Stable laundry cleaning composition and method comprising a polyAPTAC-containing polymer
Disclosed herein is a laundry or cleaning composition comprising (i) from about 0.001 wt. % to about 50 wt. % of at least one cationic polymer selected from the group consisting of poly acrylamidopropyl trimethyl ammonium chloride Poly(APTAC), polydiallyl dimethyl ammonium chloride poly(DADMAC), copolymers of polyAPTAC, copolymers of polyDADMAC, terpolymers of polyAPTAC, and/or terpolymers of polyDADMAC; (ii) from about 0.01 wt. % to about 50 wt. % of at least one non-ionic surfactant; (iii) optionally, from about 0.001 wt. % to about 5 wt. % of at least one enzyme; and (iv) optionally, from about 0.01 wt. % to about 25 wt. % of at least one laundry or cleaning additive, wherein said composition is capable of exhibiting color wash fastness or color maintenance.
1. A method of laundering and/or maintaining the appearance of a fabric comprising the steps of:
(i) washing or contacting one or more fabrics or textile articles with a wash solution containing a laundry or cleansing composition at one or more points during the main wash of laundering or cleaning process;
(ii) rinsing said fabrics or textile articles with water; and
(iii) allowing said fabrics or textile articles to air dry naturally or mechanically tumble-drying them, wherein said composition is capable of exhibiting color wash fastness or color maintenance, and wherein the laundry or cleansing composition comprises:
a) from about 0.0010 wt. % to about 50 wt. % of at least one cationic polymer selected from the group consisting of poly acrylamidopropyl trimethyl ammonium chloride (PolyAPTAC), poly(acrylamidepropyltimethylammoniumchloride-behenylmethacrylate-acrylicacid) terpolymer, poly(acrylamidopropyltrimethyl ammonium chloride-stearyl acrylate-acrylic acid) terpolymer, and poly(acrylamidopropyl trimethyl ammonium chloride-stearyl acrylate-acrylamidopropyl methane sulfonic acid) terpolymer; and has a molecular weight of from about 100,000 to about 1,000,000 daltons;
b) from about 0.01 wt. % to about 50 wt. % of at least one non-ionic surfactant which is a linear ethoxylated alcohol having a carbon chain length of C12 to C15;
c) optionally, from about 0.001 wt. % to about 5 wt. % of at least one enzyme; and
d) optionally, from about 0.01 wt. % to about 25 wt. % of at least one laundry or cleaning additive, wherein the composition exhibits color maintenance or color wash fastness of 95% to 99% for 3 wash cycles, measured in accordance with ASTM Method D-4265.
2. The method according to claim 1 , wherein said cationic polymer is present in the range of about 0.001 wt. % to about 0.004 wt. %, or about 0.0015 wt. % to about 0.003 wt. %.
3. The method according to claim 1 , wherein said non-ionic surfactant may further comprise a surfactant selected from the group consisting of additional alcohol ethoxylates, alkyl polyglucosides, alkyl phenol ethoxylates, alkyl alkanolamides, alkyl amine oxides, non-ionic block copolymers, glycerols, glyceryl esters, and mixtures thereof.
4. The method according to claim 1 , wherein said laundry or cleaning additive is compatible with the cationic polymers of claim 1 , and is selected from the group additional surfactants, alkaline builders, chelants, colorants or dyes, hydrotropes or solubilizing agents, foam control agents, dispersants, fillers compounds, functional polymers, stabilizers, rheology modifiers, fluorescent whitening agents or optical brighteners, solvents, fragrance or perfumes, soil release polymers, preservatives, antimicrobials, insect repellents, dust mite repellents, UV absorbers, light management agents, bleaching agents, oxidation catalysts, zeolites, and/or odor suppressing agents.
5. The method according to claim 1 , wherein said enzyme is selected from the group consisting of proteases, amylases, cellulases, oxidases, peroxidases, and/or lipases.
6. The method according to claim 1 , wherein said composition exhibits:
color maintenance or color wash fastness of 97% for 3 wash cycles, measured in accordance with ASTM Method D-4265.
