Materials and methods for the preparation of nanocomposites
Disclosed herein is an isolable colloidal particle comprising a nanoparticle and an inorganic capping agent bound to the surface of the nanoparticle, a method for making the same in a biphasic solvent mixture, and the formation of structures and solids from the isolable colloidal particle. The process can yield photovoltaic cells, piezoelectric crystals, thermoelectric layers, optoelectronic layers, light emitting diodes, ferroelectric layers, thin film transistors, floating gate memory devices, phase change layers, and sensor devices.
1. A colloidal material comprising nanoparticles and inorganic capping agents, wherein each inorganic capping agent is bound to an outer surface of a nanoparticle, and the inorganic capping agents comprise H n MO y , where n=0, 1, or 2, y=2, 3, or 4, M is a metal, metalloid or phosphorus and H n MO y is negatively charged.
2. The colloidal material of claim 1 , wherein M is P, As, W, V, or Mo.
3. The colloidal material of claim 1 , wherein the inorganic capping agents comprise VO 4 3− , MoO 4 2− , WO 4 2− , PO 4 3− , AsO 4 3− , HPO 3 2− , H 2 PO 2 − , or a mixture thereof.
4. A colloidal material comprising nanoparticles and inorganic capping agents, wherein the inorganic capping agents are bound to at least a portion of the surface of the nanoparticles and the inorganic capping agents comprise H 3 [PMo 12 O 40 ]; H 3 [PW 12 O 40 ]; Na 3 PMo 12 O 40 ; Na 6 H 2 W 12 O 40 ; H 4 [SiW 12 O 40 ]; (NH 4 ) 6 [H 2 W 12 O 40 ]; K 6 [P 2 W 18 O 62 ]; K 6 [P 2 Mo 18 O 62 ]; Mo 154 ; Rb 8 K 2 [{Ru 4 O 4 (OH) 2 ; (H 2 O) 4 }(γ-SiW 10 O 36 ) 2 ], or a mixture or derivative thereof.
5. The colloidal material of claim 1 , wherein the colloidal material is a super-lattice.
6. The colloidal material of claim 1 made by a method comprising admixing inorganic capping agents in a first solvent and nanoparticles-in a second solvent together to form the colloidal material, wherein the second solvent is appreciably immiscible in the first solvent.
7. A method of making the colloidal material of claim 1 , comprising
(a) admixing the nanoparticles in a first solvent and the inorganic capping agents in a second solvent in the presence of a quaternary ammonium salt to form the colloidal material; and
(b) isolating the colloidal material from the admixture, wherein the first solvent is nonpolar and the second solvent is polar.
8. A matrix comprising a plurality of colloidal particles, each comprising a nanoparticle and an inorganic capping agent, wherein the inorganic capping agent is bound to at least a portion of the nanoparticle surface, wherein the inorganic capping agent comprises H n MO y , where n=0, 1, or 2, y=2, 3, or 4, M is a metal, metalloid or phosphorus and H n MO y is negatively charged, and wherein pairs of colloidal particles are bridged by a cationic ion cross-linkages bound to the respective colloidal particles of the pair.
9. A field effect transistor comprising:
a source region and a drain region and the matrix of claim 8 extending between, and electrically coupled to, the source region and the drain region to provide current flow between the source region and the drain region, in response to activation of the field effect transistor by a gate coupled to the matrix and having a threshold gate voltage.
10. The colloidal material of claim 4 , wherein the colloidal material is a super-lattice.
11. The colloidal material of claim 4 made by a method comprising admixing inorganic capping agents in a first solvent and nanoparticles in a second solvent together to form the colloidal material, wherein the second solvent is appreciably immiscible in the first solvent.
12. A method of making the colloidal material of claim 4 , comprising
(a) admixing the nanoparticles in a first solvent and the inorganic capping agents in a second solvent in the presence of a quaternary ammonium salt to form the colloidal material; and
(b) isolating the colloidal material from the admixture, wherein the first solvent is nonpolar and the second solvent is polar.
13. A matrix comprising a plurality of colloidal particles, each comprising a nanoparticle and an inorganic capping agent, wherein the inorganic capping agent is bound to at least a portion of the nanoparticle surface, wherein the inorganic capping agent comprises H 3 [PMo 12 O 40 ]; H 3 [PW 12 O 40 ]; Na 3 PMo 12 O 40 ; Na 6 H 2 W 12 O 40 ; H 4 [SiW 12 O 40 ]; (NH 4 ) 6 [H 2 W 12 O 40 ]; K 6 [P 2 W 15 O 62 ]; K 6 [P 2 Mo 18 O 62 ]; Mo 154 ; Rb 5 K 2 [{Ru 4 O 4 (OH) 2 ; (H 2 O) 4 }(γ-SiW 10 O 36 ) 2 ], or a mixture or derivative thereof, and wherein pairs of colloidal particles are bridged by a cationic ion cross-linkages bound to the respective colloidal particles of the pair.
14. A field effect transistor comprising:
a source region and a drain region and the matrix of claim 13 extending between, and electrically coupled to, the source region and the drain region to provide current flow between the source region and the drain region, in response to activation of the field effect transistor by a gate coupled to the matrix and having a threshold gate voltage.