Process and composition for well dispersed, highly loaded color masterbatch
A highly loaded and well-dispersed masterbatch composition and process for making thereof from a split stream process. The masterbatch composition includes a colorant, a thermoplastic carrier, a metallocene polymer processing aid, and optionally an additive. The split stream may be formed of a primary feed and a secondary feed. The primary and second feeds are combined by at least one of the following: supplying the secondary feed in either the same feed port as the primary feed, in a stream located upstream the primary feed, in a stream located downstream the primary feed, or a combination thereof.
1. A process for making a masterbatch composition comprising:
providing an additive mixture including a colorant and an optional additive component or components to a primary feed;
melting a thermoplastic and providing the melted thermoplastic to a secondary feed that is physically separated from the primary feed;
combining the secondary feed with the primary feed and extruding the resultant mixture to form a masterbatch composition having greater than 45 wt. % of the additive mixture; and
wherein, upon combining the primary and secondary feeds, a weight ratio of primary to secondary feed is greater than 60:40.
2. The process according to claim 1 wherein the weight ratio is less than 95:5.
3. The process according to claim 1 wherein the weight ratio is less than 90:10.
4. The process according to claim 1 wherein the additive component or components are present and include at least one item selected from: a metallocene polymer, a polymer processing aid, a dispersion aid, a slip agent, mineral oil, and any combination of two or more items herein.
5. The process according to claim 1 wherein the masterbatch composition has up to 80 wt. % of colorant.
6. The process according to claim 1 wherein the masterbatch composition has up to 50 wt. % of organic pigment(s).
7. The process according to claim 6 wherein the organic pigment(s) is at least one item selected from: azo and disazo pigments such as azo and disazo lake, Hansas, benzimidazolones, diarylides, pyrazolones, yellows and reds; polycyclic pigments, phthalocyanines, quinacridones, perylenes, perinones, dioxazines, anthraquinones, isoindolins, thioindigo, diaryl and/or quinophthalone pigment, Aniline Black, and any combination of two or more items herein.
8. The process according to claim 1 wherein the masterbatch composition has up to 75 wt. % of inorganic pigment(s).
9. The process according to claim 8 wherein the inorganic pigment(s) is at least one item selected from: titanium oxide, titanium yellow, iron oxide, ultramarine blue, cobalt blue, chromic oxide green, Lead Yellow, cadmium yellow and cadmium red, carbon black pigments, and any combination of two or more items herein.
10. The process according to claim 1 wherein the master batch composition includes organic and inorganic pigments.
11. The process according to claim 1 wherein the masterbatch composition has between 9 to 55 wt. % of thermoplastic.
12. The process according to claim 1 wherein the masterbatch composition has up to 60 wt. % of the additive component(s).
13. The process according to claim 1 wherein the additive component or components are present and include at least one item selected from: an antioxidant, a light stabilizer, an ultraviolet light absorber, and any combination two or more items herein.
14. The process according to claim 1 wherein the additive component or components are present and consist essentially of at least one item selected from: antioxidants, ultraviolet light absorbers, light stabilizers, flame-retardants, antibacterial agents, surface tension reducers, deodorizing agents, anti-static agents, anti-blocking agents, plasticizer agents, fillers, blowing agents, and any combination of two or more items herein.
15. The process according to claim 1 wherein constituents of the secondary feed are mixed via a dry blending process prior to melting the thermoplastic.
16. A process for making a masterbatch composition from a split stream process comprising:
a) mixing a colorant into a mixture in a primary feed;
b) pre-melting a thermoplastic carrier in a secondary feed;
c) combining the mixture of the primary feed and the secondary feed, including the melted thermoplastic carrier, at a ratio (by weight) of primary feed to secondary feed between 46:54 and 87:13; and
d) extruding the combined mixture to form a masterbatch composition having between 15 to 80 wt. % of colorant.
17. The process according to claim 16 further comprising, prior to combining the mixture of the primary feed and the secondary feed, providing an additive in the primary feed and/or in the secondary feed so that the masterbatch composition has between 5 to 60 wt. % of additive.
18. The process according to claim 17 wherein the additive is at least one item selected from: antioxidants, ultraviolet light absorbers, light stabilizers, flame-retardants, antibacterial agents, surface tension reducers, deodorizing agents, anti-static agents, anti-blocking agents, plasticizer agents, fillers, blowing agents, and any combination of two or more items herein.
19. The process according to claim 18 wherein the masterbatch composition has between 9 to 60 wt. % of thermoplastic carrier.
20. The process according to claim 19 wherein the melted thermoplastic carrier consists essentially of at least one item selected from: homopolymers and copolymers of polyethylene, polypropylene, polystyrene, polyoxymethylene, polyethylene terephthalate, polybutylene terephthalate, polymethyl methacrylate, polyether sulfones, polysulfones, polyether ketones, polystyrene copolymers, acrylonitrile-butadiene-styrene terpolymers, polyamides, polycarbonate, and any combination of two or more items herein.