Copper plating bath composition and method for deposition of copper

1. An aqueous acidic copper electroplating bath which comprises at least one source of copper ions and at least one acid characterized in that the bath further comprises at least one additive obtained by a reaction of at least one aminoglycidyl compound and at least one compound selected from ammonia and amine compounds wherein the amine compounds comprise at least one primary or secondary amino group with the proviso that the aminoglycidyl compound and/or the amine compound contains at least one polyoxyalkylene residue.

2. The aqueous acidic copper electroplating bath according to claim 1 characterized in that the at least one aminoglycidyl compounds is selected from (A1) to (A5):

wherein

each R is a monovalent residue independently selected from the group consisting of hydrogen, aliphatics, nitrogen-containing aliphatics, aralkyl, aryl, hetaryl, polyoxyalkylene and combinations of the aforementioned;

A is an (a+b)-valent hydrocarbon residue and a and b are integers each ranging from 0 to 10 with the proviso that the sum of a and b ranges from 2 to 10,

or

wherein (A5) is a cyclic hydrocarbon optionally comprising further heteroatoms selected from nitrogen, sulphur and/or oxygen in the ring and which consists of 4 to 12 carbon and heteroatoms; and c is an integer ranging from 1 to 6.

3. The aqueous acidic copper electroplating bath according to claim 2 characterized in that the aminoglycidyl compound is selected from the group consisting of benzyl(glycidyl)amine, N-glycidyldiethylamine, diglycidylamine, diglycidylethylamine, diglycidylmethylamine, diglycidylamine, diglycidylmethylamine, diglycidylethylamine, triglycidylamine, 4,4′-methylenebis(N,N-diglycidylaniline), 1,3-bis-(N,N-Diglycidylaminomethyl)cyclohexane, 1,3,5-tris(2-oxiranylmethyl)-1,3,5-triazinane-2,4,6-trione, 1-glycidylpiperidine, 4-glycidylmorpholine, 4-glycidylthiomorpholine, 1-glycidylpiperazine, 1-glycidylim idazol, 1-glycidylpyrazol, 1-glycidylpyrrolidine, 1-glycidyl-2-pyrolidone, 1-glycidyl-2-pyridone, 2-glycidylpyridazin-3-one, 1-furfuryl(glycidyl)amine, furfuryl(glycidyl)amine, glycidyl(tetrahydrofurfuryl)amine, 4-glycidyl-1,4-thiazepane, 1-glycidylazepane, 1-glycidylbenzimidazole, 3-glycidylthieno[2,3-d]pyrimidin-4-one, 3-glycidylthieno[3,2-d]pyrimidin-4-one and the glycidyl, diglycidyl and oligoglycidyl derivatives of polyetheramines.

4. The aqueous acidic copper electroplating bath according to claim 3 characterized in that the amine compound is selected from alkylamines; dialkylamines; alkylarylamines; aralkylamines; alkylendiamines or higher homologues thereof having the overall structure of H—(NH-G) g -NH 2 wherein each G is an alkylene residue independently selected from each other G having 1 to 8 carbon atoms and g is an integer ranging from 1 to 6; cyclic non-aromatic amines of the following structure

wherein each J is hydrogen, —CH 2 —NH 2 or —CH 2 —CH 2 —NH 2 and r is an integer ranging from 3 to 6; arylamines; diarylamines; nitrogen-containing hetaryls with optional amine moieties bound to the hetaryl moiety; amino acids; polyetheramines; polyvinyl amines; polyallyl amines; polyethylene imines; guanidines; aminoguanidines; urea, alkylurea, dialkylurea; carbomoyl acid derivatives and esters thereof; amidinyl derivatives and salts and/or hydrates of any of the aforementioned.

