IP Library Granted Patent US 10,836,677
Granted Patent B2
US 10,836,677 · App. 15/780,931 · Granted Nov 17, 2020

Ultra-light mineral foam

Inventors: Christine Chaumilliat (Saint-Quentin-Fallavier, FR); Christian Blachier (Saint-Quentin-Fallavier, FR); Nicalas Perez (Saint-Quentin-Fallavier, FR); Lilian Ferreint (Saint-Quentin-Fallavier, FR)
Assignee: HOLCIM TECHNOLOGY LTD
C04B28/04C04B22/148C04B38/10C04B40/0028C04B2111/00465C04B2111/40C04B2111/52C04B2235/3418
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Quick Facts
Patent No.
US 10,836,677
App. No.
15/780,931
Granted
Nov 17, 2020
Kind
B2
Abstract

A process for the production of a mineral foam includes (i) separately preparing a slurry of cement and an aqueous foam, wherein the cement slurry includes water and Portland cement; (ii) contacting the slurry of cement with the aqueous foam to obtain a slurry of foamed cement; (iii) adding an aluminum salt source before or during step (ii); and (iv) casting the slurry of foamed cement and leave it to set.

Claims (28)

1. A process for the production of a mineral foam comprising the following steps:

(i) separately preparing a slurry of cement that does not contain an aluminum salt source as an accelerator and an aqueous foam, wherein the cement slurry comprises water and Portland cement;

(ii) contacting the slurry of cement with the aqueous foam to obtain a slurry of foamed cement;

(iii) adding an aluminum salt source as an accelerator during step (ii);

(iv) casting the slurry of foamed cement and leave it to set, wherein the mineral foam is substantially free of particles with a diameter D50<2 μm.

2. The process according to claim 1 , wherein aluminum sulphate is used as said aluminum salt source.

3. The process according to claim 2 , wherein aluminum sulphate is added in an amount of 0.15-5% in dry aluminum sulphate by weight of cement.

4. The process according to claim 1 , wherein the D50 of bubbles of the aqueous foam prepared in step (i) is less than or equal to 400 μm.

5. The process according to claim 1 , wherein step (ii) comprises the introduction of the slurry of cement and the aqueous foam into a static mixer to obtain the slurry of foamed cement.

6. The process according to claim 1 , wherein a water/cement ratio (wt/wt ratio) of 0.28-0.35, is used in step (i).

7. The process according to claim 1 , wherein the Portland cement is a cement of the type CEM I, CEM II, CEM III, CEM IV or CEM V.

8. The process according to claim 1 , wherein the Portland cement has a specific surface (Blaine) of 3000-10000 cm 2 /g.

9. The process according to claim 1 , wherein the cement slurry comprises a water reducer.

10. The process according to claim 1 , wherein the slurry of foamed cement comprises at least one supplementary mineral component.

11. The process according to claim 2 , wherein the aluminum sulphate is in the form of an aluminum sulphate solution.

12. The process according to claim 2 , wherein aluminum sulphate is added in an amount of 0.25-3% in dry aluminum sulphate by weight of cement.

13. The process according to claim 12 , wherein aluminum sulphate is added in an amount of 0.5-2.5% in dry aluminum sulphate by weight of cement.

14. The process according to claim 8 , wherein the Portland cement has a specific surface (Blaine) of 3500-6000 cm 2 /g.

15. The process according to claim 9 , wherein the water reducer is a plasticiser or super-plasticiser.

16. The process according to claim 10 , wherein the at least one supplementary mineral component is a supplementary cementitious material.

17. The process according to claim 10 , wherein the at least one supplementary mineral component is selected from calcium carbonate, silica, ground glass, solid or hollow glass beads, glass granules, expanded glass powders, silica aerogels, silica fume, granulated blast furnace slags, ground sedimentary siliceous sands, fly ash or pozzolanic materials or mixtures thereof.

18. A method comprising utilizing an aluminum salt source, being aluminum sulphate in the form of an aluminum sulphate solution, for enhancing the mechanical stability and/or reducing the collapse of a slurry of foamed cement, said slurry of foamed cement being obtained by

(i) separately preparing a slurry of cement that does not contain an aluminum salt source as an accelerator and an aqueous foam, wherein the cement slurry comprises water and Portland cement;

(ii) contacting the slurry of cement with the aqueous foam to obtain a slurry of foamed cement; and

(iii) adding an aluminum salt source as an accelerator during step (ii).

19. The method according to claim 18 , wherein aluminum sulphate is added in an amount of 0.15-5% in dry aluminum sulphate by weight of cement.

20. The method according to claim 19 , wherein aluminum sulphate is added in an amount of 0.25-3% in dry aluminum sulphate by weight of cement.

21. The method according to claim 20 , wherein aluminum sulphate is added in an amount of 0.5-2.5% in dry aluminum sulphate by weight of cement.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 14, 2025
From: HOLCIM TECHNOLOGY LTD
To: AMRIZE TECHNOLOGY SWITZERLAND LLC
Reel/Frame 073207/0820 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 16, 2018
From: CHAUMILLIAT, CHRISTINE; BLACHIER, CHRISTIAN; PEREZ, NICALAS; FERREINT, LILIAN
To: HOLCIM TECHNOLOGY LTD
Reel/Frame 046360/0868 →
Priority Claims (1)
EP 15306942 · Dec 4, 2015 · regional
Continuity (1)
Related Publication 20180354854A1 · Dec 13, 2018