Ternary borides and borohydrides for hydrogen storage and method of synthesis
View Patent ↗A method and a system is provided for obtaining solid-state hydrogen storage and release in materials with at least theoretical loaded hydrogen densities of 11 wt % or greater that can deliver hydrogen and be recharged at moderate temperatures enabling incorporation into hydrogen storage systems suitable for transportation applications. These materials comprise ternary boride materials comprising certain light transition metals and alkaline or alkaline earth metals, and ideally have no or very little phase separation. A process of making these materials is also provided.
1. A process for making a mixed-metal ternary boride/borohydride hydrogen storage material, comprising the steps of:
mixing an M a metal source, an M b metal source, and a borane adduct in hydrocarbon solvent;
wherein M a is one or more metals selected from the group consisting of Li, Na, K, Mg, and Ca, and M b is one or more metals selected from Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zn;
removing excess solvent and liquid by-products by drying and applying a vacuum.
2. The process of claim 1 , wherein the borane adduct in hydrocarbon solvent is borane-dimethyl sulfide adduct in heptane.
3. The process of claim 1 , wherein the vacuum, measured at 20° C., is 0.001 to 0.1 atm.
4. The process of claim 1 , wherein the M a metal source is an Mg alkyl and the M b metal source is an Mn alkyl or Co alkyl.
5. The process of claim 1 , wherein the material is essentially free of phase segregation.
6. The process of claim 1 , wherein the mixing step is performed with heating up to a maximum of 120° C.
7. The process of claim 1 , further comprising dissolving a catalyst or dopant in the solvent.
8. A process for making a mixed-metal ternary boride/borohydride hydrogen storage material, comprising the steps of:
reacting an M a metal source, an M b metal source, and a borane adduct, forming a mixed-metal borohydride;
wherein M a is one or more metals selected from the group consisting of Li, Na, K, Mg, and Ca, and M b is one or more metals selected from Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zn;
dehydrogenating the mixed metal borohydride into a ternary boride phase.
9. The process of claim 8 , wherein the hydrogen storage is essentially free of phase segregation.
10. The process of claim 8 , wherein M a is Mg and M b is Mn or Co.