LIQUID CRYSTAL POLYMER ARTICLE FOR HIGH TEMPERATURE SEMICONDUCTOR PROCESS
A Front-Opening Unified Pod (FOUP), and more particularly an injection molded liquid crystal polymer article used in making the FOUP which both positive CTE value and shrinkage values and similar expansion and shrinkage of the article in both the MD and TD directions.
1 . An injection molded liquid crystal polymer article comprising:
a thermotropic polyester;
a filler,
wherein the CTE value of the article in both the MD and TD directions are both positive, and within 12 ppm/° C. of each other, and the shrinkage values in both MD and TD are both positive and within 0.65% of each other.
2 . The article of claim 1 , wherein the filler comprises 10-80 wt % of the article.
3 . The article of claim 1 , wherein the filler comprises 20-30 wt % of the article.
4 . The article of claim 1 where the filler is graphite.
5 . The article of claim 4 , wherein the graphite is in the form of crystalline flakes, amorphous fine flakes, lump graphite, or highly ordered pyrolytic graphite flakes.
6 . The article of claim 1 , wherein the graphite filler comprises platelet shape particles.
7 . The article of claim 6 . wherein the ratio of the length to width of the shaped particles is less than 5.
8 . The article of claim 1 , wherein the filler is graphite and has a BET surface area less than 20 m 2 /g.
9 . The article of claim 1 , wherein the electrical conductivity of the filler is greater than 1×10 4 S/m and less than 1×10 6 S/cm.
10 . The article of claim 1 , wherein the filler is a graphite, and wherein the mean particle size of the graphite filler is in the range of 1-20 microns.
11 . The article of claim 4 , wherein the particle size of the graphite is in the range of 1-6 microns.
12 . The article of claim 1 , wherein the filler has impurity elemental levels of Aluminum, Calcium, Copper, Chromium, Cobalt, Nickel, Molybdenum, Silicon, Antimony, Arsenic, Lead, Titanium, Iron and Vanadium each less than 40 ppm, with the aggregate impurities level of all impurity elements being less than 75 ppm.
13 . The article of claim 1 wherein the thermotropic polyester is derived from hydroquinone(HQ), terephthalic acid(TA), 2,6-naphthalenedicarboxylic acid (NDA), or 4-hydrobenzoic acid (HBA).
14 . The article of claim 13 , wherein the thermotropic polyester is derived from 4-hydrobenzoic acid (HBA).
15 . The article of claim 15 , wherein the article has a nominal thickness of about 3 mm.
16 . The article of claim 1 , wherein the ESD resistivity of the article is in the range of 10 6 -10 10 Ohms/square.
17 . The article of claim 1 , wherein the article has a heat deflection temperature greater than 260° C.
18 . The article of claim 1 , wherein the article has a heat deflection temperature greater than 200° C.
19 . The article of claim 1 , wherein the article has CTE values, which are between 10 and 35 ppm/° C. in both MD and TD directions.
20 . The article of claim 1 , wherein the article has average shrinkage in both the MD and TD direction of less than 0.6%, and shrinkage in MD direction is positive.
21 . The article of claim 1 where the article has trace metal contamination levels which are no greater than 500 ppb in the leachate when analyzed via SEMI F48-0600 test.
22 . A Front-Opening Unified Pod comprised of a material described in claim 1 .