Quantum dot based color conversion layer in display devices
Embodiments of a display device including barrier layer coated quantum dots and a method of making the barrier layer coated quantum dots are described. Each of the barrier layer coated quantum dots includes a core-shell structure and a hydrophobic barrier layer disposed on the core-shell structure. The hydrophobic barrier layer is configured to provide a distance between the core-shell structure of one of the quantum dots with the core-shell structures of other quantum dots that are in substantial contact with the one of the quantum dots. The method for making the barrier layer coated quantum dots includes forming reverse micro-micelles using surfactants and incorporating quantum dots into the reverse micro-micelles. The method further includes individually coating the incorporated quantum dots with a barrier layer and isolating the barrier layer coated quantum dots with the surfactants of the reverse micro-micelles disposed on the barrier layer.
1. A method of making barrier layer coated quantum dots, the method comprising:
forming a solution of reverse micro-micelles using surfactants;
incorporating quantum dots into the reverse micro-micelles;
individually coating the quantum dots with a barrier layer to form barrier layer coated quantum dots; and
isolating the barrier layer coated quantum dots with the surfactants of the reverse micro-micelles disposed on the barrier layer,
wherein the barrier layer coated quantum dots exhibit a quantum yield greater than about 80%.
2. The method of claim 1 , wherein the incorporating of the quantum dots into the reverse micro-micelles includes forming a first mixture of the quantum dots and the solution of reverse micelles.
3. The method of claim 2 , wherein the individually coating of the quantum dots with a barrier layer includes:
forming a second mixture of a precursor and the first mixture; and
forming a third mixture of a catalyst and the second mixture.
4. The method of claim 3 , wherein the isolating of the barrier layer coated quantum dots includes heating the third mixture at or below a temperature of about 50° C. under vacuum.
5. The method of claim 1 , wherein the barrier layer coated quantum dots exhibit a quantum yield greater than about 90%.
6. The method of claim 1 , wherein the barrier layer coated quantum dots exhibit a quantum yield in a range of about 85% to about 95%.
7. The method of claim 1 , wherein the quantum dots and the barrier layer coated quantum dots exhibit a quantum yield greater than about 80%.
8. The method of claim 1 , wherein the quantum dots and the barrier layer coated quantum dots exhibit a quantum yield greater than about 85%.
9. The method of claim 1 , wherein the barrier layer coated quantum dots have an average size ranging from about 20 nm and to about 40 nm in diameter.
10. The method of claim 1 , wherein the barrier layer coated quantum dots have an average size ranging from about 25 nm and to about 35 nm in diameter.
11. The method of claim 1 , wherein the barrier layer comprises an oxide.
12. The method of claim 1 , wherein the barrier layer comprises silicon oxide.
13. A method of making barrier layer coated quantum dots, the method comprising:
forming a solution of reverse micro-micelles using surfactants;
incorporating quantum dots into the reverse micro-micelles;
individually coating the quantum dots with a barrier layer to form the barrier layer coated quantum dots; and
performing an acid etch treatment of the barrier layer coated quantum dots,
wherein the acid etched barrier layer coated quantum dots exhibit a quantum yield greater than about 80%.
14. The method of claim 13 , further comprising isolating the barrier layer coated quantum dots with the surfactants of the reverse micro-micelles disposed on the barrier layer after the performing of the acid etch treatment.
15. The method of claim 13 , wherein the incorporating of the quantum dots into the reverse micro-micelles comprises forming a first mixture of the quantum dots and the solution of reverse micelles.
16. The method of claim 15 , wherein the individually coating of the quantum dots with the barrier layer includes:
forming a second mixture of a precursor and the first mixture; and
forming a third mixture of a catalyst and the second mixture.
17. The method of claim 16 , wherein the performing of the acid etch treatment of the barrier layer quantum dots comprises forming a fourth mixture of an acid and the third mixture.
18. The method of claim 16 , wherein the performing of the acid etch treatment of the barrier layer quantum dots comprises:
selectively removing the catalyst; and
forming a fourth mixture of an acid and the third mixture.
19. The method of claim 13 , wherein the acid comprises acetic acid, hydrochloric acid, nitric acid, or a fatty acid.
20. A method of making barrier layer coated quantum dots, the method comprising:
(a) forming a solution of reverse micro-micelles using surfactants;
(b) incorporating quantum dots into the solution of reverse micro-micelles to form a first mixture;
(c) admixing a precursor and the first mixture to form a second mixture;
(d) admixing a catalyst and the second mixture to form a third mixture;
(e) admixing an acid and the third mixture;
to form barrier layer coated quantum dots.