Temperature sensor
A temperature sensor that includes a first electrode layer, a second electrode layer, and a thermistor layer between the first and second electrode layers. The thermistor layer includes a spinel-type semiconductor ceramic composition powder containing Mn, Ni, and Fe, and an organic polymer component. In the semiconductor ceramic composition powder, the molar ratio of Mn to Ni is 85/15≥Mn/Ni≥65/35, and when the total molar quantity of Mn and Ni is 100 parts by mole, the content of Fe is 30 parts by mole or less, and the semiconductor ceramic composition powder is 2 μm or less in particle size.
1. A temperature sensor comprising:
a first electrode layer;
a second electrode layer; and
a thermistor layer between the first electrode layer and the second electrode layer, the thermistor layer comprising a spinel semiconductor ceramic composition powder containing Mn, Ni, and Fe, and an organic polymer component,
wherein
in the spinel semiconductor ceramic composition powder, a molar ratio of Mn to Ni is 85/15≥Mn/Ni≥65/35, and when a total molar quantity of Mn and Ni is 100 parts by mol, a content of Fe is 30 parts by mol or less, and
the spinel semiconductor ceramic composition powder has a peak corresponding to a (220) plane thereof in an X-ray diffraction pattern, and the peak has a half width of 0.15 or more.
2. The temperature sensor according to claim 1 , wherein the spinel semiconductor ceramic composition powder is 2 μm or less in average particle size.
3. The temperature sensor according to claim 1 , wherein
the spinel semiconductor ceramic composition powder further comprises one or more selected from the group of Co, Ti, and Al, and
when the total molar quantity of Mn and Ni is 100 parts by mole, a content of Co, Ti, and Al is 2.0 to 60 parts by mole in total.
4. The temperature sensor according to claim 1 , wherein the spinel semiconductor ceramic composition powder has a specific surface area of 2 m 2 /g to 12 m 2 /g.
5. The temperature sensor according to claim 1 , wherein the spinel semiconductor ceramic composition powder has a volume ratio in the thermistor layer of 30 vol % to 70 vol %.
6. The temperature sensor according to claim 1 , wherein the organic polymer component comprises a thermosetting resin.
7. The temperature sensor according to claim 6 , wherein the thermosetting resin is at least one resin selected from the group of an epoxy resin, an epoxy acrylate resin, a phenol novolac-type epoxy resin, a phenol resin, a urethane resin, a silicone resin, a polyamide resin and a polyimide resin.
8. The temperature sensor according to claim 6 , wherein the organic polymer component further comprises a phenoxy resin.
9. The temperature sensor according to claim 1 , wherein the organic polymer component comprises a thermoplastic resin.
10. The temperature sensor according to claim 9 , wherein the thermoplastic resin is at least one resin selected from the group of a polyvinyl butyral resin, an epoxy resin with no curing agent added, a phenoxy resin with no curing agent, a polyester, and a polyvinyl acetate.
11. The temperature sensor according to claim 1 , wherein the thermistor layer is 200 μm or less in thickness.
12. The temperature sensor according to claim 1 , wherein the first electrode layer and the second electrode layer are arranged along a same plane of the temperature sensor.