Electrocaloric heat transfer system

1. A heat transfer system, comprising

an electrocaloric element comprising a liquid crystal elastomer or a liquid form liquid crystal retained in an elastomeric polymer matrix;

a pair of electrodes disposed on opposite surfaces of the electrocaloric element;

a first thermal flow path between the electrocaloric element and a heat sink;

a second thermal flow path between the electrocaloric element and a heat source; and

a controller configured to control electrical current to the electrodes and to selectively direct transfer of heat energy from the electrocaloric element to the heat sink along the first thermal flow path or from the heat source to the electrocaloric element along the second thermal flow path, wherein the electrocaloric element comprises a multi-phase polymer composition comprising a first phase comprising the liquid crystal elastomer, and a second phase comprising a second polymer and the second phase is a continuous phase and the first phase is a discontinuous phase or the first phase is a continuous phase and the second phase is a discontinuous phase.

2. The system of claim 1 , wherein the heat source and/or the heat sink comprises a conditioned dielectric fluid.

3. The system of claim 2 , wherein the conditioned fluid is air.

4. The system of claim 2 , wherein the electrocaloric element comprises a fluid flow path for the dielectric fluid in thermal communication with the electrocaloric element.

5. The system of claim 4 , wherein the fluid flow path is a channel in the electrocaloric element.

6. The system of claim 4 , further comprising means responsive to the controller for selectively directing a heat source conditioned dielectric fluid or a heat sink dielectric fluid along the fluid flow path.

7. The system of claim 1 , wherein electrocaloric element comprises immobilized ionic impurities.

8. The system of claim 1 , wherein the liquid crystal elastomer has a polymer backbone that comprises mesogenic groups.

9. The system of claim 1 , wherein the liquid crystal elastomer has side chains that comprise mesogenic groups.

10. The system of claim 1 , wherein the liquid crystal elastomer has a modulus of elasticity of from 1 MPa to 100 MPa in the system's operating temperature range.

11. The system of claim 1 , wherein the liquid crystal elastomer has at least partial alignment of mesogenic groups in an orientation different from an orientation when electrical current is provided to the electrodes.

12. The system of claim 1 , wherein the second polymer is elastomeric.

13. The system of claim 1 , wherein the second polymer is not elastomeric.

14. A method of using the system of claim 1 , comprising

applying an electric field as a voltage differential across the electrocaloric element, thereby causing a decrease in entropy and a release of heat energy by the electrocaloric element;

transferring at least a portion of the released heat energy to the heat sink;

removing the electric field, thereby causing an increase in entropy and a decrease in heat energy and absorption of heat energy by the electrocaloric element; and

transferring heat energy from the heat source to be absorbed by the electrocaloric element.

15. The method of claim 14 , comprising

applying the electric field to the electrocaloric element to increase the temperature of the electrocaloric element until the temperature of the electrocaloric element reaches a first threshold;

transferring heat energy from the electrocaloric element to the heat sink to reduce the temperature of the electrocaloric element until the temperature of the electrocaloric element reaches a second threshold;

removing the electric field to reduce the temperature of the electrocaloric element until the temperature of the electrocaloric element reaches a third threshold;

transferring the heat energy from the heat source to cool the heat source and increase the temperature of the electrocaloric element until the temperature of the electrocaloric element reaches a fourth threshold; and optionally

repeating the above steps until a target temperature is reached for the heat source or heat sink.