IP Library Granted Patent US 10,858,500
Granted Patent B2
US 10,858,500 · App. 15/781,162 · Granted Dec 8, 2020

Carbon nanotube / graphene composites

Inventors: Jinhu Chen (Cambridge, GB); Krzysztof Kazimierz Koziol (Cambridge, GB); Catharina Paukner (Cambridge, GB)
Assignee: FGV Cambridge Nanosystems Limited
C08K7/24C08J5/10C08K3/04C08K3/041C08K3/042H01B1/04H01B1/24B82Y30/00C08K2201/001C08K2201/003C08K2201/004C08K2201/011
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Quick Facts
Patent No.
US 10,858,500
App. No.
15/781,162
Granted
Dec 8, 2020
Kind
B2
Abstract

An electrically conductive composite material includes carbon nanotubes and graphene nanoplatelets within a polymer matrix. The carbon nanotubes have an average length greater than 10 μm. The graphene nanoplatelets form in the range of 0.005 wt. % to 0.06 wt. % of the composite material. Also provided is a mixture having such a composition, an article comprising such a composite material, and a composite production method.

Claims (33)

1. An electrically conductive composite material, comprising:

carbon nanotubes and graphene nanoplatelets within a polymer matrix; wherein the polymer matrix is an epoxy matrix;

wherein a majority of the carbon nanotubes have lengths in the range of 20 μm to 150 μm;

wherein the carbon nanotubes form of the order of 0.02 wt. % of the composite material; and

wherein the graphene nanoplatelets form in the range of 0.02.wt % to 0.06 wt. % of the composite material.

2. The electrically conductive composite material according to claim 1 , wherein the graphene nanoplatelets form of the order of 0.04 wt. % of the composite material.

3. The electrically conductive composite material according to claim 1 , wherein the majority of carbon nanotubes have a length greater than 30 μm.

4. The electrically conductive composite material according to claim 3 , wherein the majority of carbon nanotubes have a length greater than 40 μm.

5. The electrically conductive composite material according to claim 4 , wherein the majority of carbon nanotubes have a length greater than 50 μm.

6. The electrically conductive composite material according to claim 1 , wherein the majority of graphene nanoplatelets have a diameter in the range of 0.25 μm to 1 μm.

7. The electrically conductive composite material according to claim 6 , wherein the graphene nanoplatelets have an average diameter of the order of 0.5 μm.

8. The electrically conductive composite material according to claim 1 , being isotropic.

9. The electrically conductive composite material according to claim 1 , comprised in an article.

10. An electrically-conductive composite material, comprising:

carbon nanotubes and graphene nanoplatelets within a polymer matrix; wherein the polymer matrix is an epoxy matrix;

wherein a majority of the carbon nanotubes have lengths in the range of 20 μm to 150 μm;

wherein the carbon nanotubes form in the range of 0.2 wt. % to 0.3 wt. % of the composite material; and

wherein the graphene nanoplatelets form in the range of 0.005 wt. % to 0.04 wt. % of the composite material.

11. The electrically conductive composite material according to claim 10 , wherein the graphene nanoplatelets form of the order of 0.02 wt. % of the composite material.

12. The electrically conductive composite material according to claim 11 , wherein the carbon nanotubes form of the order of 0.3 wt. % of the composite material.

13. The electrically conductive composite material according to claim 10 , comprised in an article.

14. A composite production method, comprising:

preparing, by a high shear mixing process, a mixture comprising carbon nanotubes and graphene nanoplatelets within a resin; wherein the resin is an epoxy resin;

wherein a majority of the carbon nanotubes have lengths in the range of 20 μm to 150 μm;

wherein the carbon nanotubes form of the order of 0.02 wt. % of the composite material; and

wherein the graphene nanoplatelets form in the range of 0.02 wt. % to 0.06 wt. % of the mixture.

15. The method according to claim 14 , wherein the high shear mixing process is carried out at around 4500 rpm for about 20 minutes.

16. The method according to claim 14 , further comprising:

adding a hardener to the resin;

subjecting the mixture to a further high shear mixing process that is carried out at around 4500 rpm for about 5 minutes; and

subjecting the mixture to a stirring process that is carried out at around 500 rpm for about 5 minutes.

17. The method according to claim 14 , further comprising subjecting the mixture to a degassing process that is carried out at about 60° C. for about 1 hour, under negative pressure.

18. The method according to claim 14 , further comprising transferring the mixture to a mold and curing the resin.

Assignments (4)
CHANGE OF NAME Recorded Aug 6, 2021
From: CAMBRIDGE NANOSYSTEMS LIMITED
To: LEVIDIAN NANOSYSTEMS LIMITED
Reel/Frame 057099/0641 →
CHANGE OF NAME Recorded Aug 6, 2021
From: FGV CAMBRIDGE NANOSYSTEMS LIMITED
To: CAMBRIDGE NANOSYSTEMS LIMITED
Reel/Frame 057099/0646 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 4, 2018
From: CHEN, JINHU; KOZIOL, KRZYSZTOF KAZIMIERZ
To: FGV CAMBRIDGE NANOSYSTEMS LIMITED
Reel/Frame 046290/0869 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 4, 2018
From: PAUKNER, CATHARINA
To: FGV CAMBRIDGE NANOSYSTEMS LIMITED
Reel/Frame 046290/0897 →
Priority Claims (1)
GB 1521392.9 · Dec 3, 2015 · national
Continuity (1)
Related Publication 20180346689A1 · Dec 6, 2018
Cited By (5)
US 12,195,338 US 12,214,420 US 12,261,023 US 12,311,447 US 12,406,829