Electrolytes, current collectors, and binders for rechargeable metal-ion batteries
A metal-ion battery includes: 1) an anode including a metal; 2) a cathode; and 3) an ionic liquid electrolyte disposed between the anode and the cathode, wherein the ionic liquid electrolyte corresponds to a mixture of a metal halide and an organic compound.
1. A metal-ion battery comprising:
an anode including a metal;
a cathode; and
an ionic liquid electrolyte disposed between the anode and the cathode, wherein the ionic liquid electrolyte comprises a mixture of AlCl 3 and urea,
wherein a molar ratio of AlCl 3 :urea in the mixture is in a range of about 1.1 to about 1.7.
2. The metal-ion battery of claim 1 , wherein a battery operation temperature is about −30° C. to about 60° C.
3. The metal-ion battery of claim 1 , wherein the cathode includes a hydrophilic polymer binder and a cathode active material blended with the hydrophilic polymer binder.
4. The metal-ion battery of claim 3 , wherein the cathode active material is selected from graphite particles, natural graphite flakes, sulfur particles, selenium particles, black phosphorous particles, and black phosphorous films.
5. The metal-ion battery of claim 3 , wherein the cathode active material includes natural graphite flakes having sizes in a range of about 20 μm to about 300 μm.
6. The metal-ion battery of claim 3 , wherein the hydrophilic polymer binder includes one or more polymers selected from polyacrylic acid, polyvinyl alcohol, cellulose, cellulose derivatives, alginate, styrene-butadiene rubber, poly(3,4-ethylenedioxythiophene), and polystyrene sulfonate.
7. The metal-ion battery of claim 1 , wherein the cathode includes a metal substrate as a current collector, and the metal substrate is optionally applied with a protective coating.
8. The metal-ion battery of claim 7 , wherein the metal substrate is a nickel substrate, and the protective coating is a coating of a carbonaceous material, a conducting polymer, or tungsten.
9. The metal-ion battery of claim 7 , wherein the metal substrate is a tungsten substrate.
10. The metal-ion battery of claim 1 , wherein the cathode includes a fibrous, carbonaceous substrate as a current collector.
11. The metal-ion battery of claim 10 , wherein the fibrous, carbonaceous substrate is carbon fiber paper, carbon fiber cloth, graphite fiber paper, or graphite fiber cloth.
12. A metal-ion battery comprising:
an anode including a metal;
a cathode; and
an ionic liquid electrolyte disposed between the anode and the cathode, wherein the ionic liquid electrolyte comprises a mixture of a metal halide and an organic compound,
wherein the cathode includes a hydrophilic polymer binder and a cathode active material blended with the hydrophilic polymer binder, and
wherein the cathode active material is selected from graphite particles, natural graphite flakes, sulfur particles, selenium particles, black phosphorous particles, and black phosphorous films.
13. The metal-ion battery of claim 12 , wherein the metal is aluminum, and the metal halide is an aluminum halide.
14. The metal-ion battery of claim 13 , wherein the aluminum halide is AlCl 3 , and the organic compound is an amide.
15. The metal-ion battery of claim 13 , wherein the aluminum halide is AlCl 3 , and the organic compound incudes cations selected from N-(n-butyl) pyridinium, benzyltrimethylammonium, 1,2-dimethyl-3-propylimidazolium, trihexyltetradecylphosphonium, and 1-butyl-1-methyl-pyrrolidinium, and anions selected from tetrafluoroborate, tri-fluoromethanesulfonate, and bis(trifluoromethanesulfonyl)imide.
16. The metal-ion battery of claim 13 , wherein the aluminum halide is AlCl 3 , and the organic compound is selected from 4-propylpyridine, acetamide, trimethylphenylammonium chloride, and 1-ethyl-3-methylimidazolium chloride.
17. The metal-ion battery of claim 13 , wherein the ionic liquid electrolyte includes an aluminum halide cation that is datively bonded to the organic compound.
18. The metal-ion battery of claim 12 , wherein the cathode includes a metal substrate as a current collector, and the metal substrate is optionally applied with a protective coating.
19. The metal-ion battery of claim 18 , wherein the metal substrate is a nickel substrate, and the protective coating is a coating of a carbonaceous material, a conducting polymer, or tungsten.
20. The metal-ion battery of claim 18 , wherein the metal substrate is a tungsten substrate.
21. The metal-ion battery of claim 12 , wherein the cathode includes a fibrous, carbonaceous substrate as a current collector.
22. The metal-ion battery of claim 21 , wherein the fibrous, carbonaceous substrate is carbon fiber paper, carbon fiber cloth, graphite fiber paper, or graphite fiber cloth.