Low-foaming warewash detergent containing mixed cationic / nonionic surfactant system for enhanced oily soil removal
The invention includes ware detergent compositions which provides superior cleaning and removal of oily and fatty soils, without the production of excessive foam. According to the invention applicants have discovered that use of a quaternary cationic surfactant in combination with a nonionic low foaming surfactant can provide oily soil removal from ware that is superior to traditional warewash detergent formulations. Compositions for alkaline, preferably solid, warewash detergents are disclosed, as well as their use in dish machines and methods of manufacture.
1. A warewash alkaline detergent composition comprising:
from about 40 wt. % to about 90 wt. % of an alkalinity source;
from about 1 wt. % to about 20 wt. % of a blended surfactant component comprising a nonionic low foaming surfactant represented by the formula: RO-(PO) x (EO) y (PO) x H, wherein R is C8-18 alkyl, PO is propylene oxide; EO is ethylene oxide; x is 0-8 and y is 1-20, and a cationic quaternary surfactant represented by the formula:
wherein R represents a C8-C18 alkyl or alkenyl; R 1 and R 2 are C1-C4 alkyl groups; n is 10-25; and x is an anion selected from a halide or methyl sulfate, said surfactants in a ratio of greater than 1:1;
from about 0.1 wt. % to about 10 wt. % of a defoaming nonionic surfactant represented by the formula: RO-(PO) x (EO) y (PO) z , wherein R is C8-18 alkyl; PO is propylene oxide; EO is ethylene oxide; x is 0-5; y is 10-20; and z is 10-20;
with the remainder comprising one or more of a metal protector, water conditioning agent or polymer, an enzyme, a chelant, a bleaching agent, a solidification aid, and/or a carrier.
2. The composition of claim 1 , wherein said alkalinity source includes an alkali metal carbonate.
3. The composition of claim 1 , wherein said metal protector is a polyacrylic or polymaleic acid polymer or an alkali metal silicate and/or said water conditioning agent or polymer is a phosphonate, polycarboxylate or combinations thereof.
4. The composition of claim 1 , wherein said chelant is one or more of MGDA, GLDA, or EDTA.
5. The composition of claim 1 , wherein said cationic quaternary surfactant is present in an amount of from about 0.1 wt. % to about 5 wt. % and wherein said nonionic low foaming surfactant is present from about 0.5 wt. % to about 10 wt. %.
6. The composition of claim 1 , wherein said nonionic low foaming surfactant is an alcohol ethoxylate surfactant.
7. The composition of claim 1 , wherein said cationic quaternary surfactant is a quaternary coco alkyl amine ethoxylate and wherein said nonionic low foaming surfactant is an alcohol ethoxylate surfactant.
8. The composition of claim 1 , wherein said nonionic low foaming surfactant is an alcohol ethoxylate present in an amount of from about 1 wt. % to about 5 wt.
9. The composition of claim 1 , wherein said ratio of said nonionic low foaming surfactant to said cationic quaternary surfactant is less than 10:1.
10. The composition of claim 1 , wherein said composition is a pressed solid, extruded solid, or cast solid.
11. The composition of claim 10 , wherein said solid composition is diluted to form a use composition and has a pH of at least about 9.
12. A solid alkaline detergent composition comprising:
from about 40 wt. % to about 90 wt. % of an alkali metal carbonate alkalinity source;
from about 1 wt. % to about 7.5 wt. % of a blended surfactant component including a nonionic low foaming surfactant represented by the formula: RO-(PO) x (EO) y (PO) x H, wherein R is C8-18 alkyl, PO is propylene oxide; EO is ethylene oxide; x is 0-8 and y is 1-20, and a cationic quaternary surfactant represented by the formula:
wherein R represents a C8-C18 alkyl or alkenyl; R 1 and R 2 are C1-C4 alkyl groups; n is 10-25; and x is an anion selected from a halide or methyl sulfate, said surfactants in a ratio of greater than 1:1 and less than 5:1;
from about 0.5 wt. % to about 5 wt. % of a defoaming nonionic surfactant represented by the formula: RO-(PO) x (EO) y (PO) z , wherein R is C8-18 alkyl; PO is propylene oxide; EO is ethylene oxide; x is 0-5; y is 10-20; and z is 10-20;
from about 1 wt. % to about 30 wt. % of at least one chelant;
from about 0.01 to about 25 wt. % of a metal protector and/or water conditioning agent or polymer; and
from about 0.1 wt. % to about 5 wt. % of an enzyme, with any remainder comprising water, or additional functional components.
13. The composition of claim 12 , wherein said metal protector comprises one or more of a maleic acid copolymer, an acrylic acid polymer, an alkali metal silicate, or combinations thereof, wherein said water conditioning agent or polymer is a phosphonate, polycarboxylate or combinations thereof, wherein said alkalinity includes an ash based carbonate, wherein said chelant is one or more of MGDA, GLDA, or EDTA, and wherein said nonionic low foaming surfactant is an alcohol ethoxylate surfactant.
14. The composition of claim 12 , wherein said cationic quaternary surfactant is a quaternary coco alkyl amine ethoxylate and is present in an amount of from about 0.1 wt. % to about 5 wt. %, and wherein said nonionic low foaming surfactant is an alcohol ethoxylate surfactant and is present in an amount of from about 1 wt. % to about 5 wt. %.
15. The composition of claim 12 , wherein said nonionic low foaming surfactant is an alcohol ethoxylate.
16. The composition of claim 12 , wherein said defoaming nonionic surfactant is present in an amount of from about 1 wt. % to about 5 wt. %.
17. The composition of claim 12 , wherein said ratio of nonionic low foaming surfactant to cationic quaternary surfactant is from about 3:1 to about 5:1.
18. The composition of claim 12 , wherein the composition is a solid and when diluted to form a use composition has a pH of at least about 9.
19. A method of cleaning oily and fatty soils from ware comprising:
applying the detergent composition of claim 1 to a ware surface in a dish machine; and
there after rinsing said ware, wherein said detergent provides improved oily soil removal and acceptable foaming for dish machine performance.