Process for depolymerizing coal to co-produce pitch and naphthalene
A method of depolymerizing coal includes preparing a high temperature depolymerizing medium consisting of heavy hydrocarbon oils and mixing it with coal to form a mixture, performing an optional first distillation at a temperature below 250° C. to recover naphthalene, heating the mixture to a temperature between 350° C. and 450° C. to create a digested coal, centrifuging the digested coal to remove ash and obtain a centrate, and distillation of the centrate into separate fractions. The high temperature depolymerizing medium may be a heavy hydrocarbon with a hydrogen to carbon (H/C) ratio higher than 7.0% and may include liquids chosen from the group consisting of: coal tar distillate, decant oil, anthracene oil, and heavy aromatic oils. The high temperature depolymerizing medium may be blended with an oil, preferably with H/C ratio higher than 10.0%, such as soybean oil, other biomass derived oil, lignin, petroleum oil, pyrolysis oil such that the overall hydrogen-to-carbon mass ratio in a digestion reactor is over 7.0% for the mixture of depolymerizing medium and coal. The depolymerized coal is an aromatic liquid that can itself be, either wholly or in part, a depolymerizing medium so that the process can be repeated.
1. A method of depolymerizing coal, comprising:
providing a high temperature depolymerizing medium comprising heavy hydrocarbon oils;
mixing the high temperature depolymerizing medium with coal to form a mixture, wherein the high temperature depolymerizing medium is a heavy hydrocarbon with H/C ratio higher than 0.070;
performing a first distillation of the mixture to recover naphthalene;
following the first distillation, heating the mixture to create a digested coal slurry; and
centrifuging the slurry to produce a centrate liquid,
wherein the high temperature depolymerizing medium further comprises an oil, with H/C ratio higher than 0.100, chosen from the group consisting of: soybean oil, pine tar, aromatic petroleum distillate, biomass gasification tar, biomass pyrolysis tar, and oils where the overall hydrogen-to-carbon mass ratio in a digestion reactor is over 0.070 for the mixture of the high temperature depolymerizing medium and the coal.
2. The method of claim 1 , wherein the high temperature depolymerizing medium further comprises liquids chosen from the group consisting of: coal tar distillate, decant oil, anthracene oil, and heavy aromatic oils.
3. The method of claim 1 , wherein the coal is dried via air drying or heating to above 100° C. prior to exposing the coal to the depolymerizing medium.
4. The method of claim 1 , in which the centrate liquid is used as the depolymerizing medium in subsequent executions of the method.
5. The method of claim 1 , wherein the mixture comprises a ratio of 1 part coal to a range of at least 1.5 parts to 2.5 parts of depolymerizing medium.
6. The method of claim 1 , wherein centrifuging is done at a temperature of at least 100° C., or above the softening temperature of the liquid constituents of the coal digest.
7. The method of claim 1 , wherein the coal is a low rank non-coking coal with ash below 5% by mass, the method further comprising distilling the centrate liquid formed from the mixture of the low rank non-coking coal to produce a pitch.
8. The method of claim 1 , wherein the coal is selected such that it has less than 6.0% ash.
9. The method of claim 1 , further comprising, distilling the centrate liquid to separate it into different fractions according to boiling point.
10. The method of claim 1 , wherein said solid carbon coke is selected from the group consisting of: a metallurgical grade coke, a foundry grade coke, and a feedstock for other furnace grade carbon.
11. The method of claim 1 , further comprising, prior to centrifuging, filtering the digested coal slurry, so that the produced a centrate liquid has an ash content less than 0.5% by mass.
12. The method of claim 11 , wherein the ash content is less than 0.2% by mass.
13. The method of claim 1 , wherein the high temperature depolymerizing medium further comprises an oil selected from the group consisting of: a biomass-derived oil, a lignin, a petroleum oil, a pyrolysis oil, and an oil from vegetable matter.
14. The method of claim 1 , further comprising, distilling the centrate liquid to produce a pitch residue with hydrogen content between 4.0% and 5.0%, and with a softening temperature of about 110° C. and ash level less than 0.5% by mass.
15. The method of claim 1 , wherein heating the mixture is to a temperature of at least 350° C. to create the digested coal slurry.
16. The method of claim 1 , wherein the centrate liquid has an ash content of less than 0.5% by mass.
17. A method of depolymerizing coal, comprising:
providing a high temperature depolymerizing medium comprising heavy hydrocarbon oils;
mixing the high temperature depolymerizing medium with coal to form a mixture, wherein the high temperature depolymerizing medium is a heavy hydrocarbon with an H/C ratio higher than 0.070 and the coal is a low rank non-coking coal with ash below 5% by mass;
performing a first distillation of the mixture to recover naphthalene;
following the first distillation, heating the mixture to create a digested coal slurry;
centrifuging the slurry to produce a centrate liquid;
distilling the centrate liquid to produce a pitch; and
converting the pitch to a solid carbon coke, in an oxygen-depleted environment at above 600° C., and co-producing thermally liberated volatile molecules.
18. A method of depolymerizing coal, comprising:
providing a high temperature depolymerizing medium comprising heavy hydrocarbon oils;
mixing the high temperature depolymerizing medium with coal to form a mixture, wherein the high temperature depolymerizing medium is a heavy hydrocarbon with an H/C ratio higher than 0.070 and less than 0.70, and the coal is selected such that its H/C ratio is greater than 0.75, wherein the mixture of the high temperature depolymerizing medium and the coal has an overall H/C ratio greater than 0.70 on an ash-free basis;
performing a first distillation of the mixture to recover naphthalene;
following the first distillation, heating the mixture to create a digested coal slurry; and
centrifuging the slurry to produce a centrate liquid.
19. The method of claim 18 , wherein a bio-oil is not present, and hydrogenation is not used to enhance the hydrogen content of the depolymerizing medium.