IP Library Granted Patent US 11,174,163
Granted Patent B2
US 11,174,163 · App. 15/966,884 · Granted Nov 16, 2021

Biogas upgrading technology for power generation

Inventors: Theodore Tsotsis (Huntington Beach, CA); Richard Prosser (Los Angeles, CA); Mingyuan Cao (Los Angeles, CA); Sasan Dabir (Los Angeles, CA)
Assignees: University of Southern California; ES Engineering Services, LLC
C01B3/26C01B3/38C10G35/04C01B2203/0233C01B2203/0405C01B2203/1058C01B2203/1064C01B2203/1241C01B2203/84C10G2300/1011
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Quick Facts
Patent No.
US 11,174,163
App. No.
15/966,884
Granted
Nov 16, 2021
Kind
B2
Abstract

A method for powering an internal combustion engine or other device powered by combustion includes a step of feeding a first stream of biogas to a catalytic reforming reactor in which the first stream contacts oxygen to form a first product stream comprising synthesis gas. The first product stream is combined with a second stream of biogas to form a second product stream. The second product stream is provided to a device powered by combustion. A system implementing the method is also provided.

Claims (19)

1. A method comprising:

combining a first stream of biogas with an oxygen-containing stream to form a combined stream, the first stream of biogas including methane;

feeding the combined stream to a catalytic reforming reactor in which biogas reacts with an oxygen-containing compound to form a first product stream comprising synthesis gas;

exchanging heat between the first product stream and the oxygen-containing stream to heat the oxygen-containing stream;

combining the first product stream with a second stream of biogas to form a second product stream, the second stream of biogas including methane;

providing the second product stream to a device powered by combustion; and

exchanging heat between flue gas from the device powered by combustion and the first stream of biogas to heat the first stream of biogas.

2. The method of claim 1 wherein the oxygen-containing compound is steam.

3. The method of claim 2 wherein a weight ratio of steam to methane is from about 1 to 5.

4. The method of claim 1 wherein the device powered by combustion is operated under lean-burn conditions.

5. The method of claim 4 wherein the device powered by combustion is operated under lean-burn conditions with an air-to-fuel equivalence ratio greater than 1.

6. The method of claim 1 wherein the device powered by combustion is an electric generator.

7. The method of claim 1 wherein heat is transferred from the device powered by combustion to the catalytic reforming reactor.

8. The method of claim 1 wherein the oxygen-containing compound is carbon monoxide.

9. The method of claim 1 wherein the combined stream is heated to a temperature from about 550° C. to about 850° C. before being fed to the catalytic reforming reactor.

10. The method of claim 1 wherein the catalytic reforming reactor contains a catalyst that includes nickel.

11. The method of claim 1 wherein the catalytic reforming reactor contains a catalyst that includes a noble metal.

12. The method of claim 1 wherein the catalytic reforming reactor contains a catalyst that includes platinum, ruthenium or palladium.

13. The method of claim 1 wherein the first stream of biogas includes flue gas from a rich-burn engine.

Assignments (10)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 8, 2025
From: ES ENGINEERING SERVICES, LLC
To: UNIVERSITY OF SOUTHERN CALIFORNIA
Reel/Frame 071630/0591 →
SECURITY INTEREST Recorded Mar 3, 2025
From: ES ENGINEERING SERVICES, LLC
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 070387/0072 →
SECURITY INTEREST Recorded Feb 28, 2025
From: ENTHALPY ANALYTICAL, LLC; EMERGING COMPOUNDS TREATMENT TECHNOLOGIES, INC.; ES ENGINEERING SERVICES, LLC; MONTROSE AIR QUALITY SERVICES, LLC
To: BANK OF THE WEST, AS ADMINISTRATIVE AGENT
Reel/Frame 070365/0229 →
NOTICE OF SUCCESSOR AGENT AND ASSIGNMENT OF SECURITY INTEREST (INTELLECTUAL PROPERTY) Recorded Feb 28, 2025
From: BMO BANK N.A. (SUCCESSOR IN INTEREST TO BANK OF THE WEST), AS THE RESIGNING AGENT
To: BANK OF AMERICA, N.A., AS THE SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 070364/0627 →
RELEASE OF SECURITY INTEREST Recorded Feb 27, 2025
From: CAPITAL ONE, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
To: EMERGING COMPOUNDS TREATMENT TECHNOLOGIES, INC.; ENTHALPY ANALYTICAL, LLC; MONTROSE AIR QUALITY SERVICES, LLC; ES ENGINEERING SERVICES, LLC
Reel/Frame 070355/0107 →
RELEASE OF SECURITY INTEREST Recorded Apr 13, 2020
From: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
To: ES ENGINEERING SERVICES, LLC,
Reel/Frame 052381/0859 →
SECURITY INTEREST Recorded Apr 13, 2020
From: EMERGING COMPOUNDS TREATMENT TECHNOLOGIES, INC.; ENTHALPY ANALYTICAL, LLC; MONTROSE AIR QUALITY SERVICES, LLC; ES ENGINEERING SERVICES, LLC
To: CAPITAL ONE, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 052377/0845 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Jul 25, 2019
From: ES ENGINEERING SERVICES, LLC
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 049865/0478 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 2, 2018
From: TSOTSIS, THEODORE; CAO, MINGYUAN; DABIR, SASAN
To: UNIVERSITY OF SOUTHERN CALIFORNIA
Reel/Frame 047391/0021 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 6, 2018
From: PROSSER, RICHARD
To: ES ENGINEERING SERVICES, LLC
Reel/Frame 046798/0240 →
Continuity (2)
Provisional Application 62491413 · Apr 28, 2017
Related Publication 20180312400A1 · Nov 1, 2018