Method for removing contaminants from cannabinoid distillates
View Patent ↗A method for removing contaminants such as pesticides and fungicides from cannabinoid extracts. Cannabinoid extracts containing contaminants may be dissolved in a water and ethanol solution, and then cooled to allow water-soluble contaminants to settle out of the mixture. The water and ethanol may then be removed via evaporation or distillation, leaving purified cannabinoids without contaminants. Contaminant removal may be incorporated into a method for producing a blended extract of cannabinoids and terpenes, which extracts terpenes using supercritical CO2, and extracts a cannabinoid concentrate from the residual material using a cold ethanol flush followed by distillation and then by contaminant removal; the CO2-extracted terpenes are then added back to the purified cannabinoid concentrate in a final blending step. Blending terpenes at the end of extraction may enhance the flavor and effectiveness of the purified cannabinoid concentrate.
1. A method for removing contaminants from cannabinoid distillates consisting essentially of:
obtaining cannabis, wherein said cannabis contains one or more contaminants; grinding said cannabis to obtain a ground cannabis;
extracting terpene oil from said ground cannabis to yield a residual ground cannabis and said terpene oil;
wherein said extracting terpene oil from said ground cannabis to yield said residual ground cannabis and said terpene oil consists essentially of
pressurizing carbon dioxide to a pressure between 1000 psi and 1300 psi to form a supercritical carbon dioxide fluid;
exposing said ground cannabis to said supercritical carbon dioxide fluid at a temperature between 80° F. and 110° F. for an elapsed time between 15 minutes and 6 hours to obtain a carbon dioxide extraction solution;
reducing pressure of said carbon dioxide extraction solution to remove said carbon dioxide, thereby obtaining a carbon dioxide extraction product;
separating said carbon dioxide extraction product into said terpene oil and said residual ground cannabis separately; and,
filtering said terpene oil at a temperature between −80° F. and 40° F. with a filter having a pore size greater than 0.25 micron;
freezing said residual ground cannabis to obtain a frozen residual cannabis;
washing said frozen residual cannabis with cold ethanol to obtain an ethanol oil solution of cannabis;
separating said ethanol oil solution of cannabis into ethanol and cannabis oil separately; distilling said cannabis oil to obtain cannabinoid distillates;
separating said cannabinoid distillates into purified cannabinoid distillates and residual contaminants separately;
wherein said separating said cannabinoid distillates into purified cannabinoid distillates and residual contaminants separately consists essentially of
mixing said cannabinoid distillates with said ethanol and water to yield a cannabinoid-ethanol-water solution;
allowing said one or more contaminants to settle out of said cannabinoid-ethanol-water solution;
separating said cannabinoid-ethanol-water solution into a purified cannabinoid-ethanol-water solution and said residual contaminants separately; and,
removing said ethanol and said water from said purified cannabinoid-ethanol-water solution to yield said purified cannabinoid distillates; and,
wherein said separating said cannabinoid-ethanol-water solution into said purified cannabinoid-ethanol-water solution and said residual contaminants separately further consists essentially of one or more of
pouring said purified cannabinoid-ethanol-water solution off of said cannabinoid-ethanol-water solution;
siphoning said purified cannabinoid-ethanol-water solution off of said cannabinoid-ethanol-water solution; and,
filtering said residual contaminants out of said cannabinoid-ethanol-water solution to yield said purified cannabinoid-ethanol-water solution; and,
blending said purified cannabinoid distillates with said terpene oil to obtain a terpene oil enhanced cannabinoid concentrate.
2. The method of claim 1 wherein said mixing said cannabinoid distillates with ethanol and water to yield said cannabinoid-ethanol-water solution consists essentially of
adding said ethanol to said cannabinoid distillates at a ratio between 2:1 and 4:1 of ethanol by volume in mL to cannabinoid distillates by mass in grams, to yield a cannabinoid-ethanol solution;
heating said cannabinoid-ethanol solution to a temperature between 40° C. and 80° C. to yield a dissolved cannabinoid-ethanol solution;
adding distilled water to said dissolved cannabinoid-ethanol solution at a ratio between 1:4 and 1:10 of distilled water by volume in mL to cannabinoid distillates by mass in grams, to yield said cannabinoid-ethanol-water solution; and,
heating said cannabinoid-ethanol-water solution to a temperature between 40° C. and 60° C.
3. The method of claim 1 wherein said allowing said one or more contaminants to settle out of said cannabinoid-ethanol-water solution consists essentially of
cooling said cannabinoid-ethanol-water solution to a temperature between −30° C. and 10° C., yielding a cooled cannabinoid-ethanol-water solution; and,
allowing said one or more contaminants to settle out of said cooled cannabinoid-ethanol-water solution for a period of time between 2 hours and 7 days.
4. The method of claim 1 wherein said separating said ethanol oil solution of cannabis into ethanol and cannabis oil separately consists essentially of distilling said ethanol oil solution of cannabis at a temperature between 120° F. and 165° F. under a vacuum measuring between 10 inches Hg and 25 inches Hg.
5. The method of claim 4 further consisting essentially of reusing said ethanol for a subsequent washing step of a second batch of frozen residual cannabis.
6. The method of claim 1 wherein said distilling consists essentially of
generating a vacuum in a distillation vessel with a pressure at or below 5 torr; heating said cannabis oil to a temperature between 140° C. and 157° C.; collecting a first condensed vapor to yield terpene distillates;
heating said cannabis oil to a temperature between 157° C. and 230° C.; and, collecting a second condensed vapor to yield said cannabinoid distillates.
7. The method of claim 1 further consisting essentially of
redistilling said purified cannabinoid distillates to obtain a higher concentration of purified cannabinoid distillates; and,
blending said higher concentration of purified cannabinoid distillates with said terpene oil to obtain a higher concentration of said terpene oil enhanced cannabinoid concentrate.
8. The method of claim 1 , wherein said extracting terpene oil further consists essentially of separating a terpene hydrosol from said carbon dioxide extraction product.