Exciplex light-emitting device
Provided is a light-emitting element which includes a first electrode, a second electrode over the first electrode, and first and second light-emitting layers therebetween. The first light-emitting layer contains a first host material and a first light-emitting material, and the second light-emitting layer contains a second host material and a second light-emitting material. The first light-emitting material is a fluorescent material, and the second light-emitting material is a phosphorescent material. The level of the lowest triplet excited state (T 1 level) of the first light-emitting material is higher than the T 1 level of the first host material. A light-emitting device, an electronic device, and a lighting device including the light-emitting element are further provided.
1. A light-emitting device comprising:
a first electrode;
a second electrode;
a plurality of light-emitting layers between the first electrode and the second electrode, the plurality of light-emitting layers comprising a first light-emitting layer, a second light-emitting layer, and a third light-emitting layer in order from the first electrode; and
an electron-transport material, a Group 1 metal or a Group 2 metal, a hole-transport material, and an acceptor which are between the second light-emitting layer and the third light-emitting layer,
wherein the first light-emitting layer comprises a first host material and a first fluorescent material,
wherein the second light-emitting layer comprises a second host material, an additive which is configured to form an exciplex together with the second host material, and a phosphorescent material,
wherein the third light-emitting layer comprises a third host material and a second fluorescent material,
wherein an emission spectrum peak of the exciplex overlaps with an adsorption band on a longest wavelength side in an absorption spectrum of the phosphorescent material,
wherein the second host material is any one of a triazole derivative, a dibenzofuran derivative, a pyrimidine derivative, a triazine derivative, a pyridine derivative, a bipyridine derivative, and a phenanthroline derivative,
wherein a level of the lowest triplet excited state (a T1 level) of the first fluorescent material is higher than a T1 level of the first host material, and
wherein a level of the lowest singlet excited state (a S1 level) of the first host material is higher than a S1 level of the first fluorescent material.
2. The light-emitting device according to claim 1 , wherein the acceptor is an organic acceptor.
3. The light-emitting device according to claim 1 , wherein a level of the lowest triplet excited state (a T1 level) of the second host material is higher than the T1 level of the first host material.
4. A light-emitting device comprising:
a first electrode;
a second electrode;
a plurality of light-emitting layers between the first electrode and the second electrode, the plurality of light-emitting layers comprising a first light-emitting layer, a second light-emitting layer, and a third light-emitting layer in order from the first electrode; and
an electron-transport material, an oxide of a Group 1 metal or an oxide of a Group 2 metal, a hole-transport material, and an acceptor which are between the second light-emitting layer and the third light-emitting layer,
wherein the first light-emitting layer comprises a first host material and a first fluorescent material,
wherein the second light-emitting layer comprises a second host material, an additive which is configured to form an exciplex together with the second host material, and a phosphorescent material,
wherein the third light-emitting layer comprises a third host material and a second fluorescent material,
wherein an emission spectrum peak of the exciplex overlaps with an adsorption band on a longest wavelength side in an absorption spectrum of the phosphorescent material,
wherein the second host material is any one of a triazole derivative, a dibenzofuran derivative, a pyrimidine derivative, a triazine derivative, a pyridine derivative, a bipyridine derivative, and a phenanthroline derivative,
wherein a level of the lowest triplet excited state (a T1 level) of the first fluorescent material is higher than a T1 level of the first host material, and
wherein a level of the lowest singlet excited state (a S1 level) of the first host material is higher than a S1 level of the first fluorescent material.
5. The light-emitting device according to claim 4 , wherein the acceptor is an organic acceptor.
6. The light-emitting device according to claim 4 , wherein a level of the lowest triplet excited state (a T1 level) of the second host material is higher than the T1 level of the first host material.
7. A light-emitting device comprising:
an anode;
a cathode;
a plurality of light-emitting layers between the anode and the cathode, the plurality of light-emitting layers comprising a first fluorescent light-emitting layer closest to the anode, a second fluorescent light-emitting layer closest to the cathode, and a phosphorescent light-emitting layer between the first fluorescent light-emitting layer and the second fluorescent light-emitting layer; and
an electron-transport material, a Group 1 metal or a Group 2 metal, a hole-transport material, and an acceptor which are between the phosphorescent light-emitting layer and the second fluorescent light-emitting layer,
wherein the first fluorescent light-emitting layer comprises a first host material and a fluorescent material,
wherein the phosphorescent light-emitting layer comprises a second host material, an additive which is configured to form an exciplex together with the second host material, and a phosphorescent material,
wherein an emission spectrum peak of the exciplex overlaps with an adsorption band on a longest wavelength side in an absorption spectrum of the phosphorescent material, and
wherein the second host material is any one of a triazole derivative, a dibenzofuran derivative, a pyrimidine derivative, a triazine derivative, a pyridine derivative, a bipyridine derivative, and a phenanthroline derivative,
wherein a level of the lowest triplet excited state (a T1 level) of the fluorescent material is higher than a T1 level of the first host material, and
wherein a level of the lowest singlet excited state (a S1 level) of the first host material is higher than a S1 level of the fluorescent material.
8. The light-emitting device according to claim 7 , wherein the acceptor is an organic acceptor.
9. The light-emitting device according to claim 7 , wherein a level of the lowest triplet excited state (a T1 level) of the second host material is higher than the T1 level of the first host material.
10. A light-emitting device comprising:
an anode;
a cathode;
a plurality of light-emitting layers between the anode and the cathode, the plurality of light-emitting layers comprising a first fluorescent light-emitting layer closest to the anode, a second fluorescent light-emitting layer closest to the cathode, and a phosphorescent light-emitting layer between the first fluorescent light-emitting layer and the second fluorescent light-emitting layer; and
an electron-transport material, an oxide of a Group 1 metal or an oxide of a Group 2 metal, a hole-transport material, and an acceptor which are between the phosphorescent light-emitting layer and the second fluorescent light-emitting layer,
wherein the first fluorescent light-emitting layer comprises a first host material and a fluorescent material,
wherein the phosphorescent light-emitting layer comprises a second host material, an additive which is configured to form an exciplex together with the second host material, and a phosphorescent material,
wherein an emission spectrum peak of the exciplex overlaps with an adsorption band on a longest wavelength side in an absorption spectrum of the phosphorescent material, and
wherein the second host material is any one of a triazole derivative, a dibenzofuran derivative, a pyrimidine derivative, a triazine derivative, a pyridine derivative, a bipyridine derivative, and a phenanthroline derivative,
wherein a level of the lowest triplet excited state (a T1 level) of the fluorescent material is higher than a T1 level of the first host material, and
wherein a level of the lowest singlet excited state (a S1 level) of the first host material is higher than a S1 level of the fluorescent material.
11. The light-emitting device according to claim 10 , wherein the acceptor is an organic acceptor.
12. The light-emitting device according to claim 10 , wherein a level of the lowest triplet excited state (a T1 level) of the second host material is higher than the T1 level of the first host material.