High modulus glass fibre composition, and glass fibre and composite material thereof
The present invention provides a high-modulus glass fiber composition, a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 55-64% SiO 2 , 13-24% Al 2 O 3 , 0.1-6% Y 2 O 3 , 3.4-10.9% CaO, 8-14% MgO, lower than 22% CaO+MgO+SrO, lower than 2% Li 2 O+Na 2 O+K 2 O, lower than 2% TiO 2 , lower than 1.5% Fe 2 O 3 , 0-1.2% La 2 O 3 , wherein the range of the weight percentage ratio C1=(Li 2 O+Na 2 O+K 2 O)/(Y 2 O 3 +La 2 O 3 ) is greater than 0.26. Said composition can significantly increase the glass elastic modulus, effectively inhibit the crystallization tendency of glass, decrease the liquidus temperature, secure a desirable temperature range (ΔT) for fiber formation and enhance the fining of molten glass, thus making it particularly suitable for production of high-modulus glass fiber with refractory-lined furnaces.
1. A high-modulus glass fiber composition, comprising the following components expressed as percentage by weight:
SiO 2
55-64%
Al 2 O 3
16.8-24%
Y 2 O 3
3-6%
CaO
3.4-9.9%
MgO
9.3-14%
CaO + MgO + SrO
<22%
Li 2 O + Na 2 O + K 2 O
<2%
TiO 2
<2%
Fe 2 O 3
<1.5%
La 2 O 3
0-1.2%
wherein, the range of the weight percentage ratio C1=(Li 2 O+Na 2 O+K 2 O)/(Y 2 O 3 +La 2 O 3 ) is greater than 0.26.
2. The high-modulus glass fiber composition according to claim 1 , wherein the range of the weight percentage ratio C2=MgO/(CaO+SrO) is 0.8-2.1.
3. The high-modulus glass fiber composition according to claim 1 , comprising the following components expressed as percentage by weight:
SiO 2
56-60.4%
Al 2 O 3
16.8-24%
Y 2 O 3
3-6%
CaO
3.4-9.9%
MgO
9.3-14%
CaO + MgO + SrO
<22%
SrO
<3%
Li 2 O + Na 2 O + K 2 O
<2%
TiO 2
<2%
Fe 2 O 3
<1.5%
La 2 O 3
0-1.2%
wherein, the range of the weight percentage ratio C1=(Li 2 O+Na 2 O+K 2 O)/(Y 2 O 3 +La 2 O 3 ) is greater than 0.26.
4. The high-modulus glass fiber composition according to claim 1 , comprising the following components expressed as percentage by weight:
SiO 2
56-60.4%
Al 2 O 3
16.8-24%
Y 2 O 3
3-5%
CaO
3.4-9.9%
MgO
9.3-14%
CaO + MgO + SrO
<22%
SrO
<3%
Li 2 O
0.1-1.5%
Li 2 O + Na 2 O + K 2 O
<2%
TiO 2
<2%
Fe 2 O 3
<1.5%
La 2 O 3
0-1.2%
wherein, the range of the weight percentage ratio C1=(Li 2 O+Na 2 O+K 2 O)/(Y 2 O 3 +La 2 O 3 ) is greater than 0.26, and the weight percentage ratio C2=MgO/(CaO+SrO) is 0.8-2.1.
5. The high-modulus glass fiber composition according to claim 1 , comprising the following components expressed as percentage by weight:
SiO 2
56-60.4%
Al 2 O 3
16.8-24%
Y 2 O 3
3-5%
CaO
3.4-9.9%
MgO
9.3-14%
CaO + MgO + SrO
<22%
SrO
<3%
Li 2 O
0.1-1.5%
Li 2 O + Na 2 O + K 2 O
<2%
TiO 2
<2%
Fe 2 O 3
<1.5%
La 2 O 3
0-1.2%
wherein, the range of the weight percentage ratio C1=(Li 2 O+Na 2 O+K 2 O)/(Y 2 O 3 +La 2 O 3 ) is greater than 0.28, and the weight percentage ratio C2=MgO/(CaO+SrO) is 0.8-2.1.
