COMPOSITION FOR FORMING HIGH RELEASE AND LOW FRICTION FUNCTIONAL COATINGS
The present disclosure provides a composition for forming a coating including at least one dry lubricant material, at least one binder resin, and at least one β-alkoxypropionamide solvent. The composition can be applied to a wide variety of rigid and flexible substrates. A process for making articles is also provided.
1 . A composition for forming a coating, the composition comprising:
at least one functional additive;
at least one binder; and
at least one β-alkoxypropionamide solvent of the formula:
wherein R 1 is a C 1 to C 8 alkyl, and
R 2 and R 3 are independently selected from hydrogen, C 1 to C 6 alkyl, C 1 to C 6 alkoxy, C 1 to C 6 alkoxyalkyl, or glycidyl.
2 . The composition of claim 1 , wherein R 1 is a C 1 to C 4 alkyl, and R 2 and R 3 are independently selected from H or C 1 to C 4 alkyl.
3 . The composition of claim 1 , wherein the β-alkoxypropionamide solvent is 3-methoxy-N,N-dimethylpropanamide.
4 . The composition of claim 1 , wherein the β-alkoxypropionamide solvent is 3-buthoxy-N,N-dimethylpropanamide.
5 . The composition of claim 1 , wherein the at least one functional additive comprises at least one additive selected from the group consisting of: graphite, molybdenum disulphide, hexagonal boron nitride, fluoropolymers, and silicone-based materials.
6 . The composition of claim 5 , wherein the at least one functional additive includes at least one fluoropolymer selected from the group consisting of: polytetrafluorethylene (PTFE); fluorinated ethylene-propylene (FEP); perfluoroalkoxy polymer (PFA); perfluoro methylalkoxy polymer (MFA); polyvinylidene fluoride (PVDF); polyethylenetetrafluoroethlene (ETFE); polyethylenechlorotrifluoroethylene (ECTFE); and polymers of tetrafluoroethylene, hexafluoropropylene and vinylidene fluoride (THV).
7 . The composition of claim 5 , wherein the at least one functional additive includes polytetrafluorethylene (PTFE).
8 . The composition of claim 1 , wherein the at least one binder comprises at least one engineering polymer.
9 . The composition of claim 8 , wherein the engineering polymer comprises at least one polymer selected from the group consisting of: polyphenylene sulfide (PPS); polyetheretherketone (PEEK); polysulfone (PESU); polyimide (PI); polyamide-imides (PAI); and polyetherimide (PEI).
10 . The composition of claim 1 , further comprising at least one additional component selected from the group consisting of pigments and colorants; non-β-alkoxypropionamide solvents; functional fillers; defoamers; surface wetting agents; flow agents; pigment wetting additives; thickeners; fillers; additives that change the electric conductivity of the composition; pH correctors; and flash rust inhibitors.
11 . A method of forming a coating comprising:
providing a composition, wherein the composition comprises
at least one functional additive;
at least one binder; and
at least one β-alkoxypropionamide solvent of the formula:
wherein R 1 is a C 1 to C 8 alkyl, and
R 2 and R 3 are independently selected from hydrogen, C 1 to C 6 alkyl, C 1 to C 6 alkoxy, C 1 to C 6 alkoxyalkyl, or glycidyl;
applying the composition to a substrate; and
curing the composition to produce a coating.
12 . The method of claim 11 , wherein said curing step comprises heating the coating at a temperature of 400° C. to 450° C. for a time from 3 minutes to 20 minutes.
13 . The method of claim 11 , wherein said curing step comprises drying in air at ambient temperature.
14 . The method of claim 11 , further comprising the additional steps of:
heating the applied composition and substrate to form a first dried layer; and
applying a second composition to the first dried layer, wherein the second composition comprises at least one solvent, at least one binder, and at least one functional additive;
wherein said curing step comprises curing the first dried layer and the second composition to produce a coating.
15 . The method of claim 11 , wherein the β-alkoxypropionamide solvent is selected from the group consisting of 3-methoxy-N,N-dimethylpropanamide and 3-buthoxy-N,N-dimethylpropanamide.
16 . The method of claim 11 , wherein the at least one functional additive is selected from the group consisting of: graphite, molybdenum disulphide, hexagonal boron nitride, fluoropolymers, and silicone-based materials.
17 . The method of claim 11 , wherein the binder comprises at least one engineering polymer selected from the group consisting of: polyphenylene sulfide (PPS); polyetheretherketone (PEEK); polysulfone (PESU); polyimide (PI); polyamide-imides (PAI); and polyetherimide (PEI).
18 . A coated article comprising a substrate coated with a coating, wherein the coating is formed from composition comprising:
at least one functional additive;
at least one binder; and
at least one β-alkoxypropionamide solvent of the formula:
wherein R 1 is a C 1 to C 8 alkyl, and
R 2 and R 3 are independently selected from hydrogen, C 1 to C 6 alkyl, C 1 to C 6 alkoxy, C 1 to C 6 alkoxyalkyl, or glycidyl.
19 . The coated article of claim 18 , wherein the substrate is selected from the group consisting of cookware, bakeware, molds, small electrical appliances, fasteners, reprographic rollers, glasscloth, architectural fabrics, as well as heat sealing belts, circuit boards, cooking sheets, tenting fabrics, staple fiber, fiberfill, yarn, thread, textiles, nonwoven fabric, wire cloth, ropes, belting, cordage, and webbing.
20 . The coated article of claim 18 , wherein the article is an article of cookware.
21 . The coated article of claim 18 , wherein the coating has a dry film thickness from 5 microns to 30 microns.