PROCESS FOR PRODUCING TAURINE
There is disclosed a process for producing taurine by decomposing ammonium taurinate to taurine and ammonia. Ammonium taurinate is prepared by the hydrogenation of ammonium 2-nitroethanesulfonate, by the reaction of aziridine with ammonium bisulfite, or by mixing alkali taurinate with an ammonium salt selected from the group from ammonium isethionate, ammonium bisulfite, ammonium sulfite, ammonium sulfate, ammonium bisulfate, ammonium chloride, ammonium bromide, ammonium nitrate, ammonium phosphate, ammonium hydrogen phosphate, ammonium dihydrogen phosphate, ammonium carbonate, ammonium bicarbonate, ammonium carboxylate, ammonium alkyl sulfonate, ammonium aryl sulfonate, and a mixture of two or more thereof.
1 . A process for producing taurine which comprises decomposing ammonium taurinate to taurine and ammonia by heating and removing ammonia.
2 . The process according to claim 1 , wherein ammonium taurinate is prepared by reducing ammonium 2-nitroethanesulfonate.
3 . The process according to claim 1 , wherein ammonium taurinate is prepared by catalytic hydrogenation of ammonium 2-nitroethanesulfonate.
4 . The process according to claim 1 , wherein ammonium taurinate is prepared by mixing alkali taurinate or a mixture of alkali taurinate, alkali ditaurinate, and alkali tritaurinate with ammonium isethionate.
5 . The process according to claim 1 , wherein ammonium taurinate is prepared by mixing alkali taurinate or a mixture of alkali taurinate, alkali ditaurinate, and alkali tritaurinate with an ammonium salt selected from the group of ammonium bisulfite, ammonium sulfite, ammonium sulfate, ammonium bisulfate, ammonium chloride, ammonium bromide, ammonium nitrate, ammonium phosphate, ammonium hydrogen phosphate, ammonium dihydrogen phosphate, ammonium carbonate, ammonium bicarbonate, ammonium carboxylate, ammonium alkyl sulfonate, ammonium aryl sulfonate, and a mixture of two or more thereof.
6 . The process according to claim 1 , wherein ammonium taurinate is prepared by the reaction of aziridine with ammonium bisulfite, ammonium sulfite or a mixture of ammonium bisulfite and ammonium sulfite.
7 . The process according to claim 1 , wherein the decomposition of ammonium taurinate is performed at a temperature from 60° C. to 150° C. at reduced, normal, or increased pressure.
8 . The process according to claim 1 , wherein the yield of taurine from ammonium taurinate is from 90% to quantitative.
9 . The process according to claim 4 , wherein alkali taurinate is lithium taurinate, sodium taurinate, or potassium taurinate.
10 . The process according to claim 5 , wherein alkali taurinate is lithium taurinate, sodium taurinate, or potassium taurinate.