IP Library Granted Patent US 10,668,510
Granted Patent B2
US 10,668,510 · App. 15/897,892 · Granted Jun 2, 2020

Compositions, systems, and methods for removing iron sulfide scale from oilfield components

Inventors: Yang Peng (Kingwood, TX); Funian Zhao (Tomball, TX); Zhiwei Yue (Sugar Land, TX); Liu Shi (Houston, TX); Liangwei Qu (Spring, TX); Chunfang Fan (Houston, TX)
Assignee: Multi-Chem Group LLC.
B08B3/08C09K8/528C09K8/532C11D7/32C11D11/0041C23G1/24C09K2208/20
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Quick Facts
Patent No.
US 10,668,510
App. No.
15/897,892
Granted
Jun 2, 2020
Kind
B2
Abstract

The present disclosure relates to compositions, systems and methods for removing iron sulfide scale from a solid object, such as an oilfield component. The compositions include a carbon-carbon (C—C) double bond with an electron withdrawing group bonded to at least one of the double-bonded carbons.

Claims (12)

1. A method of removing iron sulfide scale from an oilfield component with iron sulfide scale, the method comprising applying to the oilfield component in an amount and for a time sufficient to remove iron sulfide scale from the oilfield component a removal material comprising a composition with the general structural formula:

wherein R 1 comprises a nitrile group and R 2 is R 1 , hydrogen (H), or a moiety comprising an electron withdrawing group, and

wherein at least 80% of the iron sulfide scale on the oilfield component is broken into component ions by the composition with general structural formula (I).

2. The method of claim 1 , wherein the removal material comprises at least two distinct compositions with the general structural formula (I).

3. The method of claim 1 , wherein the removal material further comprises a polar solvent.

4. The method of claim 1 , wherein at least 85% of the iron sulfide scale on the oilfield component is broken into component ions by the composition with general structural formula (I).

5. The method of claim 1 , wherein applying occurs in a sealed container.

6. The method of claim 1 , further comprising recovering the removal material.

7. The method of claim 1 , wherein the oilfield component comprises a perforation, a casing, a production tubular, a valve, a pump, or downhole completion equipment with iron sulfide scale.

8. The method of claim 1 , wherein at least 90% of the iron sulfide scale on the oilfield component is broken into component ions by the composition with general structural formula (I).

9. The method of claim 1 , wherein at least 95% of the iron sulfide scale on the oilfield component is broken into component ions by the composition with general structural formula (I).

10. The method of claim 1 , wherein substantially all of the iron sulfide scale on the oilfield component is broken into component ions by the composition with general structural formula (I).

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2021
From: MULTI-CHEM GROUP, LLC
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 056681/0849 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 13, 2019
From: HALLIBURTON ENERGY SERVICES, INC.
To: MULTI-CHEM GROUP LLC.
Reel/Frame 049463/0641 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 15, 2018
From: PENG, YANG; ZHAO, FUNIAN; YUE, ZHIWEI; SHI, LIU; QU, LIANGWEI; FAN, CHUNFANG
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 044946/0195 →
Continuity (2)
Continuation 15038721
Related Publication 20180169714A1 · Jun 21, 2018