Matched-type electromagnetic wave absorber
A sheet-shaped matched-type electromagnetic wave absorber can obtain electromagnetic wave absorption performance with a relatively small thickness but has a problem that particularly a dimensional change in an electromagnetic wave absorption layer (resin composition layer) has a large influence on the electromagnetic wave absorption performance when being exposed to a high temperature. By laminating a resin composition layer in which a filler with an aspect ratio of 5 or more and a filler with an aspect ratio of less than 5 are dispersed and fixed with an electromagnetic wave reflection layer in a cured product of a resin composition containing an acrylic polymerizable resin and a polymerization initiator, it is possible to provide a matched-type electromagnetic wave absorber having high heat resistant dimensional stability and high electromagnetic wave absorption performance.
1. A matched-type electromagnetic wave absorber comprising:
a laminated structure including at least a resin composition layer and an electromagnetic wave reflection layer, wherein
in the resin composition layer, a component (C): filler with an aspect ratio of 5 or more and having an average length of 0.5 to 50 μm and a component (D): filler with an aspect ratio of less than 5 are dispersed and fixed in a cured product of a resin composition containing a component (A): acrylic polymerizable resin.
2. The matched-type electromagnetic wave absorber according to claim 1 , wherein
a volume ratio represented by [the component (C)+the component (D)]/resin composition layer is 0.1 to 0.5.
3. The matched-type electromagnetic wave absorber according to claim 1 , wherein
the component (C): filler with an aspect ratio of 5 or more is a conductive filler, and
the component (D): filler with an aspect ratio of less than 5 is aluminum hydroxide and/or magnesium hydroxide.
4. The matched-type electromagnetic wave absorber according to claim 3 , wherein
the conductive filler is conductive titanium oxide.
5. The matched-type electromagnetic wave absorber according to claim 1 , wherein
the component (A): acrylic polymerizable resin contains any one or more selected from an epoxy acrylate, a urethane acrylate, an ester acrylate, a copolymerized acrylate, a butadiene acrylate, a silicone acrylate, and an amino resin acrylate each having a vinyl group.
6. The matched-type electromagnetic wave absorber according to claim 1 , wherein
the resin composition layer further comprises a component (B): polymerization initiator, and the component (B): polymerization initiator is an organic peroxide.
7. The matched-type electromagnetic wave absorber according to claim 1 , further comprising
an adhesive layer between the electromagnetic wave reflection layer and the resin composition layer.
8. The matched-type electromagnetic wave absorber according to claim 1 , wherein
the component (D) is a material different from the component (C).
9. The matched-type electromagnetic wave absorber according to claim 2 , wherein
the component (C): filler with an aspect ratio of 5 or more is a conductive filler, and
the component (D): filler with an aspect ratio of less than 5 is aluminum hydroxide and/or magnesium hydroxide.
10. The matched-type electromagnetic wave absorber according to claim 2 , wherein
the component (A): acrylic polymerizable resin contains any one or more selected from an epoxy acrylate, a urethane acrylate, an ester acrylate, a copolymerized acrylate, a butadiene acrylate, a silicone acrylate, and an amino resin acrylate each having a vinyl group.
11. The matched-type electromagnetic wave absorber according to claim 3 , wherein
the component (A): acrylic polymerizable resin contains any one or more selected from an epoxy acrylate, a urethane acrylate, an ester acrylate, a copolymerized acrylate, a butadiene acrylate, a silicone acrylate, and an amino resin acrylate each having a vinyl group.
12. The matched-type electromagnetic wave absorber according to claim 4 , wherein
the component (A): acrylic polymerizable resin contains any one or more selected from an epoxy acrylate, a urethane acrylate, an ester acrylate, a copolymerized acrylate, a butadiene acrylate, a silicone acrylate, and an amino resin acrylate each having a vinyl group.
13. The matched-type electromagnetic wave absorber according to claim 2 , wherein
the component (D) is a material different from the component (C).
14. The matched-type electromagnetic wave absorber according to claim 3 , wherein
the component (D) is a material different from the component (C).
15. The matched-type electromagnetic wave absorber according to claim 5 , wherein
the component (D) is a material different from the component (C).
16. The matched-type electromagnetic wave absorber according to claim 6 , wherein
the component (D) is a material different from the component (C).
17. The matched-type electromagnetic wave absorber according to claim 7 , wherein
the component (D) is a material different from the component (C).
18. The matched-type electromagnetic wave absorber according to claim 1 , wherein
the component (D) is particles of which an average particle diameter is ranged from 0.01 to 10 μm.