IP Library Granted Patent US 10,876,475
Granted Patent B2
US 10,876,475 · App. 15/848,763 · Granted Dec 29, 2020

Steel piston crown and/or combustion engine components with dynamic thermal insulation coating and method of making and using such a coating

Inventor: Warran Boyd Lineton (Chelsea, MI)
Assignee: Tenneco Inc.
F02B77/11C23C4/02C23C4/073C23C4/11C23C4/129C23C4/131C23C4/134C23C4/18C23C28/321C23C28/3215C23C28/3455C23C28/36F02F3/0084F02F3/12F02F3/14F02F3/26C23C28/32C23C28/345F02F2003/0061F05C2251/048
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 10,876,475
App. No.
15/848,763
Granted
Dec 29, 2020
Kind
B2
Abstract

A piston for an internal combustion engine is provided. The piston includes a thermal barrier coating applied to a crown formed of steel. According to one embodiment, a bond layer of a metal is applied to a combustion surface of the crown, followed by a mixed layer of metal and ceramic with a gradient structure, and then optionally a top layer of metal. The thermal barrier coating can also include a ceramic layer between the mixed layer and top layer, or as the outermost layer. The ceramic includes at least one of ceria, ceria stabilized zirconia, yttria, yttria stabilized zirconia, calcia stabilized zirconia, magnesia stabilized zirconia, and zirconia stabilized by another oxide. The thermal barrier coating is applied by thermal spray, HVOF, or wire arc spraying. The thermal barrier coating preferably has a thickness less than 200 microns and a surface roughness Ra of not greater than 3 microns.

Claims (49)

1. A piston, comprising:

a body portion formed of metal;

said body portion including a crown presenting a combustion surface;

a thermal harrier coating applied to said crown;

said thermal barrier coating including a bond layer formed of metal disposed on said body portion, said bond layer having a thickness of 20 to 50 microns, a mixed layer disposed on said bond layer, said mixed layer having a thickness of 20 to 50 microns, and a top layer disposed on said mixed layer, said top layer having a thickness of 50 to 100 microns;

said mixed layer formed of a mixture of ceramic and metal; and

said top layer formed of metal and filling pores of said ceramic of said mixed layer.

2. The piston of claim 1 , wherein said top layer has a surface roughness Ra of not greater than 3 microns.

3. The piston of claim 1 , wherein said thermal barrier coating has a thickness of not greater than 700 microns.

4. The piston of claim 1 , wherein said mixed layer has a gradient structure, the gradient structure including an increasing concentration of said ceramic material moving from said bond layer to said top layer.

5. The piston of claim 1 , wherein said bond layer is formed of NiCrAlY, said metal of said mixed layer is NiCrAlY, said ceramic of said mixed layer is ceria stabilized zirconia, and said top layer is NiCrAlY.

6. The piston of claim 1 , wherein said combustion surface includes at least one wavy feature and/or valve pocket, and said thermal barrier coating is, applied to said at least one wavy feature and/or valve pocket.

7. The piston of claim 1 , wherein said bond layer is formed of at least one of chromium, nickel, cobalt, chromium alloy, nickel alloy, cobalt alloy, nickel based superalloy, and cobalt based superalloy;

said ceramic of said mixed layer is formed of at least one of ceria, ceria stabilized zirconia, yttria, yttria stabilized zirconia, calcia stabilized zirconia, magnesia stabilized zirconia, and zirconia stabilized by another oxide;

said metal of said mixed layer is formed of at least one of chromium, nickel, cobalt, chromium alloy, nickel alloy, cobalt alloy, nickel based superalloy, and cobalt based superalloy; and

said top layer includes at least one, of chromium, nickel, cobalt, chromium alloy, nickel alloy, cobalt alloy, nickel based superalloy, and cobalt based superalloy.

8. A piston comprising:

a body portion formed of metal;

said body portion including a crown presenting a combustion surface;

a thermal barrier coating applied to said crown;

said thermal barrier coating including a bond layer formed of metal disposed on said body portion and a nixed layer disposed on said bond layer;

said mixed layer including a mixture of ceramic and metal;

said thermal barrier coating including a ceramic layer formed entirely ceramic material disposed on said mixed layer;

said thermal barrier coating including a top layer formed of metal disposed on said ceramic layer, said top layer having a surface roughness Ra of not greater than 3 microns, and wherein some of said ceramic layer is exposed through said top layer.

