IP Library › Granted Patent US 10,481,510
Granted Patent B2
US 10,481,510 · App. 15/974,661 · Granted Nov 19, 2019

Graphene spectral purity filter

Inventors: Andrei Mikhailovich Yakunin (Eindhoven, NL); Vadim Yevgenyevich Banine (Deurne, NL); Erik Roelof Loopstra (Eindhoven, NL); Harmen Klaas Van Der Schoot (Vught, NL); Lucas Henricus Johannes Stevens (Eindhoven, NL); Maarten Van Kampen (Eindhoven, NL)
Assignee: ASML Netherlands B.V.
G03F7/70958B82Y10/00B82Y40/00C01B32/20G02B5/0816G02B5/0891G02B5/204G02B5/208G02B27/0006G03B27/54G03F1/24G03F1/62G03F1/64G03F7/702G03F7/70058G03F7/70916G03F7/70983G21K1/062H01B1/04H01B1/24G21K2201/061
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Quick Facts
Patent No.
US 10,481,510
App. No.
15/974,661
Granted
Nov 19, 2019
Kind
B2
Abstract

A pellicle that includes graphene is constructed and arranged for an EUV reticle. A multilayer mirror includes graphene as an outermost layer.

Claims (27)

1. A spectral purity filter comprising a graphene structure having uniform thickness and homogeneous composition wherein the graphene has an EUV transmittance of greater than 85%.

2. The spectral purity filter according to claim 1 , comprising a graphene layer.

3. The spectral purity filter according to claim 1 , comprising a graphene sheet.

4. The spectral purity filter according to claim 3 , wherein the graphene sheet is disposed on a spectral purity filter frame.

5. The spectral purity filter according to claim 4 , wherein the graphene sheet is supported by the spectral purity frame without a supporting grid.

6. The spectral purity filter according to claim 3 , wherein the graphene sheet supports an out-of-band radiation suppression structure.

7. The spectral purity filter according to claim 6 , wherein the graphene sheet is configured to prevent oxidation of the out-of-band radiation suppression structure.

8. The spectral purity filter according to claim 6 or 7 , wherein both sides of the out-of-band radiation suppression structure are covered with graphene.

9. The spectral purity filter according to claim 6 , wherein the suppression structure comprises a suppression layer comprising a material selected from the group consisting of: Mo, W, Si, and Zr.

10. The spectral purity filter according to claim 1 , comprising graphene flakes.

11. The spectral purity filter according to claim 10 , wherein the graphene flakes support an out-of-band radiation suppression structure.

12. The spectral purity filter according to claim 11 , wherein the graphene flakes are configured to prevent oxidation of the out-of-band radiation suppression structure.

13. The spectral purity filter according to claim 11 , wherein the suppression structure comprises a suppression layer comprising a material selected from the group consisting of: Mo, W, Si, and Zr.

14. The spectral purity filter according claim 1 , further comprising a material which blocks out-of-band radiation and wherein the graphene is configured to protect the material from oxidation and/or outgassing.

15. The spectral purity filter according to claim 14 , comprising a grid of the material to block the out-of-band radiation.

16. The spectral purity filter according to claim 15 , wherein the grid is a tungsten grid.

17. The spectral purity filter according to claim 16 , wherein the graphene is applied such that none of the tungsten grid is exposed.

18. The spectral purity filter according to claim 16 , wherein the graphene is applied as graphene layers on either side of the tungsten grid.

19. The spectral purity filter according to any of the claims 14 to 18 , wherein the graphene is provided as a layer, a sheet or as flakes.

20. The spectral purity filter according to claim 15 , wherein the grid comprises a support structure and a reflective coating, reflective to the out-of-band radiation.

21. The spectral purity filter according to claim 20 , wherein the reflective coating comprises molybdenum to reflect the out-of-band radiation.

22. The spectral purity filter according to claim 1 , further comprising a grid, the graphene being disposed on the grid.

23. The spectral purity filter according to claim 22 , wherein the grid is configured to block out-of-band radiation, a pitch of the grid being smaller than wavelengths of the to be blocked out-of-band radiation.

24. The spectral purity filter according to claim 1 , further comprising a filter constructed and arranged to pass a selected band of radiation and to suppress out of band radiation.

25. The spectral purity filter according to claim 24 , wherein the out of band radiation is selected from the group consisting of: DUV radiation and infrared radiation.

26. The spectral purity filter according to claim 1 , wherein the graphene comprises between 1 and 100 layers of graphene.

27. The spectral purity filter according to claim 26 , wherein the graphene comprises between 10 and 100 layers of graphene.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 22, 2018
From: YAKUNIN, ANDREI MIKHAILOVICH; BANINE, VADIM YEVGENYEVICH; LOOPSTRA, ERIK ROELOF; VAN DER SCHOOT, HARMEN KLAAS; STEVENS, LUCAS HENRICUS JOHANNES; VAN KAMPEN, MAARTEN
To: ASML NETHERLANDS B.V.
Reel/Frame 045871/0750 →
Continuity (6)
Continuation 15281056 · Sep 29, 2016
Continuation 14181076 · Feb 14, 2014
Continuation 13704222
Provisional Application 61362981 · Jul 9, 2010
Provisional Application 61358645 · Jun 25, 2010
Related Publication 20180259846A1 · Sep 13, 2018
Cited By (1)
US 12,474,629