Quantum dot material, preparation method, and semiconductor device
The present invention provides a QD material, a preparation method, and a semiconductor device. The QD material includes at least one QD structural unit arranged sequentially along a radial direction of the QD material. Each QD structural unit has a gradient alloy composition structure with a changing energy level width along the radial direction or a homogeneous alloy composition structure with a constant energy level width along the radial direction. The disclosed QD material not only achieves higher light-emission efficiency of QD material, but also meets the comprehensive requirements of semiconductor devices and the corresponding display technologies on QD materials. Therefore, the disclosed QD material is a desired QD light-emitting material suitable for semiconductor devices and display technologies.
1. A quantum dot (QD) material, comprising:
at least one QD structural unit arranged sequentially along a radial direction of the QD material, wherein:
each QD structural unit has a gradient alloy composition structure with a changing energy level width along the radial direction or a homogeneous alloy composition structure with a constant energy level width along the radial direction; and
the QD material includes two types of QD structural units; wherein:
one type of QD structural unit has the homogeneous alloy composition structure;
another type of QD structural unit has the gradient alloy composition structure with an energy level width increasing along the radial direction from a center to a surface of the QD material;
an inner part of the QD material includes one or more QD structural units having the homogeneous alloy composition structure; and
an outer part of the QD material includes one or more QD structural units having the gradient alloy composition structure, and along the radial direction, energy levels of adjacent gradient alloy composition structures of the QD structural units are continuous.
2. The QD material according to claim 1 , wherein:
the QD structural unit having the gradient alloy composition structure or the homogeneous alloy composition structure includes Group II elements and Group VI elements.
3. The QD material according to claim 1 , wherein:
the plurality of monatomic layers includes 2-20 monatomic layers, or the at least one unit-cell layer includes 1-10 unit-cell layers.
4. The QD material according to claim 3 , wherein:
each monatomic layer or each unit-cell layer is a smallest structural unit, and an alloy composition of each monatomic layer or each unit-cell layer is fixed; and
each unit-cell layer has a closed unit-cell surface formed through a continuous connection of the unit-cell layers.
5. The QD material according to claim 1 , wherein:
a light-emission peak wavelength of the QD material is in a range of approximately 400 nm to 700 nm.
6. The QD material according to claim 1 , wherein:
a full width at half maximum of a light-emission peak of the QD material is in a range of approximately 12 nm to 80 nm.
7. A method for preparing the QD material according to claim 1 , comprising:
synthesizing a first compound;
synthesizing a second compound on a surface of the first compound, wherein the second compound and the first compound have same elements in different alloy compositions; and
forming the QD material through a cation exchange reaction between the first compound and the second compound, wherein a light-emission peak wavelength of the QD material experiences one or more of a blue-shift, a red-shift, and no-shift.
8. The method for preparing the QD material according to claim 7 , wherein:
a cation precursor of the first compound and/or the second compound includes a zinc precursor, wherein the zinc precursor includes at least one of dimethyl zinc, diethyl zinc, zinc acetate, zinc acetylacetonate, zinc iodide, zinc bromide, zinc chloride, zinc fluoride, zinc carbonate, zinc cyanide, zinc nitrate, zinc oxide, zinc peroxide, zinc perchlorate, zinc sulfate, zinc oleate, and zinc stearate.
9. The method for preparing the QD material according to claim 7 , wherein:
a cation precursor of the first compound and/or the second compound includes a cadmium precursor, wherein the cadmium precursor includes at least one of dimethyl cadmium, diethyl cadmium, cadmium acetate, cadmium acetylacetonate, cadmium iodide, cadmium bromide, cadmium chloride, cadmium fluoride, cadmium carbonate, cadmium nitrate, cadmium oxide, cadmium perchlorate, cadmium phosphate, cadmium sulfate, cadmium oleate, and cadmium stearate.
10. The method for preparing the QD material according to claim 7 , wherein:
an anion precursor of the first compound and/or the second compound includes a selenium precursor, wherein the selenium precursor includes at least one of Se-TOP (selenium-trioctylphosphine), Se-TBP (selenium-tributylphosphine), Se-TPP (selenium-triphenylphosphine), Se-ODE (selenium-1-octadecene), Se-OA (selenium-oleic acid), Se-ODA (selenium-octadecylamine), Se-TOA (selenium-trioctylamine), Se-ODPA (selenium-octadecylphosphonic acid), and Se-OLA (selenium-oleylamine).
11. The method for preparing the QD material according to claim 7 , wherein:
an anion precursor of the first compound and/or the second compound includes a sulfur precursor, wherein the sulfur precursor includes at least one of S-TOP (sulfur-trioctylphosphine), S-TBP (sulfur-tributylphosphine), S-TPP (sulfur-triphenylphosphine), S-ODE (sulfur-1-octadecene), S-OA (sulfur-oleic acid), S-ODA (sulfur-octadecylamine), S-TOA (sulfur-trioctylamine), S-ODPA (sulfur-octadecylphosphonic acid), S-OLA (sulfur-oleylamine), and alkyl thiol.
12. The method for preparing the QD material according to claim 7 , wherein:
an anion precursor of the first compound and/or the second compound includes a tellurium precursor, wherein the tellurium precursor includes at least one of Te-TOP (tellurium-trioctylphosphine), Te-TBP (tellurium-tributylphosphine), Te-TPP (tellurium-triphenylphosphine), Te-ODE (tellurium-1-octadecene), Te-OA (tellurium-oleic acid), Te-ODA (tellurium-octadecylamine), Te-TOA (tellurium-trioctylamine), Te-ODPA (tellurium-octadecylphosphonic acid), and Te-OLA (tellurium-oleylamine).
13. The method for preparing the QD material according to claim 7 , wherein:
the cation exchange reaction between the first compound and the second compound is performed under a heating condition.
14. The method for preparing the QD material according to claim 13 , wherein:
a heating temperature is in a range of approximately 100° C. to 400° C.
15. The method for preparing the QD material according to claim 13 , wherein:
a heating time is in a range of approximately 2 seconds to 24 hours.
16. The method for preparing the QD material according to claim 7 , wherein:
a molar feed ratio of a cationic precursor to an anion precursor used for forming the first compound is in a range of approximately 100:1 to 1:50.
17. The method for preparing the QD material according to claim 7 , wherein:
a molar feed ratio of a cationic precursor to an anion precursor used for forming the second compound is in a range of approximately 100:1 to 1:50.
18. A semiconductor device including the QD material according to claim 1 , wherein:
the semiconductor device is one of an electroluminescent device, a photoluminescent device, a solar cell, a display device, a photoelectric detector, a biological probe, and nonlinear optical device.