Separator enclosures for electrodes and electrochemical cells
The disclosure provides electrochemical cells including a separator enclosure which encloses at least a portion of a positive or negative electrode. In an embodiment, the separator generates a contact force or pressure on at least a portion of the electrode which can improve the performance of the cell. The disclosure also provides methods for charging an electrochemical cell.
1. A method for enhancing cycling performance of an electrochemical cell; said method comprising:
providing said electrochemical cell comprising
a positive electrode;
a negative electrode;
one or more electrolytes positioned between said positive electrode and said negative electrode; wherein said one or more electrolytes are capable of conducting charge carriers; and
an electrically insulating and ionically conductive separator enclosure enclosing a surface of said positive electrode or said negative electrode that is not in physical contact with a current collector; wherein said separator enclosure generates a contact force, characterized by an average contact pressure selected from the range of 10 Pa to 10 MPa, on said surface of said positive electrode or said negative electrode during charging or discharging of said electrochemical cell; wherein the separator comprises one or more layers independently comprising an elastomer having an elongation to break of from 100% to 1000%; and
establishing said contact force sufficient to prevent a substantial change in electrode porosity or surface roughness of said positive electrode or said negative electrode enclosed by said separator enclosure during cycling of said electrochemical cell.
2. The method of claim 1 , wherein said separator enclosure generates said contact force on said surface during charging or discharging of said electrochemical cell.
3. The method of claim 1 , wherein said contact force is characterized by an average contact pressure selected from the range of 1 kPa to 100 kPa.
4. The method of claim 1 , wherein said separator enclosure comprises a first layer having a plurality of apertures arranged in a first pattern and a second layer having a plurality of apertures arranged in a second pattern; wherein said second pattern has an off-set alignment relative to said first pattern such that an overlap of said apertures of said first layer and said apertures of said second layer along axes extending perpendicularly from said first layer to said second layer is less than or equal to 20%.
5. The method of claim 1 , said one or more electrolytes comprising a solid electrolyte, wherein said solid electrolyte comprises particles and a binder; wherein said particles comprise a ceramic and said binder comprises a polymer.
6. The method of claim 1 , wherein said separator enclosure entirely encloses said positive electrode or said negative electrode.
7. The method of claim 1 , wherein said contact force is generated by an elastic force of the separator enclosure provided in an expanded state, and varies as a function of a state of charge and state of health of the battery.
8. The method of claim 1 , wherein the electrically insulating and ionically conductive separator enclosure encloses an entire surface of said positive electrode or said negative electrode that is not in physical contact with a current collector; and wherein the separator generates said contact force on said entire surface of said positive electrode or said negative electrode during charging or discharging of said electrochemical cell.
9. The method of claim 1 , wherein the separator generates said contact force on said surface of said positive electrode or said negative electrode in response to a size and shape of said positive electrode or said negative electrode changing during charging and discharging of the cell; wherein the generated contact force is a function of the change of the size and shape of said positive electrode or said negative electrode.
10. The method of claim 1 , wherein the elastomer is a thermoplastic polymer.
11. The method of claim 1 , wherein the separator is in physical contact with said surface of said positive electrode or said negative electrode during charging or discharging of said electrochemical cell.
12. The method of claim 1 , wherein the elastomer has a compressive modulus selected from the range of 0.01 to 4 GPa at room temperature.
13. The method of claim 1 , wherein the elastomer has a compressive modulus selected from the range of 0.01 to 0.1 GPa at room temperature.
14. A method for generating an electrical current, the method comprising the steps of:
providing an electrochemical cell comprising:
a positive electrode;
a negative electrode;
one or more electrolytes positioned between said positive electrode and said negative electrode; wherein said one or more electrolytes are capable of conducting charge carriers; and
an electrically insulating and ionically conductive separator enclosure enclosing a surface of said positive electrode or said negative electrode that is not in physical contact with a current collector, wherein said separator enclosure generates a contact force, characterized by an average contact pressure selected from the range of 10 Pa to 10 MPa, on said surface of said positive electrode or said negative electrode during charging or discharging of said electrochemical cell; wherein the separator comprises one or more layers independently comprising an elastomer having an elongation to break of from 100% to 1000%; wherein said contact force is sufficient to prevent a substantial change electrode porosity or surface roughness of said positive electrode or said negative electrode enclosed by said separator enclosure during cycling of said electrochemical cell; and
discharging said electrochemical cell.
