IP Library Granted Patent US 11,148,122
Granted Patent B2
US 11,148,122 · App. 15/744,588 · Granted Oct 19, 2021

SCR catalyst for removing nitrogen oxides and method for producing same

Inventors: Sam Kyung Sung (Ulsan, KR); Sang Ek Lee (Ulsan, KR); Do Yun Kim (Ulsan, KR); Hyun Soo Kim (Ulsan, KR); Mong Kyu Chung (Ulsan, KR); Chan Do Park (Ulsan, KR)
Assignees: Korea Shipbuilding & Offshore Engineering Co., Ltd.; Hyundai Heavy Industries Co., Ltd.
B01J23/30B01D53/9418B01J21/06B01J21/16B01J23/22B01J23/28B01J35/0006B01J37/00B01J37/04B01J37/08B01D2255/20707B01D2255/20723B01D2255/20769B01D2255/20776
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Quick Facts
Patent No.
US 11,148,122
App. No.
15/744,588
Granted
Oct 19, 2021
Kind
B2
Abstract

A SCR catalyst for removing nitrogen oxides comprises: a carrier prepared from a support in which Ti-PILC is mixed with titania; and a catalyst material on the carrier, wherein the catalyst material contains an active material of a vanadium component and a co-catalyst of a tungsten component. On the basis of the total weight of the catalyst, the support Ti-PILC is contained at 0.01-40 wt %, and the support titania is contained at 50 to 90 wt %. In addition, a method for producing a SCR catalyst for removing nitrogen oxides comprises the steps of: preparing a carrier by using a support in which Ti-PILC is mixed with titania; and supporting a catalyst material on the carrier. The present disclosure provides: a SCR catalyst for removing nitrogen oxides, which has an excellent nitrogen oxide removing performance and a high producing convenience; and a method for producing the same.

Claims (11)

1. A SCR catalyst for removing nitrogen oxides, comprising a support in which Ti-pillared interlayer clay (Ti-PILC) is mixed with titania (TiO 2 ) as a carrier, wherein, on the basis of a total weight of the catalyst, the ratio of the support Ti-PILC to the support titania (TiO 2 ) is 0.1 to 0.4.

2. The SCR catalyst for removing nitrogen oxides according to claim 1 , wherein a catalyst material on the carrier contains an active material of a vanadium (V 2 O 5 ) component and a cocatalyst of a tungsten (WO 3 ) component.

3. The SCR catalyst for removing nitrogen oxides according to claim 2 , wherein on the basis of the total weight of the catalyst, the active material vanadium (V 2 O 5 ) is contained at 0.01-15 wt %, and the cocatalyst tungsten (WO 3 ) is contained at 0.01 to 15 wt %.

4. The SCR catalyst for removing nitrogen oxides according to claim 1 , wherein to the catalyst, a cocatalyst selected from a group consisting of cerium (Ce), sulfur dioxide (SO 2 ), iron (Fe), molybdenum (Mo), yttrium (Y), and lanthanides is further added at 10 wt % or less with respect to the total weight of the catalyst.

5. A method for producing a SCR catalyst for removing nitrogen oxides, the method comprising the steps of:

preparing a carrier by using a support in which Ti-pillared interlayer clay (Ti-PILC) is mixed with titania (TiO 2 ) wherein, on the basis of a total weight of the catalyst, the ratio of the support Ti-PILC to the support titanic (TiO 2 ) is 0.1 to 0.4; and supporting a catalyst material on the carrier.

6. The method according to claim 5 , wherein the supporting step supports a catalyst material comprising the active material vanadium (V 2 O 5 ) and the cocatalyst tungsten (WO 3 ).

7. The method according to claim 5 , wherein to the catalyst, a cocatalyst selected from a group consisting of cerium (Ce), sulfur dioxide (SO 2 ), iron (Fe), molybdenum (Mo), yttrium (Y), and lanthanides is further added in the supporting step.

8. The method according to claim 5 , wherein calcination is performed at a calcination temperature of 500° C. to 600° C. after the supporting.

9. The SCR catalyst for removing nitrogen oxides according to claim 1 , wherein, on the basis of the total weight of the catalyst, the ratio of the support Ti-PILC to the support titania (TiO 2 ) is 0.25.

10. The method according to claim 5 , wherein, on the basis of the total weight of the catalyst, the ratio of the support Ti-PILC to the support titania (TiO 2 ) is 0.25.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 26, 2021
From: KOREA SHIPBUILDING & OFFSHORE ENGINEERING CO., LTD.
To: HYUNDAI HEAVY INDUSTRIES CO., LTD.
Reel/Frame 056359/0819 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE COUNTRY PREVIOUSLY RECORDED AT REEL: 052494 FRAME: 0445. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Nov 3, 2020
From: HYUNDAI HEAVY INDUSTRIES CO., LTD.
To: KOREA SHIPBUILDING & OFFSHORE ENGINEERING CO., LTD.
Reel/Frame 054293/0679 →
CHANGE OF NAME Recorded Apr 24, 2020
From: HYUNDAI HEAVY INDUSTRIES CO., LTD.
To: KOREA SHIPBUILDING & OFFSHORE ENGINEERING CO., LTD.
Reel/Frame 052494/0445 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 12, 2018
From: SUNG, SAM KYUNG; LEE, SANG EK; KIM, DO YUN; KIM, HYUN SOO; CHUNG, MONG KYU; PARK, CHAN DO
To: HYUNDAI HEAVY INDUSTRIES CO., LTD.
Reel/Frame 044612/0694 →
Priority Claims (1)
KR 10-2015-0100674 · Jul 15, 2015 · national
Continuity (1)
Related Publication 20180200697A1 · Jul 19, 2018