5. The aqueous acidic copper electroplating bath according to claim 4 characterized in that the at least one second compound is an amine compound is selected from alkylamines, alkylendiamines or higher homologues thereof having the overall structure of H—(NH-G) g -NH 2 wherein each G is an alkylene residue independently selected from each other G having 2 to 5 carbon atoms and g ranges from 1 to 4, cyclic non-aromatic amines of the following structure

wherein each J is hydrogen, —CH 2 —NH 2 or —CH 2 —CH 2 —NH 2 and r is 3 or 4 with the proviso that only one or no J is other than hydrogen; arylamines; nitrogen-containing hetaryls with optional amine moieties bound to the hetaryl moiety; polyetheramines; aminoguanidines and salts and/or hydrates of any of the aforementioned.

6. The aqueous acidic copper electroplating bath according to claim 1 characterized in that the aminoglycidyl compound is selected from the group consisting of benzyl(glycidyl)amine, N-glycidyldiethylamine, diglycidylamine, diglycidylethylamine, diglycidylmethylamine, diglycidylamine, diglycidylmethylamine, diglycidylethylamine, triglycidylamine, 4,4′-methylenebis(N,N-diglycidylaniline), 1,3-bis-(N,N-Diglycidylaminomethyl)cyclohexane, 1,3,5-tris(2-oxiranylmethyl)-1,3,5-triazinane-2,4,6-trione, 1-glycidylpiperidine, 4-glycidylmorpholine, 4-glycidylthiomorpholine, 1-glycidylpiperazine, 1-glycidylim idazol, 1-glycidylpyrazol, 1-glycidylpyrrolidine, 1-glycidyl-2-pyrolidone, 1-glycidyl-2-pyridone, 2-glycidylpyridazin-3-one, 1-furfuryl(glycidyl)amine, furfuryl(glycidyl)amine, glycidyl(tetrahydrofurfuryl)amine, 4-glycidyl-1,4-thiazepane, 1-glycidylazepane, 1-glycidylbenzimidazole, 3-glycidylthieno[2,3-d]pyrimidin-4-one, 3-glycidylthieno[3,2-d]pyrimidin-4-one and the glycidyl, diglycidyl and oligoglycidyl derivatives of polyetheramines.

7. The aqueous acidic copper electroplating bath according to claim 6 characterized in that the amine compound is selected from alkylamines; dialkylamines; alkylarylamines; aralkylamines; alkylendiamines or higher homologues thereof having the overall structure of H—(NH-G) g -NH 2 wherein each G is an alkylene residue independently selected from each other G having 1 to 8 carbon atoms and g is an integer ranging from 1 to 6; cyclic non-aromatic amines of the following structure

wherein each J is hydrogen, —CH 2 —NH 2 or —CH 2 —CH 2 —NH 2 and r is an integer ranging from 3 to 6; arylamines; diarylamines; nitrogen-containing hetaryls with optional amine moieties bound to the hetaryl moiety; amino acids; polyetheramines; polyvinyl amines; polyallyl amines; polyethylene imines; guanidines; aminoguanidines; urea, alkylurea, dialkylurea; carbomoyl acid derivatives and esters thereof; amidinyl derivatives and salts and/or hydrates of any of the aforementioned.

8. The aqueous acidic copper electroplating bath according to claim 7 characterized in that the at least one second compound is an amine compound is selected from alkylamines, alkylendiamines or higher homologues thereof having the overall structure of H—(NH-G) g -NH 2 wherein each G is an alkylene residue independently selected from each other G having 2 to 5 carbon atoms and g ranges from 1 to 4, cyclic non-aromatic amines of the following structure

wherein each J is hydrogen, —CH 2 —NH 2 or —CH 2 —CH 2 —NH 2 and r is 3 or 4 with the proviso that only one or no J is other than hydrogen; arylamines; nitrogen-containing hetaryls with optional amine moieties bound to the hetaryl moiety; polyetheramines; aminoguanidines and salts and/or hydrates of any of the aforementioned.

