Compositions containing microcapsules coated with deposition proteins
A microcapsule composition containing microcapsules coated with a deposition protein, e.g., a protein-silanol copolymer, a protein-silane copolymer, a protein-siloxane copolymer, or a cationically modified protein, is provided as is a method for making the microcapsule composition and using the microcapsule composition in consumer products, in particular rinse-off consumer product.
1. A microcapsule composition comprising a plurality of microcapsules each containing a polymeric wall and an active material encapsulated within the polymeric wall, wherein the polymeric wall is coated with a deposition protein, and the deposition protein is cross-linked to the surface of the microcapsules via a transglutaminase, glutaraldehyde, genipin, or alkoxysilane.
2. The microcapsule composition of claim 1 , wherein the deposition protein is a cationically modified protein, a protein-silanol copolymer, a protein-silane, a protein-siloxane copolymer, or a combination thereof.
3. The microcapsule composition of claim 2 , wherein the cationically modified protein is a protein-acrylate copolymer comprising at least one nitrogen-containing acrylic moiety, which comprises a tertiary or quaternary amine group.
4. The microcapsule composition of claim 1 , wherein the deposition protein is a copolymer of ethyltrimmoniumchloride methacrylate and protein.
5. The microcapsule composition of claim 1 , wherein the deposition protein has the structure of Formula I or Formula II:
wherein
R is a protein residue;
R 1 is a protein cross-linker group;
R 2 and R 3 are each independently hydrogen, hydroxyl, halo, C 1 -C 6 alkyl, or C 1 -C 6 alkoxy; and
n is 1 to 100.
6. The microcapsule composition of claim 1 , wherein the deposition protein is a modified vegetable protein, wheat protein, marine collagen, keratin, silk protein, milk protein, or a combination thereof.
7. The microcapsule composition of claim 1 , wherein the deposition protein has a molecular weight in the range of 1000 Daltons to 500,000 Daltons.
8. The microcapsule composition of claim 1 , wherein the active material is a fragrance, pro-fragrance, flavor, malodor counteractive agent, anti-inflammatory agent, anesthetic, analgesic, anti-viral agent, anti-infectious agent, anti-acne agent, skin lightening agent, insect repellant, emollient, skin moisturizing agent, vitamin or derivative thereof, nanometer to micron size inorganic solid, polymeric or elastomeric particle, or combination thereof.
9. The microcapsule composition of claim 1 , wherein the polymeric wall comprises polyacrylate, polyurea, polyurethane, polyacrylamide, poly(acrylate-co-acrylamide), starch, silica, gelatin and gum Arabic, poly(melamine-formaldehyde), poly(urea-formaldehyde), or a combination thereof.
10. The microcapsule composition of claim 1 , further comprising a second deposition aid in addition to the deposition protein.
11. The microcapsule composition of claim 10 , wherein the second deposition aid is chitosan, starch, polysaccharide, or a combination thereof.
12. A consumer product comprising the microcapsule composition of claim 1 .
13. The consumer product of claim 12 , further comprising one or more different microcapsules, free active material, or a combination thereof.
14. The consumer product of claim 12 , wherein the consumer product is a shampoo, hair conditioner, body wash, detergent, softener, bar soap, scent booster, or hard surface cleaner.
15. The microcapsule composition of claim 1 , wherein the deposition protein is cross-linked on the surface of the microcapsules via glutaraldehyde or alkoxysilane.