Compound for organic electric element, organic electric element comprising the same and electronic device thereof

1. A compound of Formula 1 below:

wherein,

1) A ring is C 10 aryl group,

2) B ring is selected from the group consisting of the following formulas B-1 to B-16:

in formulas B-1 to B-16, “*” indicates the position to be condensed with pyrazine comprising two Ns,

3) W 1 and W 2 are each independently a single bond, S or O,

4) V is N or C,

5) X is O or S,

6) a is an integer of 0 to 6, b and c are each an integer of 0 to 4, d is an integer of 0 to 11,

7) R 1 , R 2 , R 3 and R 4 are the same or different from each other, and are each independently selected from the group consisting of hydrogen, deuterium, halogen, a cyano group, a nitro group, a C 6 -C 60 aryl group, a fluorenyl group, a C 2 -C 60 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring, a C 1 -C 50 alkyl group, a C 2 -C 20 alkenyl group, a C 2 -C 20 alkynyl group, a C 1 -C 30 alkoxyl group, a C 6 -C 30 aryloxyl group and -L′-N(R a )(R b ),

or when a, b and c are 2 or more, R 1 , R 2 and R 3 are each in plural and are the same or different, and a plurity of R 1 , a plurity of R 2 , or a plurity of R 3 may be bonded to each other to form a ring,

8) L′ is selected from the group consisting of a single bond, a C 6 -C 60 arylene group, a fluorenylene group, a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring, and a C 2 -C 60 heterocyclic group, and R a and R b are each independently selected from the group consisting of a C 6 -C 60 aryl group, a fluorenyl group, a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring, and a C 2 -C 60 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P,

9) L 1 is each independently selected from the group consisting of a single bond, a C 6 -C 60 arylene group, a fluorenylene group, a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring, and a C 2 -C 60 heterocyclic group and

the aryl group, fluorenyl group, arylene group, heterocyclic group, fused ring group, alkyl group, alkenyl group, alkoxyl group, and aryloxy group may be each optionally further substituted with one or more substituents selected from the group consisting of deuterium, halogen, a silane group substituted or unsubstituted with a C 1 -C 20 alkyl group or a C 6 -C 20 aryl group, a siloxane group, a boron group, a germanium group, a cyano group, a nitro group, -L′-N(R a )(R b ), a C 1 -C 20 alkylthio group, a C 1 -C 20 alkoxyl group, a C 1 -C 20 alkyl group, a C 2 -C 20 alkenyl group, a C 2 -C 20 alkynyl group, a C 6 -C 20 aryl group, a C 6 -C 20 aryl group substituted with deuterium, a fluorenyl group, a C 2 -C 20 heterocyclic group, a C 3 -C 20 cycloalkyl group, a C 7 -C 20 arylalkyl group, and a C 8 -C 20 arylalkenyl group, and these substituents may be linked each other to form a ring, wherein ‘ring’ comprises a C 3 -C 60 aliphatic ring, a C 6 -C 60 aromatic ring, a C 2 -C 60 heterocyclic group or the combination thereof.

2. The compound of claim 1 , wherein Formula 1 above is represented by any one of Formulas 2 to 4 below:

in Formulas 2 to 4, X, L 1 , Ar 1 , R 1 , R 2 , R 3 , a, b and c are the same as defined in claim 1 .

3. The compound of claim 1 , wherein Formula 1 above is represented by any one of Formulas 5 to 7 below:

in Formulas 5 to 7, X, L 1 , Ar 1 , R 1 , R 2 , R 3 , R 4 , a, b, c, d and B ring are the same as defined in claim 1 .

4. The compound of claim 1 , wherein the chemical structure Ar t of the formula 1 comprising the pyrazine is represented by any one of the following Formulas C-1 to C-22:

in Formulas C-1 to C-22, R 4 is the same as defined in claim 1 , and d is an integer of 0 to 11.

5. The compound of claim 1 , wherein R 4 of Formula 1 is represented by any one of the following formulas R-1 to R-10:

in Formulas R-1 to R-10,

1) Q 1 to Q 15 are each independently CR g or N,

2) W 1 is S, O or NR h ,

3) W 2 to W 4 are each independently S, O, NR h or CR i R j ,

4) R e is selected from the group consisting of hydrogen, deuterium, halogen, a silane group substituted or unsubstituted with a C 1 -C 20 alkyl group or a C 6 -C 20 aryl group, a siloxane group, a boron group, a germanium group, a cyano group, a nitro group, a C 1 -C 20 alkylthio group, a C 1 -C 20 alkoxyl group, a C 1 -C 20 alkyl group, a C 2 -C 20 alkenyl group, a C 2 -C 20 alkynyl group, a C 6 -C 20 aryl group, a C 6 -C 20 aryl group substituted with deuterium, a fluorenyl group, a C 2 -C 20 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, a C 3 -C 20 cycloalkyl group, a C 7 -C 20 arylalkyl group, and a C 8 -C 20 arylalkenyl group, and when these substituents are adjacent, they may be linked each other to form a ring,

5) R f and R g are each independently selected from the group consisting of hydrogen, deuterium, a C 6 -C 20 aryl group, a fluorenyl group, a fused ring group of a C 3 -C 20 aliphatic ring and a C 6 -C 20 aromatic ring, a C 2 -C 20 heterocyclic group containing at least one heteroatom selected from O, N, S, Si, and P, a C 1 -C 20 alkyl group, a C 2 -C 20 alkenyl group, a C 2 -C 20 alkynyl group, and a C 1 -C 30 alkoxyl group,

6) R h , R i and R j are each independently selected from the group consisting of a C 6 -C 20 aryl group, a C 2 -C 20 heterocyclic group containing at least one heteroatom selected from O, N, S, Si, and P, a C 1 -C 20 alkyl group, a C 2 -C 20 alkenyl group, a C 1 -C 20 alkoxyl group and a fluorenyl group, R i and R j may be linked each other to form a spiro compound together with C to which they are bonded,

7) q is each independently an integer of 0 to 5,

8) r is each independently an integer of 0 to 4,

9) s is each independently an integer of 0 to 3,

when q, r and s are each 2 or more, R e is each the same or different, and * indicates the position to be bonded.

6. The compound of claim 1 , wherein Formula 1 is any one of the compounds below:

7. An organic electric element comprising a first electrode, a second electrode, and an organic material layer formed between the first electrode and the second electrode, wherein the organic material layer comprises the compound of claim 1 .

8. The organic electric element of claim 7 , wherein the compound is comprised in at least one layer of a hole injection layer, a hole transport layer, an emission-auxiliary layer, an electron transport-auxiliary layer, an electron transport layer and an light emitting layer, and the compound is comprised as a single compound or a mixture of two or more different kinds.

9. The organic electric element of claim 7 , wherein the compound is used as a phosphorescent host material of the light emitting layer.

10. The organic electric element of claim 7 , wherein the organic material layer is formed by any one of the processes of spin coating, nozzle printing, inkjet printing, slot coating, dip coating or roll-to-roll.

11. An electronic device comprising a display device and a control unit for driving the display device, wherein the display device comprises the organic electric element of claim 7 .

12. The electronic device of claim 11 , wherein the organic electric element is selected from the group consisting of an organic light emitting diode, an organic solar cell, an organic photo conductor, an organic transistor, and an element for monochromatic or white illumination.