Polybutylene terephthalate resin composition
A polybutylene terephthalate resin composition containing a polybutylene terephthalate resin, 10 to 20% by mass of glass fiber relative to a total mass of the composition, an ethylene/ethyl acrylate copolymer, and an epoxy compound having an epoxy equivalent weight of 600 to 1,500 g/equivalent, and having a comparative tracking index (CTI) of 600 V or higher, measured in accordance with the third edition of IEC 60112.
1. A method of making a polybutylene terephthalate resin composition with an increased comparative tracking index measured in accordance with a third edition of IEC 60112, the method comprising combining a polybutylene terephthalate component, glass fiber, an epoxy compound having an epoxy equivalent weight of 600 to 1,500 g/equivalent, an ethylene/ethyl acrylate copolymer, and optionally one or more additives to form the polybutylene terephthalate resin composition;
wherein the polybutylene terephthalate component consists of at least one polybutylene terephthalate resin and optionally another polyester resin;
wherein the polybutylene terephthalate resin composition consists of: said polybutylene terephthalate component; 10 to 20% by mass, relative to the total mass of the composition, of said glass fiber; an amount of said epoxy compound, such that an amount of epoxy groups in the composition is within a range from 0.5×10 −2 to 2.5×10 −2 mmol/g; 4 to about 15% by mass, relative to the total mass of the composition, of said ethylene/ethyl acrylate copolymer; and said one or more optional additives;
wherein the polybutylene terephthalate resin composition has a comparative tracking index of 600 V or higher, and a molded article of the polybutylene terephthalate resin composition has a tensile elongation of at least 3%.
2. The method according to claim 1 , wherein a molded article of the polybutylene terephthalate resin composition has a tensile elongation of at least 3.2%.
3. The method according to claim 1 , wherein the glass fiber is present in an amount of 12 to 18% by mass, relative to the total mass of the composition.
4. The method according to claim 1 , wherein the epoxy compound is present in an amount such that an amount of epoxy groups in the composition is within a range from 1.0×10 −2 to 2.1×10 −2 mmol/g.
5. The method according to claim 1 , wherein the ethylene/ethyl acrylate copolymer is present in an amount of 5 to about 10% by mass, relative to the total mass of the composition.
6. The method according to claim 1 , wherein said one or more additives is selected from the group consisting of antioxidants, ultraviolet absorbers, stabilizers, plasticizers, release agents, colorants, near-infrared absorbers, fluorescent whiteners, flame retardants, flame retardancy assistants, and fillers other than glass fiber.
7. A method of making a polybutylene terephthalate resin composition with an increased comparative tracking index measured in accordance with a third edition of IEC 60112, the method comprising combining a polybutylene terephthalate resin, glass fiber, an epoxy compound having an epoxy equivalent weight of 600 to 1,500 g/equivalent, and an ethylene/ethyl acrylate copolymer to form the polybutylene terephthalate resin composition; wherein the polybutylene terephthalate resin composition consists of said polybutylene terephthalate resin, said glass fiber, said epoxy compound, and said ethylene/ethyl acrylate copolymer; wherein the glass fiber is present in an amount of 10 to 20% by mass relative to a total mass of the polybutylene terephthalate resin composition; and
wherein the polybutylene terephthalate resin composition has a comparative tracking index of 600 V or higher.