Composition for adhesive layer of non-aqueous secondary battery, adhesive layer for non-aqueous secondary battery, adhesive layer-equipped separator for non-aqueous secondary battery, adhesive layer-equipped electrode for non-aqueous secondary battery, non-aqueous secondary battery, and method for producing same
Provided is a composition for an adhesive layer of a non-aqueous secondary battery allowing formation of an adhesive layer that can achieve both high process adhesiveness and high blocking resistance in battery members such as an electrode and a separator. The presently disclosed composition for an adhesive layer of a non-aqueous secondary battery includes a particulate polymer A that has a glass-transition temperature of no higher than 20° C. and a volume-average particle diameter of at least 100 nm and less than 450 nm, and a particulate polymer B that has a glass-transition temperature of at least 30° C. and less than 60° C. and a volume-average particle diameter larger than the volume-average particle diameter of the particulate polymer A.
1. A composition for an adhesive layer of a non-aqueous secondary battery, the composition comprising:
a particulate polymer A and a particulate polymer B, wherein
the particulate polymer A has a glass-transition temperature of no higher than 20° C. and a volume-average particle diameter of at least 100 nm and less than 450 nm,
the particulate polymer B has a glass-transition temperature of at least 30° C. and no higher than 55° C. and a volume-average particle diameter larger than the volume-average particle diameter of the particulate polymer A, and
the volume-average particle diameter of the particulate polymer B is at least 400 nm and no greater than 900 nm.
2. The composition for an adhesive layer of a non-aqueous secondary battery of claim 1 , wherein a content of the particulate polymer A is at least 20 parts by mass and no greater than 70 parts by mass per 100 parts by mass of the particulate polymer B.
3. The composition for an adhesive layer of a non-aqueous secondary battery of claim 1 , wherein a degree of swelling in electrolysis solution of the particulate polymer A is at least a factor of 1 and no greater than a factor of 10.
4. The composition for an adhesive layer of a non-aqueous secondary battery of claim 1 , wherein a degree of swelling in electrolysis solution of the particulate polymer B is at least a factor of 6.
5. An adhesive layer for a non-aqueous secondary battery, the adhesive layer being formed by using the composition for an adhesive layer of a non-aqueous secondary battery of claim 1 .
6. An adhesive layer-equipped separator for a non-aqueous secondary battery, the adhesive layer-equipped separator comprising a separator and the adhesive layer for a non-aqueous secondary battery of claim 5 provided on at least one surface of the separator.
7. An adhesive layer-equipped electrode for a non-aqueous secondary battery, the adhesive layer-equipped electrode comprising an electrode and the adhesive layer for a non-aqueous secondary battery of claim 5 provided on at least one surface of the electrode.
8. A non-aqueous secondary battery comprising:
a positive electrode, a negative electrode, a separator, and the adhesive layer for a non-aqueous secondary battery of claim 5 , wherein
the adhesive layer for a non-aqueous secondary battery is arranged between the positive electrode and the separator and/or between the negative electrode and the separator.
9. A method for producing a non-aqueous secondary battery, the method comprising forming an adhesive layer for a non-aqueous secondary battery on at least one of a positive electrode, a negative electrode, and a separator using the composition for an adhesive layer of a non-aqueous secondary battery of claim 1 .