7. The method according to claim 1 , wherein the composition is used for household, industrial and/or commercial laundry operations.
8. The method according to claim 1 , wherein said composition is used in the form of liquid, solid, semisolid, emulsion, powder, dispersion or gel.
9. The method according to claim 1 , wherein the composition is a ready-to-use product, an additive rinse cycle composition, or a dilutable detergent.
10. A method of providing appearance of reduced wrinkles and/or reduced lint of a fabric comprising the steps of:
(i) washing or contacting one or more fabrics or textile articles with wash solution containing a laundry or cleansing composition at one or more points during the main wash of laundering or cleaning process;
(ii) rinsing said fabrics or textile articles with water; and
(iii) allowing said fabrics or textile articles to air dry naturally or mechanically tumble-drying them, wherein said fabric is selected from the group consisting of natural fabric, synthetic fabric, natural non-woven fabric and/or synthetic non-woven fabric, cotton, denim, polyacrylics, polyamides, polyesters, polyolefins, rayons, wool, linen, jute, ramie, hemp, sisal, regenerated cellulosic fibers, leather, and combinations thereof, and wherein the laundry or cleansing composition comprises:
a) from about 0.0010 wt. % to about 50 wt. % of at least one cationic polymer selected from the group consisting of poly acrylamidopropyl trimethyl ammonium chloride (PolyAPTAC), poly(acrylamidepropyltrimethylammoniumchloride-behenylmethacrylate-acrylicacid) terpolymer, poly(acrylamidopropyltrimethyl ammonium chloride-stearyl acrylate-acrylic acid) terpolymer, and poly(acrylamidopropyl trimethyl ammonium chloride-stearyl acrylate-acrylamidopropyl methane sulfonic acid) terpolymer; and has a molecular weight of from about 100,000 to about 1,000,000 daltons;
b) from about 0.01 wt. % to about 50 wt. % of at least one non-ionic surfactant which is a linear ethoxylated alcohol having a carbon chain length of C12 to C15;
c) optionally, from about 0.001 wt. % to about 5 wt. % of at least one enzyme; and
d) optionally, from about 0.01 wt. % to about 25 wt. % of at least one laundry or cleaning additive, wherein the composition exhibits color maintenance or color wash fastness of 95% to 99% for 3 wash cycles, measured in accordance with ASTM Method D-4265.
11. A method of inhibiting transfer of fugitive dyes released during laundering, the method comprising introducing a laundry or cleansing composition to a wash liquor of a laundering machine comprising at least one fabric selected from the group consisting of natural fabric, synthetic fabric, natural non-woven fabric and/or synthetic non-woven fabric, cotton, denim, polyacrylics, polyamides, polyesters, polyolefins, rayons, wool, linen, jute, ramie, hemp, sisal, regenerated cellulosic fibers, leather, and combinations thereof, and wherein the laundry or cleansing composition comprises:
a) from about 0.0010 wt. % to about 50 wt. % of at least one cationic polymer selected from the group consisting of poly acrylamidopropyl trimethyl ammonium chloride (PolyAPTAC), poly(acrylamidepropyltrimethylammoniumchloride-behenylmethacrylate-acrylicacid) terpolymer, poly(acrylamidopropyltrimethyl ammonium chloride-stearyl acrylate-acrylic acid) terpolymer, and poly(acrylamidopropyl trimethyl ammonium chloride-stearyl acrylate-acrylamidopropyl methane sulfonic acid) terpolymer; and has a molecular weight of from about 100,000 to about 1,000,000 daltons;
b) from about 0.01 wt. % to about 50 wt. % of at least one non-ionic surfactant which is a linear ethoxylated alcohol having a carbon chain length of C12 to C15;
c) optionally, from about 0.001 wt. % to about 5 wt. % of at least one enzyme; and
d) optionally, from about 0.01 wt. % to about 25 wt. % of at least one laundry or cleaning additive, wherein the composition exhibits color maintenance or color wash fastness of 95% to 99% for 3 wash cycles, measured in accordance with ASTM Method D-4265.