Process for fabricating polymeric articles
A process for the production of a polymeric article directed to (a) forming a ply having successive layers, namely, (i) a first layer made up of strands of an oriented polymer material; (ii) a second layer of a polymeric material; (iii) a third layer made up of strands of an oriented polymeric material, wherein the second layer has a lower peak melting temperature that of the first and third layers; (b) subjecting the ply to conditions of time, temperature, and pressure sufficient to melt a proportion of the firsts layer to melt the second layer entirely, and to melt a proportion of the third layer, and to compact the ply; and (c) cooling the compacted ply. The resultant articles have good mechanical properties yet may be made at a lower compaction temperature than articles not employing the second layer, leading to a more controllable manufacturing process.
1. A polymeric article comprising a ply of at least three layers, the at least three layers comprising, in sequence, a first layer composed of strands of a first polymeric material, a second layer composed of a second polymeric material, and a third layer composed of strands of a third polymeric material, wherein the polymeric material of each of the three layers has a melting temperature and the second polymeric material has a degree of polymeric orientation less than that of the strands of the first and third polymeric materials;
wherein the first and third layers are fabrics which are woven or knit from tapes, fibre yarns, or filament yarns;
wherein a portion of each of the at least three layers has been melted;
wherein each of the at least three layers comprises the same chemical class of polymer, the chemical class of polymer selected from the group consisting of polyethylene, polypropylene, polyoxymethylene, blends thereof, copolymers thereof, and mixtures thereof;
wherein the second layer comprises a lower melting temperature than that of the first and third layers; wherein the melting temperature of the second layer is at least 5° C. lower than the melting temperature of the first and third layers; and
wherein one of the at least three layers was biaxially oriented prior to being melted.
2. The polymeric article of claim 1 wherein the chemical class of polymer comprises polypropylene.
3. The polymeric article of claim 1 wherein the chemical class of polymer comprises a blend of polypropylene and polyethylene.
4. The polymeric article of claim 1 wherein the second layer has a thickness less than that of either the first layer or the third layer.
5. The polymeric article of claim 1 wherein each of the at least three layers has a substantially identical thickness.
6. The polymeric article of claim 1 wherein the second layer has a thickness greater than that of either the first layer or the third layer.
7. The polymeric article of claim 1 wherein at least one of the at least three layers comprises multiple layers.
8. A polymeric article comprising a ply of at least three layers, the at least three layers comprising, in sequence, a first layer composed of strands of a first polymeric material, a second layer composed of a second polymeric material, and a third layer composed of strands of a third polymeric material, wherein the polymeric material of each of the at least three layers has a melting temperature and the degree of polymeric orientation of the second polymeric material is less than that of the strands of the first and third polymeric materials;
wherein the first and third layers are fabrics which are woven or knit from tapes, fibre yarns, or filament yarns;
wherein a portion of each of the at least three layers has been melted;
wherein each of the at least three layers comprises the same chemical class of polymer, the chemical class of polymer selected from the group consisting of polyethylene, polypropylene, polyoxymethylene, blends thereof, copolymers thereof, and mixtures thereof;
wherein the second layer comprises a lower melting temperature than that of the first and third layers and is melted to a greater degree than the first and third layers; wherein the melting temperature of the second layer is at least 5° C. lower than the melting temperature of the first and third layers; and
wherein the second layer is not oriented.
9. The polymeric article of claim 8 wherein the chemical class of polymer comprises polypropylene.
10. The polymeric article of claim 8 wherein the chemical class of polymer comprises polypropylene and polyethylene.
11. The polymeric article of claim 8 wherein the second layer has a thickness less than that of either the first layer or third layer.
12. The polymeric article of claim 8 wherein each of the at least three layers has a substantially identical thickness.
13. The polymeric article of claim 8 wherein the second layer has a thickness greater than that of either the first or third layer.
14. The polymeric article of claim 8 wherein at least one of the at least three layers comprises multiple layers.