Quantum dot composite material, preparation method, and semiconductor device
The present invention provides a quantum dot (QD) composite material, a preparation method, and a semiconductor device. The method includes synthesizing a first compound at a predetermined position, synthesizing a second compound on the surface of the first compound, the second compound and the first compound having a same alloy composition or having different alloy compositions, and forming the QD composite material through a cation exchange reaction between the first compound and the second compound. The light-emission peak wavelength of the QD composite material experiences one or more of a blue-shift, a red-shift, and no-shift. The method uses the QD successive ionic layer adsorption and reaction (SILAR) synthesis method to precisely control layer-by-layer QD growth and the QD one-step synthesis method to form a composition-gradient transition shell. The QD composite materials prepared by the disclosed method not only achieve higher light-emitting efficiency, but also meet the comprehensive requirements of semiconductor devices and corresponding display technologies on QD composite materials.
1. A method for preparing a quantum dot (QD) composite material, comprising:
synthesizing a first compound;
synthesizing a second compound on a surface of the first compound, wherein the second compound and the first compound have same elements in different alloy compositions; and
forming the QD composite material through a cation exchange reaction between the first compound and the second compound, wherein a light-emission peak wavelength of the QD composite material experiences one or more of: alternating blue-shifts and red-shifts, discontinuous blue-shifts, and discontinuous red-shifts.
2. The method for preparing the QD composite material according to claim 1 , wherein:
a cation precursor of the first compound and/or the second compound includes a zinc precursor, wherein the zinc precursor includes at least one of dimethyl zinc, diethyl zinc, zinc acetate, zinc acetylacetonate, zinc iodide, zinc bromide, zinc chloride, zinc fluoride, zinc carbonate, zinc cyanide, zinc nitrate, zinc oxide, zinc peroxide, zinc perchlorate, and zinc sulfate.
3. The method for preparing the QD composite material according to claim 1 , wherein:
a cation precursor of the first compound and/or the second compound includes a cadmium precursor, wherein the cadmium precursor includes at least one of dimethyl cadmium, diethyl cadmium, cadmium acetate, cadmium acetylacetonate, cadmium iodide, cadmium bromide, cadmium chloride, cadmium fluoride, cadmium carbonate, cadmium nitrate, cadmium oxide, cadmium perchlorate, cadmium phosphate, and cadmium sulfate.
4. The method for preparing the QD composite material according to claim 1 , wherein:
an anion precursor of the first compound and/or the second compound includes a selenium precursor, wherein the selenium precursor includes at least one of Se-TOP (selenium-trioctylphosphine), Se-TBP (selenium-tributylphosphine), Se-TPP (selenium-triphenylphosphine), Se-ODE (selenium-1-octadecene), Se-OA (selenium-oleic acid), Se-ODA (selenium-octadecylamine), Se-TOA (selenium-trioctylamine), Se-ODPA (selenium-octadecylphosphonic acid), and Se-OLA (selenium-oleylamine).
5. The method for preparing the QD composite material according to claim 1 , wherein:
an anion precursor of the first compound and/or the second compound includes a sulfur precursor, wherein the sulfur precursor includes at least one of S-TOP (sulfur-trioctylphosphine), S-TBP (sulfur-tributylphosphine), S-TPP (sulfur-triphenylphosphine), S-ODE (sulfur-1-octadecene), S-OA (sulfur-oleic acid), S-ODA (sulfur-octadecylamine), S-TOA (sulfur-trioctylamine), S-ODPA (sulfur-octadecylphosphonic acid), S-OLA (sulfur-oleylamine), and alkyl thiol.
6. The method for preparing the QD composite material according to claim 1 , wherein:
an anion precursor of the first compound and/or the second compound includes a tellurium precursor, wherein the tellurium precursor includes at least one of Te-TOP (tellurium-trioctylphosphine), Te-TBP (tellurium-tributylphosphine), Te-TPP (tellurium-triphenylphosphine), Te-ODE (tellurium-1-octadecene), Te-OA (tellurium-oleic acid), Te-ODA (tellurium-octadecylamine), Te-TOA (tellurium-trioctylamine), Te-ODPA (tellurium-octadecylphosphonic acid), and Te-OLA (tellurium-oleylamine).
7. The method for preparing the QD composite material according to claim 1 , wherein:
the cation exchange reaction between the first compound and the second compound is performed under a heating condition.
8. The method for preparing the QD composite material according to claim 7 , wherein:
a beating temperature is in a range of approximately 100° C. to 400° C.
9. The method for preparing the QD composite material according to claim 7 , wherein:
a heating time is in a range of approximately 2 seconds to 24 hours.
10. The method for preparing the QD composite material according to claim 1 , wherein:
a molar feed ratio of a cationic precursor to an anion precursor used for forming the first compound is in a range of approximately 100:1 to 1:50.
11. The method for preparing the QD composite material according to claim 1 , wherein:
a molar feed ratio of a cationic precursor to an anion precursor used for forming the second compound is in a range of approximately 100:1 to 1:50.
12. The quantum dot (QD) composite material prepared by the method according to claim 1 .
13. A semiconductor device including the QD composite material according to claim 12 , wherein:
the semiconductor device is one of an electroluminescent device, a photoluminescent device, a solar cell, a display device, a photoelectric detector, a biological probe, and a nonlinear optical device.