IP Library › Granted Patent US 10,323,155
Granted Patent B2
US 10,323,155 · App. 15/867,093 · Granted Jun 18, 2019

Actinic radiation-curable inkjet ink and image forming method

Inventors: Takayuki Toeda (Tokyo, JP); Kana Yamada (Tokyo, JP)
Assignee: KONICA MINOLTA, INC.
C09D11/101C07C69/732C07D263/58C07D333/06C09D11/107C09D11/38
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Quick Facts
Patent No.
US 10,323,155
App. No.
15/867,093
Granted
Jun 18, 2019
Kind
B2
Abstract

An actinic radiation-curable inkjet ink containing a photocurable compound, a photopolymerization initiator, a fluorescent brightener, and a phenol-based antioxidant, in which the fluorescent brightener is a compound represented by general formula (1), and the photocurable compound contains a (meth)acrylate having two or more (meth)acryloyl groups in an amount of 80 mass % or more with respect to a total mass of the photocurable compound.

Claims (20)

1. An actinic radiation-curable inkjet ink, comprising a photocurable compound, a polymerization initiator, a fluorescent brightener, an antioxidant, and a gelling agent,

wherein the fluorescent brightener is a compound represented by the following general formula (1):

wherein R 1 to R 8 each independently represent a hydrogen atom or an alkyl group, adjacent substituents of R 1 to R 8 optionally forming a ring, and A represents a linking group represented by any one of the following formulas (2) to (5):

wherein each * represents a bonding position of A of each formula;

the antioxidant is a phenol-based antioxidant; and

the photocurable compound contains a (meth)acrylate having two or more (meth)acryloyl groups in an amount of 80 mass % or more with respect to a total mass of the photocurable compound.

2. The actinic radiation-curable inkjet ink according to claim 1 , wherein a content of the fluorescent brightener is 0.01 mass % or more and 0.5 mass % or less with respect to a total mass of the actinic radiation-curable inkjet ink.

3. The actinic radiation-curable inkjet ink according to claim 1 , wherein a content of the antioxidant is 0.1 mass % or more and 1.0 mass % or less with respect to a total mass of the actinic radiation-curable inkjet ink.

4. The actinic radiation-curable inkjet ink according to claim 1 , wherein the antioxidant is a polyfunctional phenol-based antioxidant.

5. The actinic radiation-curable inkjet ink according to claim 4 , wherein the antioxidant is a compound represented by the following general formula (6):

wherein R 9 and R 10 each independently represent an alkyl group having 1 or more and 4 or less carbon atoms, n represents an integer of 2 to 4, and L represents an alkyl group having 1 or more and 10 or less carbon atoms.

6. The actinic radiation-curable inkjet ink according to claim 1 ,

wherein the gelling agent contains a compound represented by the following general formula (G1) or a compound represented by the following general formula (G2):

R 11 —CO—R 12   General Formula (G1):

R 13 —COO—R 14   General formula (G2):

wherein R 11 and R 12 each independently represent a straight chain hydrocarbon group having 9 or more and 25 or less carbon atoms.

7. The actinic radiation-curable inkjet ink according to claim 1 , further comprising a colorant.

8. An image forming method, comprising:

discharging a droplet of the actinic radiation-curable inkjet ink according to claim 1 from a nozzle of an inkjet head and causing the droplet to land on a substrate; and

curing the actinic radiation-curable inkjet ink by irradiating, with actinic radiation, the droplet of the actinic radiation-curable inkjet ink landed on the substrate.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 10, 2018
From: TOEDA, TAKAYUKI; YAMADA, KANA
To: KONICA MINOLTA, INC.
Reel/Frame 044586/0624 →
Priority Claims (1)
JP 2017-020642 · Feb 7, 2017 · national
Continuity (1)
Related Publication 20180223117A1 · Aug 9, 2018