Method for dyeing golf balls and dyed golf balls
A golf ball of a first color is dyed to a second color with an anionic or nonionic disperse dye. Either or both of a pigmented coating layer or an optional clear coating layer on the pigmented coating layer comprises a member selected from the group consisting of polyurethanes, polyureas, polyamides, and combinations thereof, which can be dyed by the anionic or nonionic disperse dye.
1. A method of dyeing an article from a first color to a different color, comprising:
providing an article comprising a coating layer of a first color, the coating layer including a polyurethane; and
partially or fully immersing the article in an aqueous dye solution for a time sufficient to dye the coating layer to a second color different from the first color; wherein the aqueous dye solution consists essentially of an anionic dye, a quaternary ammonium compound selected from soluble tetrabutylammonium compounds and soluble tetrahexylammonium compounds, water, and from about 1% by volume to about 50% by volume of a water-soluble organic solvent selected from the group consisting of methanol, ethanol, n-propanol, acetone, methyl ethyl ketone, butyl acetate, and combinations thereof.
2. The method according to claim 1 , wherein a portion less than all of the coating layer of the article is dyed.
3. The method according to claim 1 , wherein the coating layer of the article is a clear coating layer.
4. The method according to claim 1 , wherein the coating layer of the article is a pigmented coating layer.
5. The method according to claim 1 , wherein the polyurethane is a polyester-polyurethane or a polyether-polyurethane.
6. The method according to claim 1 , wherein the polyurethane is a thermoplastic polyurethane.
7. The method according to claim 1 , wherein the polyurethane is a polyurethane elastomer.
8. The method according to claim 1 , wherein the polyurethane is a thermoplastic polyurethane elastomer.
9. The method according to claim 1 , wherein the polyurethane is a thermoplastic polyester-polyurethane elastomer or a thermoplastic polyether-polyurethane elastomer.
10. The method according to claim 1 , wherein the aqueous dye solution includes the soluble tetrabutylammonium compounds, and the soluble tetrabutylammonium compounds include a member selected from tetrabutylammonium bromide and tetrabutylammonium chloride.
11. The method according to claim 1 , wherein the aqueous dye solution includes from about 0.1 to about 5 equivalents of the quaternary ammonium compound per equivalent of the anionic dye.
12. The method according to claim 1 , wherein the aqueous dye solution includes from about 0.001 g/L to about 5.0 g/L of the anionic dye.
13. The method according to claim 12 , wherein the aqueous dye solution includes from about 0.01 g/L to about 2.0 g/L of the anionic dye.
14. The method according to claim 1 , wherein the article is a compression molded article, a thermoformed article, an injection molded article, a reaction injection molded article, a liquid injection molded article, a cast article, or a vacuum formed article.
15. The method according to claim 1 , wherein the article is a fluid-filled article.
16. The method according to claim 15 , wherein the fluid is a gas.
17. The method according to claim 14 , wherein a core of the article is a thermoformed core comprising a thermoplastic polyurethane, and the coating layer is an outermost layer of the core.
18. The method according to claim 1 , wherein the coating layer is applied by lamination.
19. The method according to claim 1 , wherein, during the immersing, a temperature of the aqueous dye solution is from about 40° C. to about 70° C.
20. The method according to claim 1 , wherein the article is immersed in the aqueous dye solution for up to 15 minutes.