other in the first direction with the electrolyte layer intervening therebetween, and
a sealing member having a through hole defining one of an anode chamber facing the anode and a cathode chamber facing the cathode, the sealing member being sandwiched between two other members in the first direction, thereby sealing the one of the anode chamber and the cathode chamber; and
the surface of the sealing member included in at least one of the electricity generation units, the surface facing either of the two other members, has a surface roughness Ra of 3.0 μm or less,
the sealing member has a hysteresis property, and
with regard to an inflection point at a curve representing a relationship between pressure applied to the sealing member and strain arising from the sealing member, in the sealing members, a value of the pressure of the inflection point at a position around one fastening member of the plurality of fastening members and a value of the pressure of the inflection point at a position around a midpoint of the other fastening member adjacent to the one fastening member are a value of ±20%.
2. The fuel cell stack according to claim 1 , wherein the surface of the sealing member included in at least one of the electricity generation units, the surface facing either of the two other members, exhibits a standard deviation of undulation Pa of 0.2 or less.
3. The fuel cell stack according to claim 2 , wherein the surface of the sealing member facing either of the two other members has an average undulation Pa of 1.4 μm or less.
4. A method for producing the fuel cell stack according to claim 1 , the fuel cell stack comprising a single cell including an electrolyte layer, and a cathode and an anode which face each other in a first direction with the electrolyte layer intervening therebetween; and a sealing member having a through hole defining one of an anode chamber facing the anode and a cathode chamber facing the cathode, the sealing member being sandwiched between two other members in the first direction, thereby sealing the one of the anode chamber and the cathode chamber, the single cell and the sealing member being disposed in the first direction and fastened by means of a plurality of fastening members extending in the first direction, the method being characterized by comprising:
a compression step of applying a compressive load to the sealing member having a hysteresis property;
an assembly step of fastening a plurality of the single cells and a plurality of the sealing members by means of the plurality of fastening members after the compression step, and
a compressive load in the compression step is, with regard to an inflection point at a curve representing a relationship between pressure applied to the sealing member and strain arising from the sealing member, in the sealing members, such a compressive load that a value of the pressure of the inflection point at a position around one fastening member of the plurality of fastening members and a value of the pressure of the inflection point at a position around a midpoint of other fastening member adjacent the one fastening member are a value of ±20%.
5. The method for producing a fuel cell stack according to claim 4 , the method further comprising:
a thermal treatment step of heating the sealing member before the compression step.
6. The method for producing a fuel cell stack according to claim 4 , wherein the compressive load per unit area of the sealing member in the compression step is greater than the load per unit area applied to the sealing member through fastening of the fuel cell stack by means of the fastening members at the completion of the assembly step.
7. The method for producing a fuel cell stack according to claim 5 , wherein the compressive load per unit area of the sealing member in the compression step is greater than the load per unit area applied to the sealing member through fastening of the fuel cell stack by means of the fastening members at the completion of the assembly step.