Sintered alloy and manufacturing method thereof
View Patent ↗A sintered alloy includes, in percentage by mass, Cr: 10.37 to 39.73, Ni: 5.10 to 24.89, Si: 0.14 to 2.52, Cu: 1.0 to 10.0, P: 0.1 to 1.5, C: 0.18 to 3.20 and the balance of Fe plus unavoidable impurities; a phase A containing precipitated metallic carbide with an average particle diameter of 10 to 50 μm; and a phase B containing precipitated metallic carbide with an average particle diameter of 10 μm or less, wherein the phase A is randomly dispersed in the phase B and the average particle diameter DA of the precipitated metallic carbide in the phase A is larger than the average particle diameter DB of the precipitated metallic carbide of the phase B.
1. A method for manufacturing a sintered alloy, comprising the steps of:
preparing an iron alloy powder A consisting of, in percentage by mass, Cr: 25 to 45, Ni: 5 to 15, Si: 1.0 to 3.0, C: 0.5 to 4.0 and a balance of Fe plus unavoidable impurities;
preparing an iron alloy powder B consisting of, in percentage by mass, Cr: 12 to 25, Ni: 5 to 15 and a balance of Fe plus unavoidable impurities;
preparing an iron-phosphorus powder consisting of, in percentage by mass, P:10 to 30 and the balance of Fe plus unavoidable impurities or P: 5 to 25 and a balance of Cu plus unavoidable impurities, a nickel powder, a copper powder or a copper alloy powder, and graphite powder;
forming a raw material powder, consisting of, in percentage by mass, Cr: 10.37 to 39.73, Ni: 5.10 to 24.89, Si: 0.14 to 2.52, Cu: 1.0 to 10.0, P: 0.1 to 1.5, C: 0.18 to 3.20 and a balance of Fe plus unavoidable impurities by mixing the iron alloy powder A with the iron alloy powder B so that a ratio of the iron alloy powder A to the total of the iron alloy powder A and the iron alloy powder B is within a range of 20 to 80 mass %, and adding the iron-phosphorus powder, the nickel powder, the copper powder or copper alloy powder, and the graphite powder;
pressing the raw material powder to obtain a compact; and sintering the compact.
2. The manufacturing method as set forth in claim 1 , wherein a maximum particle diameter of the iron alloy powder A is set within a range of 300 μm or less, which corresponds to a powder passing a sieve with 50 mesh.
3. The manufacturing method as set forth in claim 1 , wherein a maximum particle diameter of the nickel powder is set within a range of 74 μm or less, which corresponds to a powder passing a sieve with 200 mesh.
4. The manufacturing method as set forth in claim 1 , wherein the copper alloy powder is a copper-nickel alloy powder.
5. The manufacturing method as set forth in claim 1 , further comprising a step of adding 5 mass % or less of at least one selected from the group consisting of Mo, V, W, Nb and Ti to either or both of the iron alloy powder A and the iron alloy powder B.
6. The manufacturing method as set forth in claim 1 ,
wherein a sintering temperature at the sintering is set within a range of 1000 to 1200° C.