6. The high-modulus glass fiber composition according to claim 1 , comprising the following components expressed as percentage by weight:
SiO 2
57-60.4%
Al 2 O 3
16.8-24%
Y 2 O 3
3-5%
CaO
5-9.9%
MgO
9.3-14%
CaO + MgO + SrO
<21%
SrO
<3%
Li 2 O
0.1-1%
Li 2 O + Na 2 O + K 2 O
<2%
TiO 2
<2%
Fe 2 O 3
<1.5%
La 2 O 3
0-1.2%
wherein, the range of the weight percentage ratio C1=(Li 2 O+Na 2 O+K 2 O)/(Y 2 O 3 +La 2 O 3 ) is greater than 0.28, and the weight percentage ratio C2=MgO/(CaO+SrO) is 0.8-2.1.
7. The high-modulus glass fiber composition according to claim 1 , comprising the following components expressed as percentage by weight:
SiO 2
57-60.4%
Al 2 O 3
16.8-23%
Y 2 O 3
3-5%
CaO
6-9.9%
MgO
9.3-13%
CaO + MgO + SrO
<21%
SrO
<3%
Li 2 O
0.1-1%
Li 2 O + Na 2 O + K 2 O
<2%
TiO 2
<2%
Fe 2 O 3
<1.5%
La 2 O 3
0-1.2%
wherein, the range of the weight percentage ratio C1=(Li 2 O+Na 2 O+K 2 O)/(Y 2 O 3 +O 3 ) is greater than 0.29, and the weight percentage ratio C2=MgO/(CaO+SrO) is 0.9-1.8.
8. The high-modulus glass fiber composition according to claim 1 , comprising the following components expressed as percentage by weight:
SiO 2
57-60.4%
Al 2 O 3
16.8-23%
Y 2 O 3
3-5%
CaO
6-9.9%
MgO
9.3-13%
CaO + MgO + SrO
<21%
SrO
<3%
Li 2 O
0.1-1%
Li 2 O + Na 2 O + K 2 O
<2%
TiO 2
<2%
Fe 2 O 3
<1.5%
La 2 O 3
0-1.2%
wherein, the range of the weight percentage ratio C1=(Li 2 O+Na 2 O+K 2 O)/(Y 2 O 3 +La 2 O 3 ) is greater than 0.29, and the weight percentage ratio C2=MgO/(CaO+SrO) is 0.9-1.7.
9. The high-modulus glass fiber composition according to claim 1 , comprising the following components expressed as percentage by weight:
SiO 2
55-64%
Al 2 O 3
greater than 19% and not greater than 21%
Y 2 O 3
3-6%
CaO
3.4-9.9%
MgO
9.3-10.5%
CaO + MgO + SrO
<22%
Li 2 O + Na 2 O + K 2 O
≤1%
TiO 2
<2%
Fe 2 O 3
<1.5%
La 2 O 3
0-1.2%
wherein, the range of the weight percentage ratio C1=(Li 2 O+Na 2 O+K 2 O)/(Y 2 O 3 +La 2 O 3 ) is greater than 0.26.
10. The high-modulus glass fiber composition according to claim 1 , wherein the content range of Li 2 O by weight is 0.1-1.5%.
11. The high-modulus glass fiber composition according to claim 1 , wherein the content range of SrO by weight is 0.1-2.5%.
12. The high-modulus glass fiber composition according to claim 1 , wherein the content range of CaO by weight is 6-9.9%.
13. The high-modulus glass fiber composition according to claim 1 , wherein the content range of MgO by weight is 9.38-13%.
14. The high-modulus glass fiber composition according to claim 1 , wherein the content range of MgO by weight is greater than 12% and not greater than 13%.
15. The high-modulus glass fiber composition according to claim 2 , wherein the content range of Y 2 O 3 by weight is 39.5-5%.
16. The high-modulus glass fiber composition according to claim 1 , wherein the content range of La 2 O 3 by weight is 0.1-1%.
17. The high-modulus glass fiber composition according to claim 1 , comprising CeO2 with the weight percentage of 0-1%.
18. A glass fiber produced from the glass fiber composition described in claim 1 .
19. The glass fiber according to claim 18 having the range of the elastic modulus 90-103 GPa.
20. A composite material incorporating the glass fiber described in claim 18 .