Metallic nanospring and method for manufacturing of the same
A method for manufacturing a metallic nanospring includes preparing a nanotemplate having a nanopore and including a working electrode disposed on its one surface, preparing a first metal precursor mixture including ascorbic acid (C 6 H 8 O 6 ), vanadium (IV) oxide sulfate (VOSO 4 .xH 2 O), and a metal precursor solution including a metal desired to be deposited, preparing a second metal precursor mixture by mixing the first metal precursor mixture with nitric acid (HNO 3 ), depositing a metallic nanospring into the nanopore using electrodeposition by dipping the nanotemplate into the second metal precursor mixture and applying current between a counter electrode inserted into the second metal precursor mixture and the working electrode, and selectively removing the working electrode on the nanotemplate with the deposited metallic nanospring and the nanotemplate.
1. A method for manufacturing a metallic nanospring, comprising:
preparing a nanotemplate having a nanopore and including a working electrode disposed on a surface of the nanotemplate;
preparing a first metal precursor mixture including ascorbic acid (C 6 H 8 O 6 ), vanadium (IV) oxide sulfate hydrate (VOSO 4 .xH 2 O), and a metal precursor solution including a metal desired to be deposited;
preparing a second metal precursor mixture by mixing the first metal precursor mixture with nitric acid (HNO 3 );
depositing a metallic nanospring into the nanopore using electrodeposition by dipping the nanotemplate into the second metal precursor mixture and applying current between a counter electrode inserted into the second metal precursor mixture and the working electrode; and
selectively removing both the working electrode and the nanotemplate, on which the metallic nanospring was deposited, to obtain the metallic nanospring.
2. The method according to claim 1 , wherein:
the metal precursor solution includes at least one of cobalt (II) sulfate heptahydrate (CoSO 4 .7H 2 O) and iron (II) sulfate heptahydrate (FeSO 4 .7H 2 0 ).
3. The method according to claim 2 , wherein:
a concentration of cobalt (II) sulfate heptahydrate (CoSO 4 .7H 2 O) is 40 mM in the second metal precursor mixture,
a concentration of vanadium (IV) oxide sulfate hydrate (VOSO 4 .xH 2 O) is 20 mM in the second metal precursor mixture, a concentration of iron (II) sulfate heptahydrate (FeSO 4 .7H 2 O) is 40 mM in the second metal precursor mixture, and
a concentration of ascorbic acid (C 6 H 8 O 6 ) is 20 mM in the second metal precursor mixture.
4. The method according to claim 3 , wherein:
a pH of the second metal precursor mixture is between 1.5 and 2.5.
5. The method according to in claim 1 , wherein:
a mean diameter of the nanopore is between 5 and 500 nanometers.
6. The method according to claim 1 , further comprising:
dipping the nanotemplate into the second metal precursor mixture and depressurizing a plating bath storing the second metal precursor solution,
wherein a pressure of the plating bath is between 100 and 700 Torr.
7. The method according to claim 1 , wherein:
a concentration of the ascorbic acid is between 20 and 100 mM in the second metal precursor mixture.
8. The method according to claim 1 , wherein:
a density of current flowing to the working electrode during electrodeposition is between 0.1 and 300 mA/cm 2 , and
a time required for the electrodeposition is between one minute and 48 hours.