Organic electroluminescence device and electronic device

1. An organic electroluminescence device, comprising a cathode, an anode and an organic layer between the cathode and the anode,

wherein the organic layer comprises a light emitting layer, and a hole transporting region between the anode and the light emitting layer,

the hole transporting region comprises a first hole transporting layer and a second hole transporting layer from the anode toward the light emitting layer in this order, and

the first hole transporting layer comprises a compound represented by the following formula (1):

wherein one selected from R 1 to R 8 , R 11 to R 18 , and R 21 to R 25 is a single bond bonded to *a;

each of R 1 to R 8 , R 11 to R 18 , and R 21 to R 25 which is not the single bond bonded to *a is a hydrogen atom or a substituent;

R 11 and R 23 , or R 18 and R 24 may be bonded to each other to form a single bond;

one selected from R 31 to R 48 is a single bond bonded to *b;

each of R 31 to R 38 and R 39 to R 48 which is not the single bond bonded to *b is a hydrogen atom or a substituent;

R 43 and R 44 may be bonded to each other to form a single bond;

adjacent two selected from R 31 to R 34 may be bonded to each other to form a ring structure;

adjacent two selected from R 35 to R 38 may be bonded to each other to form a ring structure;

adjacent two selected from R 39 to R 43 may be bonded to each other to form a ring structure;

adjacent two selected from R 44 to R 48 may be bonded to each other to form a ring structure;

each of L 1 , L 2 , and L 3 is independently a single bond or a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms; and

Ar is a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms or a substituted or unsubstituted heteroaryl group having 5 to 30 ring atoms,

wherein the substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms is a phenyl group, a biphenylyl group, a terphenylyl group, a biphenylenyl group, a naphthyl group, an acenaphthylenyl group, an anthryl group, a benzanthryl group, an aceanthryl group, a phenanthryl group, a benzophenanthryl group, a phenalenyl group, a fluorenyl group, a pentacenyl group, a picenyl group, a pentaphenyl group, a pyrenyl group, a chrysenyl group, a benzochrysenyl group, a s-indacenyl group, an as-indacenyl group, a fluoranthenyl group, or a perylenyl group, and

the substituted or unsubstituted heteroaryl group having 5 to 30 ring carbon atoms is a pyrrolyl group, a furyl group, a thienyl group, a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, an imidazolyl group, an oxazolyl group, a thiazolyl group, a pyrazolyl group, an isoxazolyl group, an isothiazolyl group, an oxadiazolyl group, a thiadiazolyl group, a triazolyl group, an indolyl group, an isoindolyl group, a benzofuranyl group, an isobenzofuranyl group, a benzothiophenyl group, an indolizinyl group, a quinolizinyl group, a quinolyl group, an isoquinolyl group, a cinnolyl group, a phthalazinyl group, a quinazolinyl group, a quinoxalinyl group, a benzimidazolyl group, a benzoxazolyl group, a benzothiazolyl group, an indazolyl group, a benzisoxazolyl group, a benzisothiazolyl group, a dibenzofuranyl group, a naphthobenzofuranyl group, a dibenzothiophenyl group, a naphthobenzothiophenyl group, a carbazolyl group (a N-carbazolyl group and a C-carbazolyl group), a benzocarbazolyl group (a benzo-N-carbazolyl group and a benzo-C-carbazolyl group), a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a phenothiazinyl group, a phenoxazinyl group, or a xanthenyl group.

2. The organic electroluminescence device according to claim 1 , wherein the light emitting layer comprises a dopant material, and the dopant material is a fluorescent emitting material or a phosphorescent emitting material.

3. An electronic device comprising the organic electroluminescence device according to claim 1 .

4. The organic electroluminescence device according to claim 1 , wherein the compound is represented by formula (2):

wherein R 1 to R 8 , R 12 to R 18 , R 21 to R 22 , R 24 to R 25 , R 31 to R 48 , L 1 to L 3 , and Ar are as defined above.

5. The organic electroluminescence device according to claim 1 , wherein the compound is represented by formula (3):

wherein R 1 to R 8 , R 12 to R 18 , R 21 to R 25 , R 31 to R 48 , L 1 to L 3 , and Ar are as defined above, provided that R 11 and R 23 are not bonded to each other.

6. The organic electroluminescence device according to claim 1 , wherein the compound is represented by formula (4):

wherein R 1 to R 8 , R 12 to R 18 , R 21 to R 25 , R 31 to R 48 , L 1 to L 3 , and Ar are as defined above, provided that R 18 and R 24 are not bonded to each other.

7. The organic electroluminescence device according to claim 1 , wherein R 2 , R 4 , R 5 , or R 7 is the single bond bonded to *a.