15. The method of claim 14 , wherein said separator enclosure generates said contact force on said surface during charging or discharging of said electrochemical cell.
16. The method of claim 14 , wherein said contact force is characterized by an average contact pressure selected from the range of 1 kPa to 100 kPa.
17. The method of claim 14 , wherein said separator enclosure comprises a first layer having a plurality of apertures arranged in a first pattern and a second layer having a plurality of apertures arranged in a second pattern; wherein said second pattern has an off-set alignment relative to said first pattern such that an overlap of said apertures of said first layer and said apertures of said second layer along axes extending perpendicularly from said first layer to said second layer is less than or equal to 20%.
18. The method of claim 14 , said one or more electrolytes comprising a solid electrolyte, wherein said solid electrolyte comprises particles and a binder; wherein said particles comprise a ceramic and said binder comprises a polymer.
19. The method of claim 14 , wherein said contact force is generated by an elastic force of the separator enclosure provided in an expanded state, and varies as a function of a state of charge and state of health of the battery.
20. A method of making an electrochemical cell, the method comprising the steps of:
providing a positive electrode;
providing a negative electrode;
providing one or more electrolytes positioned between said positive electrode and said negative electrode; wherein said one or more electrolytes are capable of conducting charge carriers; and
at least partially enclosing said positive electrode or said negative electrode with an electrically insulating and ionically conductive separator enclosure enclosing a surface of said positive electrode or said negative electrode that is not in physical contact with a current collector, wherein said separator enclosure generates a contact force, characterized by an average contact pressure selected from the range of 10 Pa to 10 MPa, on said surface of said positive electrode or said negative electrode during charging or discharging of said electrochemical cell; wherein the separator comprises one or more layers independently comprising an elastomer having an elongation to break of from 100% to 1000%; wherein said contact force is sufficient to prevent a substantial change in electrode porosity or surface roughness of said positive electrode or said negative electrode enclosed by said separator enclosure during cycling of said electrochemical cell.
21. The method of claim 20 , wherein said separator enclosure generates said contact force on said surface during charging or discharging of said electrochemical cell.
22. The method of claim 20 , wherein said contact force is characterized by an average contact pressure selected from the range of 1 kPa to 100 kPa.
23. The method of claim 20 , wherein said separator enclosure comprises a first layer having a plurality of apertures arranged in a first pattern and a second layer having a plurality of apertures arranged in a second pattern; wherein said second pattern has an off-set alignment relative to said first pattern such that an overlap of said apertures of said first layer and said apertures of said second layer along axes extending perpendicularly from said first layer to said second layer is less than or equal to 20%.
24. The method of claim 20 , said one or more electrolytes comprising a solid electrolyte, wherein said solid electrolyte comprises particles and a binder; wherein said particles comprise a ceramic and said binder comprises a polymer.
25. The method of claim 20 , wherein said contact force is generated by an elastic force of the separator enclosure provided in an expanded state, and varies as a function of a state of charge and state of health of the battery.
26. An electrochemical cell comprising:
a positive electrode;
a negative electrode;
one or more electrolytes positioned between said positive electrode and said negative electrode; wherein said one or more electrolytes are capable of conducting charge carriers; and wherein said one or more electrolytes comprises a solid electrolyte, wherein said solid electrolyte comprises particles and a binder; wherein said particles comprise a ceramic and said binder comprises a polymer; and
an electrically insulating and ionically conductive separator enclosure enclosing a surface of said positive electrode or said negative electrode that is not in physical contact with a current collector, wherein said separator enclosure generates a contact force, characterized by an average contact pressure selected from the range of 10 Pa to 10 MPa, on said surface of said positive electrode or said negative electrode during charging or discharging of said electrochemical cell; wherein the separator comprises one or more layers independently comprising an elastomer having an elongation to break of from 100% to 1000%; wherein said contact force is sufficient to prevent a substantial change in the electrode porosity or surface roughness of said positive electrode or said negative electrode enclosed by said separator enclosure during cycling of said electrochemical cell.