9. The aqueous acidic copper electroplating bath according to claim 1 characterized in that the amine compound is selected from alkylamines; dialkylamines; alkylarylamines; aralkylamines; alkylendiamines or higher homologues thereof having the overall structure of H—(NH-G) g -NH 2 wherein each G is an alkylene residue independently selected from each other G having 1 to 8 carbon atoms and g is an integer ranging from 1 to 6; cyclic non-aromatic amines of the following structure

wherein each J is hydrogen, —CH 2 —NH 2 or —CH 2 —CH 2 —NH 2 and r is an integer ranging from 3 to 6; arylamines; diarylamines; nitrogen-containing hetaryls with optional amine moieties bound to the hetaryl moiety; amino acids; polyetheramines; polyvinyl amines; polyallyl amines; polyethylene imines; guanidines; aminoguanidines; urea, alkylurea, dialkylurea; carbomoyl acid derivatives and esters thereof; amidinyl derivatives and salts and/or hydrates of any of the aforementioned.

10. The aqueous acidic copper electroplating bath according to claim 9 characterized in that the at least one second compound is an amine compound is selected from alkylamines, alkylendiamines or higher homologues thereof having the overall structure of H—(NH-G) g -NH 2 wherein each G is an alkylene residue independently selected from each other G having 2 to 5 carbon atoms and g ranges from 1 to 4, cyclic non-aromatic amines of the following structure

wherein each J is hydrogen, —CH 2 —NH 2 or —CH 2 —CH 2 —NH 2 and r is 3 or 4 with the proviso that only one or no J is other than hydrogen; arylamines; nitrogen-containing hetaryls with optional amine moieties bound to the hetaryl moiety; polyetheramines; aminoguanidines and salts and/or hydrates of any of the aforementioned.

11. The aqueous acidic copper electroplating bath according to claim 1 characterized in that the molar ratio of glycidyl moieties of one or more aminoglycidyl compounds and amino groups of the one or more amine compounds and/or ammonia is in the range of 1:0.8 and 1:1.5.

12. The aqueous acidic copper electroplating bath according to claim 1 characterized in that the polyoxyalkylene residues have been formed by propylene oxide and ethylene oxide in a molecular ratio of at least 0.25 mole propylene oxide per mole ethylene oxide.

13. The aqueous acidic copper electroplating bath according to claim 1 characterized in that the at least one additive bears at least one polyoxyalkylene residue having a molecular weight M w in the range of 100 to 10,000 g/mol.

14. The aqueous acidic copper electroplating bath according to claim 1 characterized in that at least one additive is one according to formula (I) to (III)

wherein R 1 and R 2 are monovalent residues independently from each other selected from the group consisting of hydrogen, aliphatics, nitrogen-containing aliphatics, aryl, hetaryl, alkaryl, carbamoyl, amidinyl, guanyl, ureyl, and polyoxyalkylene;

R 3 and R 4 are monovalent residues independently from each other selected from the group consisting of hydrogen, aliphatics, nitrogen-containing aliphatics, aryl, hetaryl, alkaryl and polyoxyalkylene and

with R 5 and R 6 being monovalent residues independently from each other selected from the group consisting of hydrogen, aliphatics, nitrogen-containing aliphatics, aryl, hetaryl, alkaryl, carbamoyl, amidinyl, guanyl, ureyl, and polyoxyalkylene;

with the proviso that at least one monovalent residue of R 1 to R 6 is selected to be polyoxyalkylene;

wherein R 7 and R 8 are monovalent residues independently from each other selected from the group consisting of hydrogen, aliphatics, nitrogen-containing aliphatics, aryl, hetaryl, alkaryl, carbamoyl, amidinyl, guanyl, ureyl, and polyoxyalkylene;

h is an integer ranging from 2 to 6;

X is an h-valent residue selected from the group consisting of

wherein

R 9 is a linear and/or cyclic, branched or unbranched alkylene of 1 to 12 carbon atoms, arylene and combinations thereof;

