Fiber with elemental additive(s) and method of making
A multi-composition fiber is provided including a primary fiber material and an elemental additive material deposited on grain boundaries between adjacent crystalline domains of the primary fiber material. A method of making a multi-composition fiber is also provided, which includes providing a precursor laden environment, and promoting fiber growth using laser heating. The precursor laden environment includes a primary precursor material and an elemental precursor material.
1. A multi-composition fiber comprising a primary fiber material and an elemental additive material, said elemental additive material having too large an atom size to fit within a single crystalline domain within a crystalline structure of the fiber, and being deposited on grain boundaries between adjacent crystalline domains of the primary fiber material to present an energy barrier to atomic diffusion through the grain boundaries and to increase creep resistance by slowing down grain growth between the adjacent crystalline domains of the primary fiber material.
2. The multi-composition fiber of claim 1 , wherein the primary fiber material is a refractory-grade, inorganic primary fiber material.
3. The multi-composition fiber of claim 1 , wherein the primary fiber material is selected from a group consisting of silicon carbide, boron carbide, silicon nitride, zirconium carbide, hafnium diboride, hafnium carbide, tantalum carbide, niobium carbide, tantalum diboride, zirconium diboride, tungsten diboride, hafnium nitride, tantalum nitride, zirconium nitride, and combinations thereof.
4. The multi-composition fiber of claim 1 , wherein the elemental additive material is selected from a group consisting of hafnium, tantalum, niobium, yttrium, lanthanum, cerium, zirconium, molybdenum, tungsten, and combinations thereof.
5. The multi-composition fiber of claim 1 , wherein the multi-composition fiber has a substantially non-uniform diameter.
6. A multi-composition fiber comprising a primary fiber material and an elemental additive material, said elemental additive material having too large an atom size to fit within a single crystalline domain within a crystalline structure of the fiber, and being deposited on grain boundaries between adjacent crystalline domains of the primary fiber material to present an energy barrier to atomic diffusion through the grain boundaries and to increase creep resistance by slowing down grain growth between the adjacent crystalline domains of the primary fiber material:
the primary fiber material being selected from a group consisting of silicon carbide, boron carbide, silicon nitride, zirconium carbide, hafnium diboride, hafnium carbide, tantalum carbide, niobium carbide, tantalum diboride, zirconium diboride, tungsten diboride, hafnium nitride, tantalum nitride, zirconium nitride, and combinations thereof; and the elemental additive material being selected from a group consisting of hafnium, tantalum, niobium, yttrium, lanthanum, cerium, zirconium, molybdenum, tungsten, and combinations thereof.
7. The multi-composition fiber of claim 6 , wherein the multi-composition fiber has a substantially non-uniform diameter.