IP Library Granted Patent US 10,513,601
Granted Patent B2
US 10,513,601 · App. 15/815,815 · Granted Dec 24, 2019

Ethylene-propylene copolymers with amorphous and semi-crystalline components

Inventors: Xin Chen (Humble, TX); Sudhin Datta (Houston, TX); Rohan A. Hule (Houston, TX)
Assignee: ExxonMobil Chemical Patents Inc.
C08L23/16C08L23/0815C08L23/142C08L2205/06C08L2207/04C08L2207/14
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 10,513,601
App. No.
15/815,815
Granted
Dec 24, 2019
Kind
B2
Abstract

This invention relates to a polyolefin composition with (a) 80 to 90 wt % of an amorphous ethylene-propylene copolymer having either no crystallinity or crystallinity derived from ethylene, having about 30 wt % or more units derived from ethylene; (b) 5 to 15 wt % of a semi-crystalline ethylene-propylene copolymer having substantial crystallinity derived from ethylene and having 70 wt % or more units derived from ethylene; and (c) 1 to 5 wt % of a propylene-based elastomer having within the range from 5 to 25 wt % ethylene derived units and having a melting point temperature of less than 110° C. and a Mw/Mn within the range from 2.0 to 4.0.

Claims (22)

1. A polyolefin composition comprising:

a. about 75 wt % to about 90 wt % based on the total weight of the composition of an amorphous ethylene-propylene copolymer having either no crystallinity or crystallinity derived from ethylene, having about 30 wt % or more units derived from ethylene;

b. about 5 wt % to about 25 wt % based on the total weight of the composition of a semi-crystalline ethylene-propylene copolymer having substantial crystallinity derived from ethylene and having about 70 wt % or more units derived from ethylene; and

c. about 1 wt % to about 5 wt % based on the total weight of the composition of a propylene-based elastomer having within the range from 5 to 25 wt % ethylene derived units and having a melting point temperature of less than 110° C. and a Mw/Mn within the range from 2.0 to 4.0.

2. The composition of claim 1 , wherein composition is a reactor blend of the amorphous ethylene-propylene copolymer, the semi-crystalline ethylene-propylene copolymer, and the propylene-based elastomer.

3. The composition of claim 1 , wherein the composition is a physical blend of the amorphous ethylene-propylene copolymer, the semi-crystalline ethylene-propylene copolymer, and the propylene-based elastomer.

4. The composition of claim 1 , wherein the composition has greater about 70 wt % to about 80 wt % units derived from ethylene.

5. The composition of claim 1 , wherein the composition is substantially free of diene units.

6. The composition of claim 1 , wherein the propylene-based elastomer has a melting point temperature within the range of from 80° C. to 110° C.

7. The composition of claim 1 , wherein the composition has a total ethylene content within the range of 6 to 25 wt %.

8. The composition of claim 1 , wherein the amorphous ethylene-propylene copolymer has a melt flow rate of about 0.01 g/10 min to about 1 g/10 min.

9. The composition of claim 1 , wherein the semi-crystalline ethylene-propylene copolymer has a melt flow rate of about 0.1 g/10 min to about 15 g/10 min.

10. The composition of claim 1 , wherein the amorphous ethylene-propylene copolymer has about 35 wt % to about 55 wt % of units derived from ethylene.

11. The composition of claim 1 , wherein the semi-crystalline ethylene-propylene copolymer has about 70 wt % to about 80 wt % of units derived from ethylene.

12. An automotive component made from the composition of claim 1 .

13. A polyolefin composition comprising:

a. about 80 wt % to about 90 wt % based on the total weight of the composition of an amorphous ethylene-propylene copolymer having either no crystallinity or crystallinity derived from ethylene, having from about 35 wt % to about 55 wt % units derived from ethylene;

b. about 5 wt % to about 15 wt % based on the total weight of the composition of a semi-crystalline ethylene-propylene copolymer having substantial having substantial crystallinity derived from ethylene, having from about 70 wt % to about 80 wt % units derived from ethylene; and

c. about 1.5 wt % to about 3.5 wt % based on the total weight of the composition of a propylene-based elastomer having within the range from 6 to 20 wt % ethylene derived units and having a melting point temperature of less than 110° C., a melt flow rate of about 0.1 g/10 min to about 3 g/10 min, and a Mw/Mn within the range from 2.0 to 4.0.

14. The composition of claim 13 , wherein the amorphous ethylene-propylene copolymer has a melt flow rate of about 0.01 g/10 min to about 1 g/10 min.

15. The composition of claim 13 , wherein the semi-crystalline ethylene-propylene copolymer has a melt flow rate of about 0.1 g/10 min to about 15 g/10 min.

16. An automotive component made from the composition of claim 13 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 6, 2018
From: CHEN, XIN; DATTA, SUDHIN; HULE, ROHAN A.
To: EXXONMOBIL CHEMICAL PATENTS INC.
Reel/Frame 045113/0239 →
Continuity (2)
Provisional Application 62442659 · Jan 5, 2017
Related Publication 20180186986A1 · Jul 5, 2018
Cited By (2)
US 12,259,083 US 12,291,813