Nanopatch graphene composite
View Patent ↗Disclosed is a nanopatch graphene composite, which includes graphene including a defect and a nanopatch positioned on the defect, and is configured such that a nanopatch is formed through a self-assembling process on the surface of graphene, thus improving the mechanical properties and durability of the graphene composite. Also, a flexible organic transistor, including the nanopatch graphene composite of the invention, is transparent and has high mechanical durability, thus exhibiting device stability, and the molecular alignment of the organic semiconductor layer growing on the nanopatch graphene composite is induced so as to become favorable for charge injection, thereby increasing the performance of the device.
1. A nanopatch graphene composite, comprising:
a graphene including a defect; and
a nanopatch disposed on the defect,
wherein the defect is at least one selected from the group consisting of a grain boundary, a dot defect, a line defect, cracking, folding, and wrinkling, and
the nanopatch includes a self-assembled monolayer (SAM).
2. The nanopatch graphene composite of claim 1 , wherein the self-assembled monolayer is formed by self-assembling, on the defect, a compound represented by Chemical Formula 1 below:
in Chemical Formula 1,
R 1 is a C3 to C30 alkyl group,
R 2 and R 3 , which are identical to or different from each other, are independently a hydrogen atom or a C1 to C6 alkyl group, and
R 4 is a C1 to C6 alkyl group.
3. The nanopatch graphene composite of claim 2 , wherein the compound represented by Chemical Formula 1 is octadecyltrimethoxysilane (OTS).
4. The nanopatch graphene composite of claim 1 , wherein the nanopatch suppresses or delays fracture of the graphene growing on the defect upon transforming the graphene.
5. The nanopatch graphene composite of claim 1 , wherein the graphene is at least one selected from the group consisting of single-layer graphene, double-layer graphene and multilayer graphene.
6. An organic transistor, comprising:
a flexible substrate;
a semiconductor layer on the flexible substrate; and
a gate electrode, a source electrode and a drain electrode,
wherein at least one selected from the group consisting of the gate electrode, the source electrode and the drain electrode includes the nanopatch graphene composite of claim 1 .
7. The organic transistor of claim 6 , wherein the flexible substrate is at least one selected from the group consisting of polydimethylsiloxane, polyimide, polyethylene terephthalate, polyethylene naphthalate, polypropylene, polyethylene, polyamide and fiberglass-reinforced plastic.
8. A flexible strain sensor, comprising:
a flexible substrate;
an active layer formed on the flexible substrate and including the nanopatch graphene composite of claim 1 ; and
an electrode electrically connected to the active layer.
9. A method of manufacturing a nanopatch graphene composite, comprising:
(a) providing graphene including a defect;
(b) oxidizing the graphene to form a functional group containing an oxygen atom on the defect, thus obtaining surface-modified graphene; and
(c) bonding a self-assembled monolayer to the functional group, thus obtaining the nanopatch graphene composite.
10. The method of claim 9 , wherein, in step (c), the self-assembled monolayer is formed by self-assembling a compound represented by Chemical Formula 1 below:
in Chemical Formula 1,
R 1 is a C3 to C30 alkyl group,
R 2 and R 3 , which are identical to or different from each other, are independently a hydrogen atom or a C1 to C6 alkyl group, and
R 4 is a C1 to C6 alkyl group.
11. The method of claim 9 , wherein the oxidizing is selectively carried out on the defect of the graphene.
12. The method of claim 11 , wherein the oxidizing is performed using UV/ozone.