9. The piston of claim 8 , wherein said mixed layer has a surface roughness Ra of 3 microns or less, and said thermal harrier coating has a thickness of not greater than 200 microns.

10. The piston of claim 8 , wherein said bond layer is formed of NiCrAlY, said metal of said mixed layer is NiCrAlY and said ceramic of said mixed layer is ceria stabilized zirconia.

11. The piston of claim 8 , wherein said metal of said bond layer and/or said metal of said mixed layer of formed of NiCrAl.

12. The piston of claim 8 , wherein said bond layer has a thickness 50 to 100 microns and said mixed layer has a thickness of 50 to 350 microns.

13. The piston of claim 8 , wherein said top layer has a surface roughness of not greater than 1 micron.

14. The piston of claim 8 , wherein said thermal barrier coating has a thickness of not greater than 700 microns.

15. A piston, comprising:

a body portion formed of metal;

said body portion including a crown presenting a combustion surface;

a thermal barrier coating applied to said crown;

said thermal barrier coating including a bond layer formed of metal disposed on said body portion and a mixed layer disposed on said bond layer;

said mixed layer including mixture of ceramic and metal;

said thermal barrier coating including a ceramic layer formed entirely of a ceramic material disposed on said mixed layer, wherein said ceramic layer is an outermost exposed layer of said thermal barrier coating, and said ceramic layer has a thickness of not greater than 100 microns.

16. The piston of claim 15 , wherein said ceramic layer has a surface roughness Ra of not greater than 5 microns.

17. The piston of claim 16 , wherein said ceramic layer has a surface roughness Ra of not greater than 3 microns.

18. The piston of claim 15 , wherein said thermal barrier coating has a thickness of not greater than 700 microns.

19. A piston, comprising:

a body portion formed of metal;

said body portion including a crown presenting a combustion surface;

a thermal barrier coating applied to said crown;

said thermal harrier coating including a bond layer formed of metal disposed on said body portion and a mixed layer disposed on said bond layer,

said mixed layer including a mixture of ceramic and metal;

a ceramic layer formed entirely of a ceramic material disposed on said mixed layer;

said ceramic layer presenting an outermost exposed surface of said thermal barrier coating and having a surface roughness Ra of not greater than 3 microns; and

said thermal barrier coating having a total thickness of not greater than 200 microns.

Assignments (14)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 20, 2025
From: TENNECO INC.
To: FEDERAL-MOGUL POWERTRAIN LLC
Reel/Frame 072553/0043 →
PATENT SECURITY AGREEMENT (ABL) Recorded Apr 7, 2023
From: TENNECO INC.; DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 063268/0506 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Nov 22, 2022
From: DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 061989/0689 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVE TRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
Reel/Frame 061975/0218 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061975/0031 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061971/0156 →
SECURITY AGREEMENT Recorded Mar 17, 2021
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 055626/0065 →
SECURITY AGREEMENT Recorded Dec 1, 2020
From: TENNECO INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 054555/0592 →
MERGER Recorded Jul 1, 2020
From: FEDERAL-MOGUL LLC
To: TENNECO INC.
Reel/Frame 053102/0437 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT, JOINDER, ASSUMPTION AND DESIGNATION AGREEMENT Recorded Oct 26, 2018
From: BANK OF AMERICA, N.A., AS CO-COLLATERAL TRUSTEE AND RESIGNING COLLATERAL TRUSTEE
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS CO-COLLATERAL TRUSTEE, SUCCESSOR COLLATERAL TRUSTEE
Reel/Frame 047630/0661 →
RELEASE OF SECURITY INTEREST Recorded Oct 22, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
To: FEDERAL-MOGUL LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL MOGUL POWERTRAIN LLC
Reel/Frame 047276/0720 →
CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Recorded Oct 9, 2018
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVETRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE
Reel/Frame 047223/0001 →
CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Recorded Apr 3, 2018
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY
To: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 045822/0454 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 22, 2017
From: LINETON, WARRAN BOYD
To: FEDERAL-MOGUL LLC
Reel/Frame 044468/0752 →
Continuity (4)
Continuation In Part 15354001 · Nov 17, 2016
Provisional Application 62578105 · Oct 27, 2017
Provisional Application 62257993 · Nov 20, 2015
Related Publication 20180128166A1 · May 10, 2018