High density and high temperature emulsifier for use in an oil based drilling fluid system
An emulsifying composition for an oil based drilling fluid includes oleyl alcohol and a mixture of polymeric amides. The polymeric amides can be 1,3-dihydroxypropan-2-yl (E)-12-hydroxyoctadec-9-enoate, (9E,9′E)-N,N′-(azanediylbis(ethane-2,1-diyl))bis(12-hydroxyoctadec-9-enamide, (E)-12-hydroxy-N,N-bis(2-((E)-12-hydroxyoctadec-9-enamido(ethyl)octadec-9-enamide, (Z)-4-(bis(2-((E)-12-hydroxyoctadec-9-enamido)ethy)amino)-4-oxobut-2-enoic acid, 1,3-dihydroxypropan-2-yl(Z)-4-(bis(2-((E)-12-hydroxyoctadec-9-enamido)ethy)amino)-4-oxobut-2-enoate, and N1,N1,N4,N4-tetrakis(2-((E)-12-hydroxyoctadec-9-enamido)ethyl)maleamide. The method of forming the emulsifying composition includes reacting a fatty oil with diethylenetriamine and then maleic acid, and adding oleyl alcohol. The high density emusifying composition is stable at high temperatures of drilling operations at greater depths in the wellbore.
1. An emulsifying composition for an oil based drilling fluid, comprising:
a saturated or unsaturated, monohydroxylated or polyhydroxylated, branched or straight chain alcohol;
1,3-dihydroxypropan-2-yl (E)-12-hydroxyoctadec-9-enoate as Compound A;
(9E,9′E)-N,N′-(azanediylbis(ethane-2,1-diyl))bis(12-hydroxyoctadec-9-enamide as Compound B;
(E)-12-hydroxy-N,N-bis(2-((E)-12-hydroxyoctadec-9-enamido(ethyl)octadec-9-enamide as Compound C;
(Z)-4-(bis(2-((E)-12-hydroxyoctadec-9-enamido)ethy)amino)-4-oxobut-2-enoic acid as Compound D;
1,3-dihydroxypropan-2-yl (Z)-4-(bis(2-((E)-12-hydroxyoctadec-9-enamido)ethy)amino)-4-oxobut-2-enoate as Compound E; and
N1,N1,N4,N4-tetrakis(2-((E)-12-hydroxyoctadec-9-enamido)ethyl)maleamide as Compound F.
2. The emulsifying composition, according to claim 1 , wherein said alcohol is 10-50% by weight, said Compound A is 10-50% by weight, and said Compound B is 5-30% by weight.
3. The emulsifying composition, according to claim 2 , wherein each of said Compound C, said Compound D, said Compound E, and said Compound F is 5-40% by weight.
4. The emulsifying composition, according to claim 1 , wherein said alcohol is 20-30% by weight, said Compound A is 10-30% by weight, and said Compound B is 10-20% by weight.
5. The emulsifying composition, according to claim 3 , wherein each of said Compound C, said Compound D, and said Compound E is 5-10% by weight, and said Compound F is 5-20% by weight.
6. The emulsifying composition, according to claim 1 , being produced by reactions of a fatty oil with diethylenetriamine and then maleic acid.
7. The emulsifying composition, according to claim 1 , wherein the said alcohol is C16-C24 unsaturated, a C4-C12 monohydroxylated, C8-C16branched chain alcohol.