8. The organic electroluminescence device according to claim 1 , wherein the compound is represented by formula (2a):

wherein R 2 , R 4 , R 5 , R 7 , R 31 to R 48 , L 1 to L 3 , and Ar are as defined above, provided that R 43 and R 44 are not bonded to each other.

9. The organic electroluminescence device according to claim 1 , wherein the compound is represented by formula (3a):

wherein, R 2 , R 4 , R 5 , R 7 , R 31 to R 48 , L 1 to L 3 , and Ar are as defined above, provided that R 43 and R 44 are not bonded to each other.

10. The organic electroluminescence device according to claim 1 , wherein the compound is represented by formula (2b):

wherein R 2 , R 4 , R 5 , R 7 , to R 42 , R 45 to R 48 , L 1 to L 3 , and Ar are as defined above.

11. The organic electroluminescence device according to claim 1 , wherein the compound is represented by formula (3b):

wherein R 2 , R 4 , R 5 , R 7 , R 31 to R 42 , R 45 to R 48 , L 1 to L 3 , and Ar are as defined above.

12. The organic electroluminescence device according to claim 1 , wherein R 32 , R 34 , R 35 , or R 37 is the single bond bonded to *b.

13. The organic electroluminescence device according to claim 1 , wherein R 2 , R 4 , R 5 , or R 7 is the single bond bonded to *a, and R 32 , R 34 , R 35 , or R 37 is the single bond bonded to *b.

14. The organic electroluminescence device according to claim 1 , wherein each of L 1 , L 2 , and L 3 is independently a phenylene group, a biphenylene group, a terphenylene group, or a naphthylene group.

15. The organic electroluminescence device according to claim 1 , wherein L 1 and L 2 are both single bonds.

16. The organic electroluminescence device according to claim 1 , wherein Ar is the substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms.

17. The organic electroluminescence device according to claim 1 , wherein Ar is the substituted or unsubstituted heteroaryl group having 5 to 30 ring atoms.

18. The organic electroluminescence device according to claim 1 , wherein L 3 is the substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms.

19. The organic electroluminescence device according to claim 1 , wherein each of the substituent, and the optional substituent which is referred to by “substituted or unsubstituted” is at least one selected from the group consisting of an alkyl group having 1 to 30 carbon atoms; a cycloalkyl group having 3 to 30 ring carbon atoms; an aryl group (inclusive of a non-fused aryl group, a fused aryl group, and an aromatic ring assembly) having 6 to 30 ring carbon atoms; an aralkyl group having 7 to 31 carbon atoms which includes an aryl group having 6 to 30 ring carbon atoms; an alkoxy group having an alkyl group having 1 to 30 carbon atoms; an aryloxy group having an aryl group (inclusive of a non-fused aryl group, a fused aryl group, and an aromatic ring assembly) having 6 to 30 ring carbon atoms; a mono-, di- or tri-substituted silyl group having a substituent selected from an alkyl group having 1 to 30 carbon atoms and an aryl group (inclusive of a non-fused aryl group, a fused aryl group, and an aromatic ring assembly) having 6 to 30 ring carbon atoms; a haloalkyl group having 1 to 30 carbon atoms; a haloalkoxy group having a haloalkyl group having 1 to 30 carbon atoms; a halogen atom; a cyano group; and a nitro group.

20. The organic electroluminescence device according to claim 1 , wherein the substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms is a phenyl group, a biphenylyl group, a terphenylyl group, a biphenylenyl group, a naphthyl group, an acenaphthylenyl group, an anthryl group, a benzanthryl group, an aceanthryl group, a phenanthryl group, a benzophenanthryl group, a phenalenyl group, a pentacenyl group, a picenyl group, a pentaphenyl group, a pyrenyl group, a chrysenyl group, a benzochrysenyl group, a s-indacenyl group, an as-indacenyl group, a fluoranthenyl group, or a perylenyl group, and

the substituted or unsubstituted heteroaryl group having 5 to 30 ring carbon atoms is a pyrrolyl group, a furyl group, a thienyl group, a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, an imidazolyl group, an oxazolyl group, a thiazolyl group, a pyrazolyl group, an isoxazolyl group, an isothiazolyl group, an oxadiazolyl group, a thiadiazolyl group, a triazolyl group, an indolyl group, an isoindolyl group, a benzofuranyl group, an isohenzofuranyl group, a benzothiophenyl group, an indolizinyl group, a quinolizinyl group, a quinolyl group, an isoquinolyl group, a cinnolyl group, a phthalazinyl group, a quinazolinyl group, a quinoxalinyl group, a benzimidazolyl group, a benzoxazolyl group, a benzothiazolyl group, an indazolyl group, a benzisoxazolyl group, a benzisothiazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a phenothiazinyl group, a phenoxazinyl group, or a xanthenyl group.

21. The organic electroluminescence device according to claim 1 , wherein the substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms is a phenyl group, a biphenylyl group, or a terphenylyl group.