Electrochemical cells comprising short-circuit resistant electronically insulating regions
The present disclosure is related to electrochemical cells and associated methods. According to certain embodiments, the electrochemical cells comprise an electronically insulating region. In some embodiments, the electronically insulating region can be mechanically compliant. In some embodiments, the insulating region may comprise multiple layers (e.g., mechanically separable layers). The use of such arrangements can, according to certain embodiments, reduce the degree to which the electronically insulating region is breached by lithium dendrite growth.
1. An electrochemical cell, comprising:
a first electrode comprising metallic lithium as an electrode active material;
a second electrode;
a liquid-containing electrolyte; and
an electronically insulating region between the first electrode and the second electrode, the electronically insulating region mechanically separable from the first and second electrodes, the electronically insulating region comprising:
a first electronically insulating layer;
a second electronically insulating layer; and
an interface between the first electronically insulating layer and the second electronically insulating layer;
wherein at least 5% of the volume of the first electronically insulating layer is occupied by the electrolyte and at least 5% of the volume of the second electronically insulating layer is occupied by the electrolyte;
wherein at least 5% of the area of the first electronically insulating layer at the interface between the first electronically insulating layer and the second electronically insulating layer is not mechanically separable from the second electronically insulating layer; and
wherein the interface between the first electronically insulating layer and the second electronically insulating layer comprises a portion over which the first electronically insulating layer is mechanically separable from the second electronically insulating layer through application of a force with a magnitude of less than 5 N/mm.
2. An electrochemical cell, comprising:
a first electrode comprising metallic lithium as an electrode active material;
a second electrode; and
an electronically insulating region between the first electrode and the second electrode, the electronically insulating region mechanically separable from the first and second electrodes, the electronically insulating region comprising:
a first electronically insulating layer;
a second electronically insulating layer; and
an interface between the first electronically insulating layer and the second electronically insulating layer;
wherein the ionic conductivity of the second electronically insulating layer is within 10% of the ionic conductivity of the first electronically insulating layer;
wherein at least 5% of the area of the first electronically insulating layer at the interface between the first electronically insulating layer and the second electronically insulating layer is not mechanically separable from the second electronically insulating layer; and
wherein the interface between the first electronically insulating layer and the second electronically insulating layer comprises a portion over which the first electronically insulating layer is mechanically separable from the second electronically insulating layer through application of a force with a magnitude of less than 5 N/mm.
3. The electrochemical cell of claim 1 , wherein the first electronically insulating layer and the second electronically insulating layer are in direct contact.
4. The electrochemical cell of claim 1 , wherein one or more intervening layers is present between the first electronically insulating layer and the second electronically insulating layer.
5. The electrochemical cell of claim 1 , wherein the electronically insulating region comprises a polymer.
6. The electrochemical cell of claim 1 , wherein at least one of the first electronically insulating layer and the second electronically insulating layer comprises a polymer.
7. The electrochemical cell of claim 1 , wherein each of the first electronically insulating layer and the second electronically insulating layer comprises a polymer.
8. The electrochemical cell of claim 1 , wherein the electronically insulating region comprises pores.
9. The electrochemical cell of claim 1 , wherein at least one of the first electronically insulating layer and the second electronically insulating layer comprises pores.
10. The electrochemical cell of claim 1 , wherein both the first electronically insulating layer and the second electronically insulating layer comprise pores.
11. The electrochemical cell of claim 8 , wherein at least 50% of the pore volume is made up of pores having cross-sectional diameters of greater than or equal to 0.001 microns.
12. The electrochemical cell of claim 8 , wherein the at least 50% of the pore volume is made up of pores having cross-sectional diameters of greater than or equal to 0.001 microns and less than or equal to 0.5 microns.
13. The electrochemical cell of claim 8 , wherein at least a portion of the pores extend from one external surface of the electronically insulating region to a second, opposite external surface of the electronically insulating region.
14. The electrochemical cell of claim 1 , wherein the electronically insulating region does not qualify as a gel.
15. The electrochemical cell of claim 1 , wherein the electronically insulating region has an ionic conductivity greater than or equal to 10 −4 S/cm.
16. The electrochemical cell of claim 1 , wherein the first electrode comprises a lithium alloy.
17. The electrochemical cell of claim 1 , wherein the second electrode comprises sulfur.
18. The electrochemical cell of claim 1 , wherein the second electrode comprises a lithium-intercalation electrode.
19. The electrochemical cell of claim 1 , wherein the first electrode comprises a layer of lithium metal.
20. The electrochemical cell of claim 1 , wherein the electronically insulating region comprises exactly two electronically insulating layers.
21. The electrochemical cell of claim 1 , wherein the first electronically insulating layer and the second electronically insulating layer can be separated across at least 50% of the interface between the first electronically insulating layer and the second electronically insulating layer through application of a force with a magnitude of less than 5 N/mm.
22. The electrochemical cell of claim 1 , wherein the first electronically insulating layer and the second electronically insulating layer can be separated across at least 90% of the interface between the first electronically insulating layer and the second electronically insulating layer through application of a force with a magnitude of less than 5 N/mm.
23. The electrochemical cell of claim 1 , further comprising a lithium metal dendrite within the portion of the interface between the first electronically insulating layer and the second electronically insulating layer over which the first electronically insulating layer is mechanically separable from the second electronically insulating layer through application of a force with a magnitude of less than 5 N/mm.
24. The electrochemical cell of claim 2 , wherein the first electronically insulating layer and the second electronically insulating layer can be separated across at least 50% of the interface between the first electronically insulating layer and the second electronically insulating layer through application of a force with a magnitude of less than 1 N/mm.
25. The electrochemical cell of claim 2 , wherein the first electronically insulating layer and the second electronically insulating layer can be separated across at least 90% of the interface between the first electronically insulating layer and the second electronically insulating layer through application of a force with a magnitude of less than 1 N/mm.
26. The electrochemical cell of claim 2 , wherein the electronically insulating region comprises a polymer.
27. The electrochemical cell of claim 2 , wherein the electronically insulating region comprises pores.
28. The electrochemical cell of claim 2 , wherein the first electrode comprises a lithium alloy.
29. The electrochemical cell of claim 2 , wherein the second electrode comprises a lithium-intercalation electrode.
30. The electrochemical cell of claim 2 , wherein the first electrode comprises a layer of lithium metal.