IP Library Granted Patent US 11,230,681
Granted Patent B2
US 11,230,681 · App. 15/866,734 · Granted Jan 25, 2022

Superlubricating graphene and graphene oxide films

Inventors: Anirudha V. Sumant (Plainfield, IL); Ali Erdemir (Naperville, IL); Junho Choi (Chicago, IL); Diana Berman (Darien, IL)
Assignee: UChicago Argonne, LLC
C10M103/04B05D1/02B05D5/08C10M103/02C10M177/00C23C16/26C23C16/40B82Y30/00C10M2201/0413C10N2030/06C10N2050/02C10N2050/08C10N2070/00C10N2080/00Y10T428/30
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Quick Facts
Patent No.
US 11,230,681
App. No.
15/866,734
Granted
Jan 25, 2022
Kind
B2
Abstract

A system and method for forming at least one of graphene and graphene oxide on a substrate and an opposed wear member. The system includes graphene and graphene oxide formed by an exfoliation process or solution processing method to dispose graphene and/or graphene oxide onto a substrate. The system further includes an opposing wear member disposed on another substrate and a gas atmosphere of an inert gas like N 2 , ambient, a humid atmosphere and a water solution.

Claims (19)

1. A method of interacting with reduced friction comprising:

providing relative movement between a first surface having disposed thereon graphene oxide flakes and being substantially free of oil with a second surface having a diamond like coating; and

interacting the first surface with the second surface wherein the coefficient of friction is between 0.15 and 1.0.

2. The method of claim 1 , further wherein the relative movement including an atmosphere surrounding a solution processed wear member consisting of at least one of ambient, N 2 , Ar and a high vacuum.

3. The method of claim 1 , wherein a substrate is selected from the group of a plastic injection mold surface, a gun barrel, a cutting blade and a bearing, the substrate comprises the first surface.

4. The method of claim 1 , wherein the graphene oxide is a film on the first surface.

5. The method of claim 1 , wherein the graphene oxide is a layer of graphene oxide flakes on the first surface.

6. The method as defined in claim 5 , wherein the opposing wear member is pre-processed to control surface roughness.

7. A method of forming graphene oxide on a substrate, comprising the steps of:

disposing graphene oxide on the substrate substantially free of oil, thereby establishing a low friction wear surface;

providing an opposing wear member comprising diamond like coating (DLC); and

positioning the low friction wear surface and the opposing wear member in water wherein the opposing wear member slides against the graphene oxide on the substrate.

8. The method of claim 7 , wherein disposing graphene oxide comprises forming a layer of graphene oxide flakes.

9. The method of claim 8 , wherein the layer of graphene oxide flakes is formed by solution processing, chemical exfoliation, or mechanical exfoliation.

10. The method as defined in claim 7 , wherein disposing the graphene oxide comprises spraying a liquid containing graphene oxide onto the substrate.

11. The method of claim 7 , wherein disposing graphene oxide comprises forming a graphene oxide film.

12. The method as defined in claim 11 , wherein the graphene oxide film is formed by chemical deposition.

13. The method as defined in claim 7 , wherein the substrate is selected from the group of a metal, a transition metal and an insulator.

14. The method of claim 7 , wherein the DLC is a hydrogenated form of DLC.

Assignments (3)
CONFIRMATORY LICENSE Recorded Jun 21, 2022
From: UCHICAGO ARGONNE, LLC
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 060455/0241 →
CONFIRMATORY LICENSE Recorded Jun 21, 2022
From: UCHICAGO ARGONNE, LLC
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 060455/0256 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 8, 2019
From: SUMANT, ANIRUDHA; ERDEMIR, ALI; BERMAN, DIANA; CHOI, JUNHO
To: UCHICAGO ARGONNE, LLC
Reel/Frame 048273/0136 →
Continuity (3)
Division 14415499
Continuation 13553484 · Jul 19, 2012
Related Publication 20180171251A1 · Jun 21, 2018