R 10 is a monovalent residue selected from the group consisting of hydrogen, aliphatics, nitrogen-containing aliphatics, aryl, hetaryl, alkaryl, and polyoxyalkylene;

i is an integer ranging from 0 to h and j is an integer ranging from 0 to h/2 with the proviso that the sum of i and 2*j equals h;

and each R 11 is a divalent residue independently selected from each other —(CH 2 ) k — with k being an integer ranging from 1 to 7, —C(O)—, —CH 2 —CH 2 —O—CH 2 —CH 2 —, —CH═CH—CH═CH—, —CH═CH—N═CH—, —CH═CH—N═N—, —CH═CH—CH═N—, —CH═CH—CH═CH—CH═N—, —CH═CH—CH═CH—N═CH—, and —CH═CH—CH═N—CH═CH—

with the proviso that at least one residue of R 7 , R 8 and to R 10 is selected to be polyoxyalkylene; and

R 12 and R 13 are monovalent residues independently selected from the group consisting of hydrogen, aliphatics, nitrogen-containing aliphatics, aryl, hetaryl, alkaryl, carbamoyl, amidinyl, guanyl, ureyl, and polyoxyalkylene;

R 14 is a divalent residue selected from alicyclic and/or cyclic, branched or unbranched alkylene, arylene, polyoxyalkylene and combinations thereof;

m is an integer ranging from 1 to 25;

Y is an at least divalent residue selected from the group consisting of

wherein

R 15 is selected from the group consisting of hydrogen, linear and/or cyclic, branched or unbranched alkyl, aryl, aralkyl and polyalkoxylene;

R 16 is an hydrocarbon residue having a valency of the sum of n and o selected from linear and/or cyclic, branched or unbranched alkylene of 1 to 12 carbon atoms, arylene and combinations thereof;

n is an integer ranging from 0 to 10 and o is an integer ranging from 0 to 10 with the proviso that the sum of n and o ranges from 1 to 10;

p is an integer ranging from 2 to 5;

each R 17 is independently selected from each other —(CH 2 ) q — with q being an integer ranging from 1 to 7, —C(O)—, —CH 2 —CH 2 —O—CH 2 —CH 2 —, —CH═CH—CH═CH—, —CH═CH—N═CH—, —CH═CH—N═N—, —CH═CH—CH═N—, —CH═CH—CH═CH—CH═N—, —CH═CH—CH═CH—N═CH—, and —CH═CH—CH═N—CH═CH—

with the proviso that at least one residue of R 12 to R 16 is selected to be polyoxyalkylene.

15. The aqueous acidic copper electroplating bath according to claim 1 characterized in that the concentration of the additive ranges from 1 mg/l to 500 mg/l.

16. A method for deposition of copper onto a substrate comprising the steps

(i) providing a substrate and

(ii) contacting the substrate with an aqueous acidic copper electroplating bath according to claim 1 ,

(iii) applying an electrical current between the substrate and at least one anode,

and thereby depositing copper onto the substrate.

17. The method for deposition of copper onto a substrate according to claim 16 wherein the substrate is selected from the group consisting of printed circuit boards, IC substrates, semiconducting wafers, ceramics and glass substrates.

18. The method for deposition of copper onto a substrate according to claim 17 wherein the copper is deposited into recessed structures selected from the group consisting of trenches, blind micro vias, through holes, through silicon vias and through glass vias.

19. The method for deposition of copper onto a substrate according to claim 16 wherein the copper is deposited into recessed structures selected from the group consisting of trenches, blind micro vias, through holes, through silicon vias and through glass vias.

20. A method for deposition of a metal or metal alloy onto a substrate comprising the steps

providing a substrate,

contacting the substrate with an aqueous acidic metal or metal alloy plating bath comprising at least one source of metal ions and at least one acid, and an additive obtained by a reaction of at least one aminoglycidyl compound comprising at least one amino group which bears at least one glycidyl moiety and at least one second compound selected from ammonia and amine compounds wherein the amine compounds comprise at least one primary or secondary amino group with the proviso that the aminoglycidyl compound contains at least one polyoxyalkylene residue and/or the amine compound contains at least one polyoxyalkylene residue, and

depositing metal or metal alloy onto the substrate.