IP Library Granted Patent US 10,519,310
Granted Patent B2
US 10,519,310 · App. 15/748,310 · Granted Dec 31, 2019

Polycarbonate resin composition

Inventor: Yasunori Inazawa (Osaka, JP)
Assignee: TEIJIN LIMITED
C08L69/00C08K5/0066C08K5/49C08L23/00C08L23/06C08L23/0838C08L23/14C08L51/04C08L53/02C08L2205/025C08L2205/03C08L2205/035
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Quick Facts
Patent No.
US 10,519,310
App. No.
15/748,310
Granted
Dec 31, 2019
Kind
B2
Abstract

A resin composition comprising 1 to 20 parts by weight of (C) at least one styrene-based thermoplastic elastomer (component C) selected from the group consisting of a styrene-ethylene.propylene-styrene block copolymer (SEPS), a styrene-ethylene-butylene-styrene block copolymer (SEBS) and a styrene-butadiene-butylene-styrene block copolymer (SBBS) based on 100 parts by weight of the total of (A) a polycarbonate-based resin (component A) and (B) a polyolefin-based resin having a MFR at 230° C. under a load of 2.16 kg of not less than 40 g/10 min (component B). The resin composition is excellent in mechanical properties, chemical resistance, appearance and tape peeling resistance.

Claims (33)

1. A resin composition comprising:

1 to 20 parts by weight of (C) at least one styrene-based thermoplastic elastomer (component C) selected from the group consisting of a styrene-ethylene-propylene-styrene block copolymer (SEPS), a styrene-ethylene-butylene-styrene block copolymer (SEBS) and a styrene-butadiene-butylene-styrene block copolymer (SBBS),

based on 100 parts by weight of the total of (A) a polycarbonate-based resin (component A) and (B) a polyolefin-based resin having a MFR at 230° C. under a load of 2.16 kg of not less than 40 g/10 min (component B),

wherein the polyolefin-based resin (component B) includes a maleic anhydride-modified polypropylene resin having a MFR at 190° C. under a load of 2.16 kg of not less than 50 g/10 min.

2. A resin composition comprising:

1 to 20 parts by weight of (C) at least one styrene-based thermoplastic elastomer (component C) selected from the group consisting of a styrene-ethylene-propylene-styrene block copolymer (SEPS), a styrene-ethylene-butylene-styrene block copolymer (SEBS) and a styrene-butadiene-butylene-styrene block copolymer (SBBS), and

1 to 10 parts by weight of (D) a graft polymer (component D),

based on 100 parts by weight of the total of (A) a polycarbonate-based resin (component A) and (B) a polyolefin-based resin having a MFR at 230° C. under a load of 2.16 kg of not less than 40 g/10 min (component B),

wherein the graft polymer (component D) is a core-shell type graft polymer.

3. The resin composition according to claim 1 which comprises 0.01 to 30 parts by weight of a flame retardant (component E) based on 100 parts by weight of the total of the components A and B.

4. The resin composition according to claim 1 which comprises 1 to 100 parts by weight of an inorganic filler (component F) based on 100 parts by weight of the total of the components A and B.

5. The resin composition according to claim 1 which comprises 1 to 30 parts by weight of a phosphorus-based flame retardant (component E-2) and 0.01 to 1 part by weight of a hindered amine-based compound (component G) based on 100 parts by weight of the total of the components A and B.

6. The resin composition according to claim 1 which comprises 0.05 to 2 parts by weight of a dripping inhibitor (component H) based on 100 parts by weight of the total of the components A and B.

7. The resin composition according to claim 1 , wherein a MFR at 230° C. under a load of 2.16 kg of the polyolefin-based resin (component B) is not less than 60 g/10 min.

8. The resin composition according to claim 1 , wherein the polyolefin-based resin (component B) is a polypropylene-based resin.

9. The resin composition according to claim 1 , wherein the styrene content of the styrene-based thermoplastic elastomer (component C) is 40 to 80 wt %.

10. The resin composition according to claim 1 , wherein the weight ratio of the component A to the component B is 50/50 to 95/5.

11. The resin composition according to claim 5 , wherein the hindered amine-based compound (component G) is either N—R type (alkyl group (R) is bonded to a nitrogen atom) or N—OR type (alkoxy group (OR) is bonded to a nitrogen atom) hindered amine-based compound.

12. A molded article formed from the resin composition of claim 1 and having a tape peeling resistance of less than 0.5%.

13. A method of improving the tape peeling resistance of a molded article comprising a polycarbonate-based resin (component A), a polyolefin-based resin (component B) and a styrene-based thermoplastic elastomer (component C),

said method comprising:

selecting at least one from the group consisting of a styrene-ethylene-propylene-styrene block copolymer (SEPS), a styrene-ethylene-butylene-styrene block copolymer (SEBS) and a styrene-butadiene-butylene-styrene block copolymer (SBBS) as the styrene-based thermoplastic elastomer (component C), and

selecting a resin having a MFR at 230° C. under a load of 2.16 kg of not less than 40 g/10 min as the polyolefin-based resin (component B),

wherein the polyolefin-based resin (component B) includes a maleic anhydride-modified polypropylene resin having a MFR at 190° C. under a load of 2.16 kg of not less than 50 g/10 min.

14. A method of improving the tape peeling resistance of a molded article comprising a polycarbonate-based resin (component A), a polyolefin-based resin (component B), a styrene-based thermoplastic elastomer (component C), and a graft polymer (component D),

said method comprising:

selecting at least one from the group consisting of a styrene-ethylene-propylene-styrene block copolymer (SEPS), a styrene-ethylene-butylene-styrene block copolymer (SEBS) and a styrene-butadiene-butylene-styrene block copolymer (SBBS) as the styrene-based thermoplastic elastomer (component C), and

selecting a resin having a MFR at 230° C. under a load of 2.16 kg of not less than 40 g/10 min as the polyolefin-based resin (component B),

wherein the graft polymer (component D) is a core-shell type graft polymer.

15. The resin composition according to claim 2 which comprises 0.01 to 30 parts by weight of a flame retardant (component E) based on 100 parts by weight of the total of the components A and B.

16. The resin composition according to claim 2 which comprises 1 to 100 parts by weight of an inorganic filler (component F) based on 100 parts by weight of the total of the components A and B.

17. The resin composition according to claim 2 which comprises 1 to 30 parts by weight of a phosphorus-based flame retardant (component E-2) and 0.01 to 1 part by weight of a hindered amine-based compound (component G) based on 100 parts by weight of the total of the components A and B.

18. The resin composition according to claim 2 which comprises 0.05 to 2 parts by weight of a dripping inhibitor (component H) based on 100 parts by weight of the total of the components A and B.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 29, 2018
From: INAZAWA, YASUNORI
To: TEIJIN LIMITED
Reel/Frame 044754/0066 →
Priority Claims (4)
JP 2015-163840 · Aug 21, 2015 · national
JP 2015-249824 · Dec 22, 2015 · national
JP 2015-251702 · Dec 24, 2015 · national
JP 2015-256371 · Dec 28, 2015 · national
Continuity (1)
Related Publication 20180223098A1 · Aug 9, 2018