Process for producing dispersion containing electroconductive polymer
A method for producing a conductive polymer-containing dispersion, the method including a polymerization step of subjecting a monomer that is to be a constitutional unit of a conjugated conductive polymer to a polymerization reaction in a mixed solution containing the monomer, a polyanion, and a dispersion medium to produce a polymerized product; and a dispersion treatment step of performing a dispersion treatment on a reaction solution obtained in the polymerization step to prepare a dispersion of the polymerized product, wherein a dispersion medium is added one or more times at any point in time from after the polymerization step to during the dispersion treatment step to make a mass concentration (B) of the polymerized product in the dispersion after the dispersion treatment step lower than a mass concentration (A) of the polymerized product in the reaction solution.
1. A method for producing a conductive polymer-containing dispersion, the method comprising:
a polymerization step of subjecting a monomer that is to be a constitutional unit of a conjugated conductive polymer to a polymerization reaction in a mixed solution comprising the monomer, a polyanion, and a dispersion medium to produce a polymerized product; and
a dispersion treatment step of performing a dispersion treatment on a reaction solution obtained in the polymerization step to prepare a dispersion of the polymerized product, wherein
the dispersion medium is added one or more times during the dispersion treatment step to make a mass concentration (B) of the polymerized product in the dispersion after the dispersion treatment step lower than a mass concentration (A) of the polymerized product in the reaction solution,
the dispersion medium is added after a time course of at least 10% of a time required for the dispersion treatment from a beginning of the dispersion treatment, and
the mass concentration (B) is not more than 0.95 times a mass concentration (C) of the polymerized product in the dispersion before the beginning of the dispersion treatment.
2. The method for producing a conductive polymer-containing dispersion according to claim 1 , wherein the mass concentration (B) is not more than 0.95 times the mass concentration (A).
3. The method for producing a conductive polymer-containing dispersion according to claim 1 , wherein the mixed solution comprises seed particles that have been converted into colloid protected by the polyanion.
4. The method for producing a conductive polymer-containing dispersion according to claim 3 , wherein the seed particles are a polymer comprising an ethylenically unsaturated monomer as a constitutional unit.
5. The method for producing a conductive polymer-containing dispersion according to claim 1 , wherein at least any of the polyanion and seed particles that have been converted into colloid protected by the polyanion is further added in the polymerization step.
6. The method for producing a conductive polymer-containing dispersion according to claim 1 , further comprising a monomer dispersion preparation step of adding the monomer and the polyanion to the dispersion medium to prepare a dispersion of the monomer before the polymerization step.
7. The method for producing a conductive polymer-containing dispersion according to claim 6 , wherein the monomer dispersion comprises seed particles that have been converted into colloid protected by the polyanion.
8. The method for producing a conductive polymer-containing dispersion according to claim 6 , wherein the monomer is dispersed by ultrasonic irradiation in the monomer dispersion preparation step.
9. The method for producing a conductive polymer-containing dispersion according to claim 1 , wherein the polymerized product is dispersed by ultrasonic irradiation in at least any of the polymerization step and the dispersion treatment step.
10. The method for producing a conductive polymer-containing dispersion according to claim 1 , wherein
the dispersion medium in the mixed solution comprises water, and
the polymerization reaction is carried out with one or more oxidizing agents selected from the group consisting of peroxodisulfuric acid and a salt thereof.
11. The method for producing a conductive polymer-containing dispersion according to claim 1 , wherein the polyanion is a polymer having a sulfonic acid group.
12. The method for producing a conductive polymer-containing dispersion according to claim 1 , wherein a total amount of the polyanion used is an amount such that an anionic group in the polyanion is 0.25 to 30 mol per 1 mol of the monomer.
13. The method for producing a conductive polymer-containing dispersion according to claim 1 , wherein the monomer comprises one or more selected from the group consisting of an optionally substituted pyrrole, an optionally substituted aniline, and an optionally substituted thiophene.
14. The method for producing a conductive polymer-containing dispersion according to claim 1 , wherein the monomer comprises a compound represented by formula (1) below:
wherein R 1 and R 2 each independently represent any of a hydrogen atom, a hydroxyl group, an optionally substituted alkyl group having 1 to 18 carbon atoms, an optionally substituted alkoxy group having 1 to 18 carbon atoms, or an optionally substituted alkylthio group having 1 to 18 carbon atoms; or R 1 and R 2 are bonded to each other to form an optionally substituted alicyclic ring having 3 to 10 carbon atoms, an optionally substituted aromatic ring having 6 to 10 carbon atoms, an optionally substituted oxygen atom-containing heterocyclic ring having 2 to 10 carbon atoms, an optionally substituted sulfur atom-containing heterocyclic ring having 2 to 10 carbon atoms, or an optionally substituted sulfur atom and oxygen atom-containing heterocyclic ring having 2 to 10 carbon atoms.