Graphene oxide/metal nanocrystal multilaminates the atomic limit for safe, selective hydrogen storage
Various embodiments of the invention describe an environmentally stable, and exceptionally dense hydrogen storage (6.5 wt % and 0.105 kg H 2 /L in the total composite, 7.56 wt % in Mg) using atomically thin and gas-selective reduced graphene oxide sheets as encapsulants. Other approaches to protecting reactive materials involve energy intensive introduction of considerable amounts of inactive, protective matrix which compromises energy density. However, these multilaminates are able to deliver exceptionally dense hydrogen storage far-exceeding 2020 DOE target metrics for gravimetric capacity (5.5 wt %), and ultimate full-fleet volumetric targets (0.070 kg H 2 /L) for fuel cell electric vehicles. Methods of stabilizing reactive nanocrystalline metals in zero-valency also has wide-ranging applications for batteries, catalysis, encapsulants, and energetic materials.
1. A composition of matter comprising:
a reduced graphene oxide (rGO)-magnesium (Mg) nanocrystal nanolaminate, the nanolaminate comprising two rGO sheets with Mg nanocrystals distributed therebetween, the nanolaminate having a hydrogen storage capacity of approximately 6.5 weight percent hydrogen and 0.105 kg H 2 /L, the hydrogen storage capacity of the nanolaminate being equivalent to approximately 7.56 weight percent hydrogen in the Mg nanocrystals.
2. The composition of matter claim 1 , wherein the Mg nanocrystals are distributed in an approximately hexagonal pattern corresponding to a d-spacing of 2.778 Å.
3. The composition of matter claim 2 , wherein the Mg nanocrystals are distributed in an approximately hexagonal close-packed (hcp) pattern.
4. The composition of matter claim 3 , wherein a Mg nanocrystal size distribution is approximately 3.26 nanometers ±0.87 nanometers in diameter.
5. The composition of matter claim 3 , wherein at least 50% of the Mg nanocrystals are zero-valent crystalline Mg.
6. The composition of matter claim 1 , wherein the nanolaminate further comprises hydrogen.
7. The composition of matter claim 1 , wherein the nanolaminate further comprises hydrogen in the form of MgH 2 .
8. A method of preparing reduced graphene oxide (rGO)-magnesium (Mg) nanocrystal nanolaminates comprising:
ball-milling graphene oxide (GO) to break down the GO to GO platelets in order to complex with bis(cyclopentadienyl) magnesium (Cp 2 Mg);
preparing a lithium naphthalenide solution by dissolving naphthalene in tetrahydrofuran (THF), followed by the addition of Li metal to produce the lithium naphthalenide solution;
dispersing GO in the THF to form a GO solution;
adding a Cp 2 Mg solution to the GO solution to produce a GO/Cp 2 Mg solution;
adding the GO/Cp 2 Mg solution to the lithium naphthalenide solution to produce the reduced graphene oxide (rGO) magnesium (Mg) nanocrystal nanolaminates;
centrifuging and washing the reduced graphene oxide (rGO)-magnesium (Mg) nanocrystal nanolaminates with THF; and
drying the graphene oxide (rGO)-magnesium (Mg) nanocrystal nanolaminates a graphene oxide (rGO)-magnesium (Mg) nanocrystal nanolaminate comprising two rGO sheets with Mg nanocrystals distributed therebetween, the nanolaminate having a hydrogen storage capacity of approximately 6.5 weight percent hydrogen and 0.105 kg H 2 /L, the hydrogen storage capacity of the nanolaminate being equivalent to approximately 7.56 weight percent hydrogen in the Mg nanocrystals.