Evaporative chilling systems and methods using a selective transfer membrane

1. A compact membrane evaporative chiller for cooling a process fluid comprising:

a first selective transfer membrane;

a heat exchanger adjacent a first side of the first selective transfer membrane, the heat exchanger configured to provide an inflow of uncooled process fluid into the heat exchanger and an outflow of cooled process fluid out of the heat exchanger;

a working fluid compartment between the first selective transfer membrane and the heat exchanger configured to physically isolate a working fluid from the process fluid, wherein the working fluid compartment is in direct physical contact with both the first selective transfer membrane and the heat exchanger such that the working fluid compartment provides at least a film of the working fluid that is simultaneously in contact with both the first side of the first selective transfer membrane and a first side of the heat exchanger; and

a vapor chamber adjacent a second side of the first selective transfer membrane configured to maintain a partial pressure of the working fluid in the chamber less than a partial pressure of the same fluid in the working fluid compartment and to collect vapor of the working fluid transferred through the first selective transfer membrane and evaporated into the vapor chamber, wherein the compact membrane evaporative chiller is configured for transfer of heat from the heat exchanger to the working fluid in the working fluid compartment.

2. The chiller of claim 1 , wherein the working fluid in the vapor chamber is maintained at an absolute pressure less than atmospheric pressure.

3. The chiller of claim 1 , wherein the heat exchanger comprises metal, plastic, ceramic, or a composite surface.

4. The chiller of 1 , wherein the working fluid compartment comprises a mesh or a porous foam capable of being filled with the working fluid.

5. The chiller of claim 4 , wherein the mesh or porous foam comprises metal, plastic, ceramic, composite, or combinations thereof.

6. The chiller of claim 1 , further comprising a compressor to compress the vapor of the working fluid transferred through the first selective transfer membrane and evaporated into the vapor chamber such that the pressurized vapor is cooled by a second working fluid stream in a condenser that provides condensed working fluid in a liquid state.

7. The chiller of claim 6 , wherein the chiller further comprises a pathway configured to return condensed working fluid to the working fluid compartment.

8. The chiller of claim 6 , wherein the compressor is a mechanical vapor compressor or an electrochemical vapor compressor.

9. The chiller of claim 6 , wherein the condenser is a sensible condenser.

10. The chiller of claim 8 , wherein the sensible condenser is a selected from the group consisting of a fluid cooling condenser, a radiative cooling condenser, a conductive cooling condenser, a thermoelectric cooling condenser, and combinations thereof.

11. The chiller of claim 8 , wherein the sensible condenser is an air cooled or water cooled sensible condenser.

12. The chiller claim 6 , further comprising a metering pump configured to optionally divert a portion of the condensed working fluid from the return pathway to a desuperheat spray nozzle configured to spray atomized condensed working fluid into the vapor stream between the compressor and the condenser to create additional evaporative cooling.

13. The chiller of claim 6 , further comprising a roughing pump connected to the condenser through an isolation valve and configured to optionally remove non-condensable gases.

14. The chiller of claim 6 , wherein the pathway to return the condensed working fluid to the working fluid compartment is configured to maintain the working fluid compartment at a pressure less than or equal to the pressure inside the condenser, which allows the condensate to return to the working fluid compartment under the influence of gravity and/or pressure differentials.

15. The chiller of claim 6 , wherein the compressor is an electrochemical compressor, and the system further comprises a pressure regulation device configured to accept a mixture of working fluid vapor and electrochemical carrier gas or gases from the return condensed working fluid pathway at a first pressure, and configured to reduce that pressure to a second, lower pressure such that the condensed working fluid returns to the working fluid compartment of the chiller without compromising the partial pressure of the working fluid in the vapor chamber.

16. The chiller of claim 1 , wherein the working fluid compartment further comprises an inlet for adding additional working fluid and/or a drain for draining working fluid and any dissolved solids.

17. The chiller of claim 6 , wherein the chiller is configured such that condensed working fluid is removed from the chiller system and additional working fluid is provided to the working fluid compartment, allowing the generation of a purified working fluid that has been distilled through the first selective transfer membrane, while other species and impurities have been removed from the working fluid compartment by draining a portion of the concentrated working fluid.

18. The chiller of claim 6 , wherein the condenser comprises a second selective transfer membrane, and the compressed vapor is presented to a first surface of the second selective transfer membrane, and an exhaust fluid is presented to a second surface of the second selective transfer membrane, wherein a partial pressure of the working fluid in the exhaust fluid is lower than the partial pressure of the working fluid at the first surface of the second selective transfer membrane, causing the transport of working fluid through the second selective transfer membrane.

19. The chiller of claim 1 , wherein the working fluid further comprises at least one additional component that does not readily transfer through the first selective transfer membrane, and the working fluid and the at least one additional component are in the form of a mixture, suspension, emulsion, slurry, colloid, or combination thereof.